Theory of heterogeneous / homogeneous catalytic reaction with presaturation
In this communication we present a theoretical study of chemical reactions in a system of solid particles, immersed in a fluid environment. Our primary concern here is investigation of the systems of catalytic particles in a liquid media; however with some slight modifications our results are applic...
Збережено в:
| Дата: | 2012 |
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| Автори: | , , |
| Формат: | Стаття |
| Мова: | English |
| Опубліковано: |
LPCA – Laboratoire de Physico-Chimie de l’Atmosph`ere EA 4493 CNRS, Universit´e du Littoral Cˆote d’Opale
2012
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| Назва видання: | Вопросы атомной науки и техники |
| Теми: | |
| Онлайн доступ: | http://dspace.nbuv.gov.ua/handle/123456789/107379 |
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| Назва журналу: | Digital Library of Periodicals of National Academy of Sciences of Ukraine |
| Цитувати: | Theory of heterogeneous / homogeneous catalytic reaction with presaturation / C. Coeur-Tourneur, D.Yu. Kopiychenko, P.O. Mchedlov-Petrossyan // Вопросы атомной науки и техники. — 2012. — № 1. — С. 311-315. — Бібліогр.: 7 назв. — англ. |
Репозиторії
Digital Library of Periodicals of National Academy of Sciences of Ukraine| Резюме: | In this communication we present a theoretical study of chemical reactions in a system of solid particles, immersed in a fluid environment. Our primary concern here is investigation of the systems of catalytic particles in a liquid media; however with some slight modifications our results are applicable to aerosol systems as well. We consider a second-order reaction, which proceeds both homogeneously in the environment, and heterogeneously at surfaces of catalyst particles. The Langmuir adsorption-desorption kinetics is considered explicitly. For definiteness, we are considering the so-called "three-step mechanism'' of the heterogeneous reaction. |
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