Theory of heterogeneous / homogeneous catalytic reaction with presaturation

In this communication we present a theoretical study of chemical reactions in a system of solid particles, immersed in a fluid environment. Our primary concern here is investigation of the systems of catalytic particles in a liquid media; however with some slight modifications our results are applic...

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Видавець:LPCA – Laboratoire de Physico-Chimie de l’Atmosph`ere EA 4493 CNRS, Universit´e du Littoral Cˆote d’Opale
Дата:2012
Автори: Coeur-Tourneur, C., Kopiychenko, D.Yu., Mchedlov-Petrossyan, P.O.
Формат: Стаття
Мова:English
Опубліковано: LPCA – Laboratoire de Physico-Chimie de l’Atmosph`ere EA 4493 CNRS, Universit´e du Littoral Cˆote d’Opale 2012
Назва видання:Вопросы атомной науки и техники
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Онлайн доступ:http://dspace.nbuv.gov.ua/handle/123456789/107379
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Цитувати:Theory of heterogeneous / homogeneous catalytic reaction with presaturation / C. Coeur-Tourneur, D.Yu. Kopiychenko, P.O. Mchedlov-Petrossyan // Вопросы атомной науки и техники. — 2012. — № 1. — С. 311-315. — Бібліогр.: 7 назв. — англ.

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Digital Library of Periodicals of National Academy of Sciences of Ukraine
id irk-123456789-107379
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spelling irk-123456789-1073792016-10-20T03:02:20Z Theory of heterogeneous / homogeneous catalytic reaction with presaturation Coeur-Tourneur, C. Kopiychenko, D.Yu. Mchedlov-Petrossyan, P.O. Section E. Phase Transitions and Diffusion Processes in Condensed Matter and Gases In this communication we present a theoretical study of chemical reactions in a system of solid particles, immersed in a fluid environment. Our primary concern here is investigation of the systems of catalytic particles in a liquid media; however with some slight modifications our results are applicable to aerosol systems as well. We consider a second-order reaction, which proceeds both homogeneously in the environment, and heterogeneously at surfaces of catalyst particles. The Langmuir adsorption-desorption kinetics is considered explicitly. For definiteness, we are considering the so-called "three-step mechanism'' of the heterogeneous reaction. Мы рассматриваем одну реакцию второго порядка, которая протекает как гомогенно в окружающей среде, так и гетерогенно на поверхностях каталитических частиц. Адсорбционно-десорбционная ленгмюровская кинетика учитывается явно. Для определённости мы рассматриваем так называемый "трёхступенчатый механизм'' гетерогенной реакции. Ми розглядаємо одну реакцію другого порядку, що протікає як гомогенно в оточуючому середовищі, так і гетерогенно на поверхнях каталітичних частин. Адсорбційно-дисорбційна ленгмюрівська кінетика враховується явно. Для визначеності ми розглядаємо так званий "триступінчатий механізм'' гетерогенної реакції. 2012 Article Theory of heterogeneous / homogeneous catalytic reaction with presaturation / C. Coeur-Tourneur, D.Yu. Kopiychenko, P.O. Mchedlov-Petrossyan // Вопросы атомной науки и техники. — 2012. — № 1. — С. 311-315. — Бібліогр.: 7 назв. — англ. 1562-6016 PACS: 82.20.-w, 82.65.+r, 82.40.-g http://dspace.nbuv.gov.ua/handle/123456789/107379 en Вопросы атомной науки и техники LPCA – Laboratoire de Physico-Chimie de l’Atmosph`ere EA 4493 CNRS, Universit´e du Littoral Cˆote d’Opale
institution Digital Library of Periodicals of National Academy of Sciences of Ukraine
collection DSpace DC
language English
topic Section E. Phase Transitions and Diffusion Processes in Condensed Matter and Gases
Section E. Phase Transitions and Diffusion Processes in Condensed Matter and Gases
spellingShingle Section E. Phase Transitions and Diffusion Processes in Condensed Matter and Gases
Section E. Phase Transitions and Diffusion Processes in Condensed Matter and Gases
Coeur-Tourneur, C.
Kopiychenko, D.Yu.
Mchedlov-Petrossyan, P.O.
Theory of heterogeneous / homogeneous catalytic reaction with presaturation
Вопросы атомной науки и техники
description In this communication we present a theoretical study of chemical reactions in a system of solid particles, immersed in a fluid environment. Our primary concern here is investigation of the systems of catalytic particles in a liquid media; however with some slight modifications our results are applicable to aerosol systems as well. We consider a second-order reaction, which proceeds both homogeneously in the environment, and heterogeneously at surfaces of catalyst particles. The Langmuir adsorption-desorption kinetics is considered explicitly. For definiteness, we are considering the so-called "three-step mechanism'' of the heterogeneous reaction.
format Article
author Coeur-Tourneur, C.
Kopiychenko, D.Yu.
Mchedlov-Petrossyan, P.O.
author_facet Coeur-Tourneur, C.
Kopiychenko, D.Yu.
Mchedlov-Petrossyan, P.O.
author_sort Coeur-Tourneur, C.
title Theory of heterogeneous / homogeneous catalytic reaction with presaturation
title_short Theory of heterogeneous / homogeneous catalytic reaction with presaturation
title_full Theory of heterogeneous / homogeneous catalytic reaction with presaturation
title_fullStr Theory of heterogeneous / homogeneous catalytic reaction with presaturation
title_full_unstemmed Theory of heterogeneous / homogeneous catalytic reaction with presaturation
title_sort theory of heterogeneous / homogeneous catalytic reaction with presaturation
publisher LPCA – Laboratoire de Physico-Chimie de l’Atmosph`ere EA 4493 CNRS, Universit´e du Littoral Cˆote d’Opale
publishDate 2012
topic_facet Section E. Phase Transitions and Diffusion Processes in Condensed Matter and Gases
url http://dspace.nbuv.gov.ua/handle/123456789/107379
citation_txt Theory of heterogeneous / homogeneous catalytic reaction with presaturation / C. Coeur-Tourneur, D.Yu. Kopiychenko, P.O. Mchedlov-Petrossyan // Вопросы атомной науки и техники. — 2012. — № 1. — С. 311-315. — Бібліогр.: 7 назв. — англ.
series Вопросы атомной науки и техники
work_keys_str_mv AT coeurtourneurc theoryofheterogeneoushomogeneouscatalyticreactionwithpresaturation
AT kopiychenkodyu theoryofheterogeneoushomogeneouscatalyticreactionwithpresaturation
AT mchedlovpetrossyanpo theoryofheterogeneoushomogeneouscatalyticreactionwithpresaturation
first_indexed 2023-10-18T20:15:01Z
last_indexed 2023-10-18T20:15:01Z
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