Crystalline structure and polymorphism in powders and thin films of dibenzotetraaza[14]annulene

• Дата: 2016
• Автор: Udovitskiy, V.G.
• Формат: Стаття
• Мова: English
• Опубліковано: Науковий фізико-технологічний центр МОН та НАН України 2016
• Назва видання: Журнал физики и инженерии поверхности
• Онлайн доступ: http://dspace.nbuv.gov.ua/handle/123456789/117009
• Назва журналу: Digital Library of Periodicals of National Academy of Sciences of Ukraine
• Цитувати: Crystalline structure and polymorphism in powders and thin films of dibenzotetraaza[14]annulene / V.G. Udovitskiy // Журнал физики и инженерии поверхности. — 2016. — Т. 1, № 3. — С. 310-319 . — Бібліогр.: 34 назв. — англ.

The increasing interest in dibenzotetraaza[14]annulene (TAA) is motivated by the demonstrated perspectives for using this organic semiconductor in actively progressive now spintronics and in other fields of electronics. This work is the first study on polymorphism, which may occur in powder and in thin TAA films. The results of this study showed that the initial TAA powder synthesized by chemical methods are both now known polymorphic forms of TAA which were registered at Cambridge Crystallographic Data Centre as GAGVAL and GAGVAL01. It was also found that at the condensation of thin films G-form initially formed while after increasing the film thickness the G01-form will forms also and a continuous films have twophases and contain both known polymorphs — G and G01. The X-ray diffraction pattern indicated also that crystallites in thin TAA films show a strong preffered orientation (texture) with the (100) plane (for G-polymorph) and (002) plane (for G01-polymorph) parallel to the surface of the substrate