Ion–molecule reactions of CoAr₆⁺ with nitrogen oxides N₂O, NO, and NO₂: measuring absolute pressure by shock-freezing of the collision complex

Ion–molecule reactions of CoAr₆⁺ with nitrogen oxides N₂O, NO, and NO₂: measuring absolute pressure by shock-freezing of the collision complex

A new method to determine the absolute pressure in an ultra-high vacuum apparatus is tested using ion molecule reactions with CoAr₆⁺. In a collision with a neutral reactant, the complex between Co⁺ and the collision partner is stabilized by evaporation of argon atoms. If CoAr₆⁺ reacts with collision...

Повний опис

Збережено в:
Бібліографічні деталі
Дата:2010
Автори: Linde, C. van der, Höckendorf, R.F., Balaj, O.P., Beyer, M.K.
Формат: Стаття
Мова:English
Опубліковано: Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України 2010
Назва видання:Физика низких температур
Теми:
Nanostructures and Impurity Centers in Cryogenic Environment
Онлайн доступ:http://dspace.nbuv.gov.ua/handle/123456789/117041
Теги: Додати тег
Немає тегів, Будьте першим, хто поставить тег для цього запису!
Назва журналу:Digital Library of Periodicals of National Academy of Sciences of Ukraine
Цитувати:Ion–molecule reactions of CoAr₆⁺ with nitrogen oxides N₂O, NO, and NO₂: measuring absolute pressure by shock-freezing of the collision complex / C. van der Linde, R.F. Höckendorf, O.P. Balaj, M.K. Beyer // Физика низких температур. — 2010. — Т. 36, № 5. — С. 516-523. — Бібліогр.: 63 назв. — англ.

Репозитарії

Digital Library of Periodicals of National Academy of Sciences of Ukraine
id irk-123456789-117041
record_format dspace
spelling irk-123456789-1170412017-05-20T03:03:03Z Ion–molecule reactions of CoAr₆⁺ with nitrogen oxides N₂O, NO, and NO₂: measuring absolute pressure by shock-freezing of the collision complex Linde, C. van der Höckendorf, R.F. Balaj, O.P. Beyer, M.K. Nanostructures and Impurity Centers in Cryogenic Environment A new method to determine the absolute pressure in an ultra-high vacuum apparatus is tested using ion molecule reactions with CoAr₆⁺. In a collision with a neutral reactant, the complex between Co⁺ and the collision partner is stabilized by evaporation of argon atoms. If CoAr₆⁺ reacts with collision rate, the absolute pressure can be determined by comparing the experimental collision rate with the collision rate calculated from average dipole orientation theory. The experimental results with N₂O, NO, and NO₂ indeed show that the collision complex is frozen out. Comparison of the rates of primary, secondary and tertiary reaction products, however, suggests that not all collisions of CoAr₆⁺ are reactive. 2010 Article Ion–molecule reactions of CoAr₆⁺ with nitrogen oxides N₂O, NO, and NO₂: measuring absolute pressure by shock-freezing of the collision complex / C. van der Linde, R.F. Höckendorf, O.P. Balaj, M.K. Beyer // Физика низких температур. — 2010. — Т. 36, № 5. — С. 516-523. — Бібліогр.: 63 назв. — англ. 0132-6414 PACS: 82.30.Fi http://dspace.nbuv.gov.ua/handle/123456789/117041 en Физика низких температур Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України
institution Digital Library of Periodicals of National Academy of Sciences of Ukraine
collection DSpace DC
language English
topic Nanostructures and Impurity Centers in Cryogenic Environment
Nanostructures and Impurity Centers in Cryogenic Environment
spellingShingle Nanostructures and Impurity Centers in Cryogenic Environment
Nanostructures and Impurity Centers in Cryogenic Environment
Linde, C. van der
Höckendorf, R.F.
Balaj, O.P.
Beyer, M.K.
Ion–molecule reactions of CoAr₆⁺ with nitrogen oxides N₂O, NO, and NO₂: measuring absolute pressure by shock-freezing of the collision complex
Физика низких температур
description A new method to determine the absolute pressure in an ultra-high vacuum apparatus is tested using ion molecule reactions with CoAr₆⁺. In a collision with a neutral reactant, the complex between Co⁺ and the collision partner is stabilized by evaporation of argon atoms. If CoAr₆⁺ reacts with collision rate, the absolute pressure can be determined by comparing the experimental collision rate with the collision rate calculated from average dipole orientation theory. The experimental results with N₂O, NO, and NO₂ indeed show that the collision complex is frozen out. Comparison of the rates of primary, secondary and tertiary reaction products, however, suggests that not all collisions of CoAr₆⁺ are reactive.
format Article
author Linde, C. van der
Höckendorf, R.F.
Balaj, O.P.
Beyer, M.K.
author_facet Linde, C. van der
Höckendorf, R.F.
Balaj, O.P.
Beyer, M.K.
author_sort Linde, C. van der
title Ion–molecule reactions of CoAr₆⁺ with nitrogen oxides N₂O, NO, and NO₂: measuring absolute pressure by shock-freezing of the collision complex
title_short Ion–molecule reactions of CoAr₆⁺ with nitrogen oxides N₂O, NO, and NO₂: measuring absolute pressure by shock-freezing of the collision complex
title_full Ion–molecule reactions of CoAr₆⁺ with nitrogen oxides N₂O, NO, and NO₂: measuring absolute pressure by shock-freezing of the collision complex
title_fullStr Ion–molecule reactions of CoAr₆⁺ with nitrogen oxides N₂O, NO, and NO₂: measuring absolute pressure by shock-freezing of the collision complex
title_full_unstemmed Ion–molecule reactions of CoAr₆⁺ with nitrogen oxides N₂O, NO, and NO₂: measuring absolute pressure by shock-freezing of the collision complex
title_sort ion–molecule reactions of coar₆⁺ with nitrogen oxides n₂o, no, and no₂: measuring absolute pressure by shock-freezing of the collision complex
publisher Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України
publishDate 2010
topic_facet Nanostructures and Impurity Centers in Cryogenic Environment
url http://dspace.nbuv.gov.ua/handle/123456789/117041
citation_txt Ion–molecule reactions of CoAr₆⁺ with nitrogen oxides N₂O, NO, and NO₂: measuring absolute pressure by shock-freezing of the collision complex / C. van der Linde, R.F. Höckendorf, O.P. Balaj, M.K. Beyer // Физика низких температур. — 2010. — Т. 36, № 5. — С. 516-523. — Бібліогр.: 63 назв. — англ.
series Физика низких температур
work_keys_str_mv AT lindecvander ionmoleculereactionsofcoar6withnitrogenoxidesn2onoandno2measuringabsolutepressurebyshockfreezingofthecollisioncomplex
AT hockendorfrf ionmoleculereactionsofcoar6withnitrogenoxidesn2onoandno2measuringabsolutepressurebyshockfreezingofthecollisioncomplex
AT balajop ionmoleculereactionsofcoar6withnitrogenoxidesn2onoandno2measuringabsolutepressurebyshockfreezingofthecollisioncomplex
AT beyermk ionmoleculereactionsofcoar6withnitrogenoxidesn2onoandno2measuringabsolutepressurebyshockfreezingofthecollisioncomplex
first_indexed 2023-10-18T20:28:53Z
last_indexed 2023-10-18T20:28:53Z
_version_ 1796150312320368640

Схожі ресурси