Crystal field splitting on D↔S transitions of atomic manganese isolated in solid krypton
Narrow excitation features present on the [Ar]3d⁶4s¹ a⁶D(J=9/2–1/2)←[Ar]3d⁵4s² a⁶S1/2 transitions of manganese atoms isolated in solid Kr are analyzed within the framework of weak crystal field splitting. Use of the Wp optical lineshape function allowed identification of multiple zero-phonon lines f...
Збережено в:
| Дата: | 2010 |
|---|---|
| Автори: | , , , |
| Формат: | Стаття |
| Мова: | English |
| Опубліковано: |
Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України
2010
|
| Назва видання: | Физика низких температур |
| Теми: | |
| Онлайн доступ: | http://dspace.nbuv.gov.ua/handle/123456789/117042 |
| Теги: |
Додати тег
Немає тегів, Будьте першим, хто поставить тег для цього запису!
|
| Назва журналу: | Digital Library of Periodicals of National Academy of Sciences of Ukraine |
| Цитувати: | Crystal field splitting on D↔S transitions of atomic manganese isolated in solid krypton / O. Byrne, M.A. Collier, M.C. Ryan, J.G. McCaffrey // Физика низких температур. — 2010. — Т. 36, № 5. — С. 524-531. — Бібліогр.: 13 назв. — англ. |
Репозиторії
Digital Library of Periodicals of National Academy of Sciences of Ukraine| id |
irk-123456789-117042 |
|---|---|
| record_format |
dspace |
| spelling |
irk-123456789-1170422017-05-20T03:03:04Z Crystal field splitting on D↔S transitions of atomic manganese isolated in solid krypton Byrne, O. Collier, M.A. Ryan, M.C. McCaffrey, J.G. Nanostructures and Impurity Centers in Cryogenic Environment Narrow excitation features present on the [Ar]3d⁶4s¹ a⁶D(J=9/2–1/2)←[Ar]3d⁵4s² a⁶S1/2 transitions of manganese atoms isolated in solid Kr are analyzed within the framework of weak crystal field splitting. Use of the Wp optical lineshape function allowed identification of multiple zero-phonon lines for individual spin-orbit J states of the a⁶D←a⁶S transition recorded with laser-induced excitation spectroscopy. Excellent agreement exists between the predicted crystal field splitting patterns for the J levels of the a⁶D state isolated in the «red» tetravacancy site of solid Kr. The tetrahedral crystal field of the «red» trapping site splits J>3/2 levels of the a⁶DJ and a⁴D₇/₂ states by approximately 30 cm⁻¹. This report represents the first definitive evidence of crystal field splitting, induced by the weak van der Waals interactions between a neutral metal atom and the rare gas atoms surrounding it in a well defined solid state site. 2010 Article Crystal field splitting on D↔S transitions of atomic manganese isolated in solid krypton / O. Byrne, M.A. Collier, M.C. Ryan, J.G. McCaffrey // Физика низких температур. — 2010. — Т. 36, № 5. — С. 524-531. — Бібліогр.: 13 назв. — англ. 0132-6414 PACS: 31.70.Dk, 78.40.–q, 78.55.–m http://dspace.nbuv.gov.ua/handle/123456789/117042 en Физика низких температур Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України |
| institution |
Digital Library of Periodicals of National Academy of Sciences of Ukraine |
| collection |
DSpace DC |
| language |
English |
| topic |
Nanostructures and Impurity Centers in Cryogenic Environment Nanostructures and Impurity Centers in Cryogenic Environment |
| spellingShingle |
Nanostructures and Impurity Centers in Cryogenic Environment Nanostructures and Impurity Centers in Cryogenic Environment Byrne, O. Collier, M.A. Ryan, M.C. McCaffrey, J.G. Crystal field splitting on D↔S transitions of atomic manganese isolated in solid krypton Физика низких температур |
| description |
Narrow excitation features present on the [Ar]3d⁶4s¹ a⁶D(J=9/2–1/2)←[Ar]3d⁵4s² a⁶S1/2 transitions of manganese atoms isolated in solid Kr are analyzed within the framework of weak crystal field splitting. Use of the Wp optical lineshape function allowed identification of multiple zero-phonon lines for individual spin-orbit J states of the a⁶D←a⁶S transition recorded with laser-induced excitation spectroscopy. Excellent agreement exists between the predicted crystal field splitting patterns for the J levels of the a⁶D state isolated in the «red» tetravacancy site of solid Kr. The tetrahedral crystal field of the «red» trapping site splits J>3/2 levels of the a⁶DJ and a⁴D₇/₂ states by approximately 30 cm⁻¹. This report represents the first definitive evidence of crystal field splitting, induced by the weak van der Waals interactions between a neutral metal atom and the rare gas atoms surrounding it in a well defined solid state site. |
| format |
Article |
| author |
Byrne, O. Collier, M.A. Ryan, M.C. McCaffrey, J.G. |
| author_facet |
Byrne, O. Collier, M.A. Ryan, M.C. McCaffrey, J.G. |
| author_sort |
Byrne, O. |
| title |
Crystal field splitting on D↔S transitions of atomic manganese isolated in solid krypton |
| title_short |
Crystal field splitting on D↔S transitions of atomic manganese isolated in solid krypton |
| title_full |
Crystal field splitting on D↔S transitions of atomic manganese isolated in solid krypton |
| title_fullStr |
Crystal field splitting on D↔S transitions of atomic manganese isolated in solid krypton |
| title_full_unstemmed |
Crystal field splitting on D↔S transitions of atomic manganese isolated in solid krypton |
| title_sort |
crystal field splitting on d↔s transitions of atomic manganese isolated in solid krypton |
| publisher |
Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України |
| publishDate |
2010 |
| topic_facet |
Nanostructures and Impurity Centers in Cryogenic Environment |
| url |
http://dspace.nbuv.gov.ua/handle/123456789/117042 |
| citation_txt |
Crystal field splitting on D↔S transitions of atomic manganese isolated in solid krypton / O. Byrne, M.A. Collier, M.C. Ryan, J.G. McCaffrey // Физика низких температур. — 2010. — Т. 36, № 5. — С. 524-531. — Бібліогр.: 13 назв. — англ. |
| series |
Физика низких температур |
| work_keys_str_mv |
AT byrneo crystalfieldsplittingondstransitionsofatomicmanganeseisolatedinsolidkrypton AT collierma crystalfieldsplittingondstransitionsofatomicmanganeseisolatedinsolidkrypton AT ryanmc crystalfieldsplittingondstransitionsofatomicmanganeseisolatedinsolidkrypton AT mccaffreyjg crystalfieldsplittingondstransitionsofatomicmanganeseisolatedinsolidkrypton |
| first_indexed |
2023-10-18T20:28:53Z |
| last_indexed |
2023-10-18T20:28:53Z |
| _version_ |
1796150312427323392 |