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Investigation of dynamic glass transitions and structure transformations in cryovacuum condensates of ethanol

Investigation of dynamic glass transitions and structure transformations in cryovacuum condensates of ethanol

IR spectrometric investigation of dynamic glass transition from the rotationally disordered crystal into orientationally disordered crystal of ethanol was carried out. The examples considered are thin films formed from the gas phase at a substrate temperature of T = 16 K. The measurements were perfo...

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Main Authors: Aldiyarov, А., Aryutkina, М., Drobyshev, А., Kaikanov, M., Kurnosov, V.
Format: Article
Language:English
Published: Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України 2009
Series:Физика низких температур
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7th International Conference on Cryocrystals and Quantum Crystals
Online Access:http://dspace.nbuv.gov.ua/handle/123456789/117087
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spelling irk-123456789-1170872017-05-20T03:02:53Z Investigation of dynamic glass transitions and structure transformations in cryovacuum condensates of ethanol Aldiyarov, А. Aryutkina, М. Drobyshev, А. Kaikanov, M. Kurnosov, V. 7th International Conference on Cryocrystals and Quantum Crystals IR spectrometric investigation of dynamic glass transition from the rotationally disordered crystal into orientationally disordered crystal of ethanol was carried out. The examples considered are thin films formed from the gas phase at a substrate temperature of T = 16 K. The measurements were performed using the experimental apparatus which has been described in detail in our recent work. The thickness of the sample was d = 2 μm, the typical rate of annealing was approximately 10 K/min. The obtained results are compared with the phase diagram of solid ethanol proposed by M.A. Ramos et al. We observe a good agreement between the temperature intervals of existence of amorphous and crystalline states. The low-temperature amorphous phase (12–70 K) is described by the present authors as amorphous solid ethanol by analogy with the amorphous solid water. 2009 Article Investigation of dynamic glass transitions and structure transformations in cryovacuum condensates of ethanol / A. Aldiyarov, M. Aryutkina, A. Drobyshev, M. Kaikanov, V. Kurnosov // Физика низких температур. — 2009. — Т. 35, № 4. — С. 333-338. — Бібліогр.: 10 назв. — англ. 0132-6414 PACS: 61.50.–f, 78.30.–j, 78.30.Hv http://dspace.nbuv.gov.ua/handle/123456789/117087 en Физика низких температур Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України
institution Digital Library of Periodicals of National Academy of Sciences of Ukraine
collection DSpace DC
language English
topic 7th International Conference on Cryocrystals and Quantum Crystals
7th International Conference on Cryocrystals and Quantum Crystals
spellingShingle 7th International Conference on Cryocrystals and Quantum Crystals
7th International Conference on Cryocrystals and Quantum Crystals
Aldiyarov, А.
Aryutkina, М.
Drobyshev, А.
Kaikanov, M.
Kurnosov, V.
Investigation of dynamic glass transitions and structure transformations in cryovacuum condensates of ethanol
Физика низких температур
description IR spectrometric investigation of dynamic glass transition from the rotationally disordered crystal into orientationally disordered crystal of ethanol was carried out. The examples considered are thin films formed from the gas phase at a substrate temperature of T = 16 K. The measurements were performed using the experimental apparatus which has been described in detail in our recent work. The thickness of the sample was d = 2 μm, the typical rate of annealing was approximately 10 K/min. The obtained results are compared with the phase diagram of solid ethanol proposed by M.A. Ramos et al. We observe a good agreement between the temperature intervals of existence of amorphous and crystalline states. The low-temperature amorphous phase (12–70 K) is described by the present authors as amorphous solid ethanol by analogy with the amorphous solid water.
format Article
author Aldiyarov, А.
Aryutkina, М.
Drobyshev, А.
Kaikanov, M.
Kurnosov, V.
author_facet Aldiyarov, А.
Aryutkina, М.
Drobyshev, А.
Kaikanov, M.
Kurnosov, V.
author_sort Aldiyarov, А.
title Investigation of dynamic glass transitions and structure transformations in cryovacuum condensates of ethanol
title_short Investigation of dynamic glass transitions and structure transformations in cryovacuum condensates of ethanol
title_full Investigation of dynamic glass transitions and structure transformations in cryovacuum condensates of ethanol
title_fullStr Investigation of dynamic glass transitions and structure transformations in cryovacuum condensates of ethanol
title_full_unstemmed Investigation of dynamic glass transitions and structure transformations in cryovacuum condensates of ethanol
title_sort investigation of dynamic glass transitions and structure transformations in cryovacuum condensates of ethanol
publisher Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України
publishDate 2009
topic_facet 7th International Conference on Cryocrystals and Quantum Crystals
url http://dspace.nbuv.gov.ua/handle/123456789/117087
citation_txt Investigation of dynamic glass transitions and structure transformations in cryovacuum condensates of ethanol / A. Aldiyarov, M. Aryutkina, A. Drobyshev, M. Kaikanov, V. Kurnosov // Физика низких температур. — 2009. — Т. 35, № 4. — С. 333-338. — Бібліогр.: 10 назв. — англ.
series Физика низких температур
work_keys_str_mv AT aldiyarova investigationofdynamicglasstransitionsandstructuretransformationsincryovacuumcondensatesofethanol
AT aryutkinam investigationofdynamicglasstransitionsandstructuretransformationsincryovacuumcondensatesofethanol
AT drobysheva investigationofdynamicglasstransitionsandstructuretransformationsincryovacuumcondensatesofethanol
AT kaikanovm investigationofdynamicglasstransitionsandstructuretransformationsincryovacuumcondensatesofethanol
AT kurnosovv investigationofdynamicglasstransitionsandstructuretransformationsincryovacuumcondensatesofethanol
first_indexed 2023-10-18T20:28:59Z
last_indexed 2023-10-18T20:28:59Z
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