Heat transfer in solid methyl alcohol

Thermal conductivity coefficient к(T) of two crystalline (orientationally-ordered and orientationally-disordered) phases of pure methanol (at temperatures from 2 K to Tm , Tm is the melting temperature), CH₃OH + 6.6 % H₂O glass from 2 K to Tg , Tg is the glass transition temperature and a supercoole...

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Дата:2009
Автори: Korolyuk, O.A., Krivchikov, A.I., Sharapova, I.V., Romantsova, O.O.
Формат: Стаття
Мова:English
Опубліковано: Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України 2009
Назва видання:Физика низких температур
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Онлайн доступ:http://dspace.nbuv.gov.ua/handle/123456789/117111
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Назва журналу:Digital Library of Periodicals of National Academy of Sciences of Ukraine
Цитувати:Heat transfer in solid methyl alcohol / O.A. Korolyuk, A.I. Krivchikov, I.V. Sharapova, O.O. Romantsova // Физика низких температур. — 2009. — Т. 35, № 4. — С. 380-384. — Бібліогр.: 34 назв. — англ.

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Digital Library of Periodicals of National Academy of Sciences of Ukraine
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spelling irk-123456789-1171112017-05-20T03:03:39Z Heat transfer in solid methyl alcohol Korolyuk, O.A. Krivchikov, A.I. Sharapova, I.V. Romantsova, O.O. 7th International Conference on Cryocrystals and Quantum Crystals Thermal conductivity coefficient к(T) of two crystalline (orientationally-ordered and orientationally-disordered) phases of pure methanol (at temperatures from 2 K to Tm , Tm is the melting temperature), CH₃OH + 6.6 % H₂O glass from 2 K to Tg , Tg is the glass transition temperature and a supercooled liquid from Tg to 120 K has been measured under equilibrium vapor pressure. The dependence к(T) is described approximately as a sum of two contributions: кI(T) describing heat transport by acoustic phonons and кII(T) —by localized high-frequency excitations. The temperature dependences of the thermal conductivity of primary monoatomic alcohols CH₃OH, C₂H₅OH, and C₃H₇OH in the glass state have been compared. Different mechanisms of phonon scattering in the crystalline phases and glass have been analyzed. The кII(T) has been calculated within the Cahill–Pohl model. There is an anomaly of the thermal conductivity of the glass state near Tg (a smeared minimum in the к(T) — curve). 2009 Article Heat transfer in solid methyl alcohol / O.A. Korolyuk, A.I. Krivchikov, I.V. Sharapova, O.O. Romantsova // Физика низких температур. — 2009. — Т. 35, № 4. — С. 380-384. — Бібліогр.: 34 назв. — англ. 0132-6414 PACS: 66.70.–f, 63.20.–e, 63.50.–x http://dspace.nbuv.gov.ua/handle/123456789/117111 en Физика низких температур Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України
institution Digital Library of Periodicals of National Academy of Sciences of Ukraine
collection DSpace DC
language English
topic 7th International Conference on Cryocrystals and Quantum Crystals
7th International Conference on Cryocrystals and Quantum Crystals
spellingShingle 7th International Conference on Cryocrystals and Quantum Crystals
7th International Conference on Cryocrystals and Quantum Crystals
Korolyuk, O.A.
Krivchikov, A.I.
Sharapova, I.V.
Romantsova, O.O.
Heat transfer in solid methyl alcohol
Физика низких температур
description Thermal conductivity coefficient к(T) of two crystalline (orientationally-ordered and orientationally-disordered) phases of pure methanol (at temperatures from 2 K to Tm , Tm is the melting temperature), CH₃OH + 6.6 % H₂O glass from 2 K to Tg , Tg is the glass transition temperature and a supercooled liquid from Tg to 120 K has been measured under equilibrium vapor pressure. The dependence к(T) is described approximately as a sum of two contributions: кI(T) describing heat transport by acoustic phonons and кII(T) —by localized high-frequency excitations. The temperature dependences of the thermal conductivity of primary monoatomic alcohols CH₃OH, C₂H₅OH, and C₃H₇OH in the glass state have been compared. Different mechanisms of phonon scattering in the crystalline phases and glass have been analyzed. The кII(T) has been calculated within the Cahill–Pohl model. There is an anomaly of the thermal conductivity of the glass state near Tg (a smeared minimum in the к(T) — curve).
format Article
author Korolyuk, O.A.
Krivchikov, A.I.
Sharapova, I.V.
Romantsova, O.O.
author_facet Korolyuk, O.A.
Krivchikov, A.I.
Sharapova, I.V.
Romantsova, O.O.
author_sort Korolyuk, O.A.
title Heat transfer in solid methyl alcohol
title_short Heat transfer in solid methyl alcohol
title_full Heat transfer in solid methyl alcohol
title_fullStr Heat transfer in solid methyl alcohol
title_full_unstemmed Heat transfer in solid methyl alcohol
title_sort heat transfer in solid methyl alcohol
publisher Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України
publishDate 2009
topic_facet 7th International Conference on Cryocrystals and Quantum Crystals
url http://dspace.nbuv.gov.ua/handle/123456789/117111
citation_txt Heat transfer in solid methyl alcohol / O.A. Korolyuk, A.I. Krivchikov, I.V. Sharapova, O.O. Romantsova // Физика низких температур. — 2009. — Т. 35, № 4. — С. 380-384. — Бібліогр.: 34 назв. — англ.
series Физика низких температур
work_keys_str_mv AT korolyukoa heattransferinsolidmethylalcohol
AT krivchikovai heattransferinsolidmethylalcohol
AT sharapovaiv heattransferinsolidmethylalcohol
AT romantsovaoo heattransferinsolidmethylalcohol
first_indexed 2023-10-18T20:29:03Z
last_indexed 2023-10-18T20:29:03Z
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