2025-02-23T19:01:33-05:00 DEBUG: VuFindSearch\Backend\Solr\Connector: Query fl=%2A&wt=json&json.nl=arrarr&q=id%3A%22irk-123456789-117267%22&qt=morelikethis&rows=5
2025-02-23T19:01:33-05:00 DEBUG: VuFindSearch\Backend\Solr\Connector: => GET http://localhost:8983/solr/biblio/select?fl=%2A&wt=json&json.nl=arrarr&q=id%3A%22irk-123456789-117267%22&qt=morelikethis&rows=5
2025-02-23T19:01:33-05:00 DEBUG: VuFindSearch\Backend\Solr\Connector: <= 200 OK
2025-02-23T19:01:33-05:00 DEBUG: Deserialized SOLR response

The nature of spin trimer in Ca₃Cu₂Ni(PO₄)₄

The nature of spin trimer and 3d spin dynamics in Ca₃Cu₂Ni(PO₄)₄ was studied using ³¹P NMR measurements. This material is obtained replacing one of the Cu ions by a Ni ion in one dimensional spin trimer compound Ca₃Cu₃(PO₄)₄. NMR spectrum suggests the presence of two types of magnetically inequiva...

Full description

Saved in:
Bibliographic Details
Main Authors: Ghosh, M., Ghoshray, K.
Format: Article
Language:English
Published: Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України 2012
Series:Физика низких температур
Subjects:
Online Access:http://dspace.nbuv.gov.ua/handle/123456789/117267
Tags: Add Tag
No Tags, Be the first to tag this record!
id irk-123456789-117267
record_format dspace
spelling irk-123456789-1172672017-05-22T03:03:28Z The nature of spin trimer in Ca₃Cu₂Ni(PO₄)₄ Ghosh, M. Ghoshray, K. Магнетизм The nature of spin trimer and 3d spin dynamics in Ca₃Cu₂Ni(PO₄)₄ was studied using ³¹P NMR measurements. This material is obtained replacing one of the Cu ions by a Ni ion in one dimensional spin trimer compound Ca₃Cu₃(PO₄)₄. NMR spectrum suggests the presence of two types of magnetically inequivalent phosphorous atoms as in the parent compound. This finding reveals the presence of only one type of trimer viz. Cu₂–Ni–Cu₂ rather than three types viz., Cu₂–Cu₁–Cu₂, Cu₂–Cu₁–Ni and Ni–Cu₁–Ni as suggested from neutron scattering. Hence the ground state of Ca3Cu2Ni(PO4)4 appears to be a quintet. The present finding also explains the magnetic susceptibility behavior showing no indication of the reduction of net spin of a trimer in Ca₃Cu₂Ni(PO₄)₄, as expected for JNi–Cu = – 0.85 meV compared to JCu–Cu = – 4.74 meV, reported from neutron scattering. The spin lattice relaxation rate suggests that the three magnon mediated scattering process, dominant in Ca₃Cu₃(PO₄)₄, is reduced in Ca₃Cu₂Ni(PO₄)₄. 2012 Article The nature of spin trimer in Ca₃Cu₂Ni(PO₄)₄ / M. Ghosh, K. Ghoshray // Физика низких температур. — 2012. — Т. 38, № 7. — С. 815-820. — Бібліогр.: 18 назв. — англ. 0132-6414 PACS: 75.50.Ee, 75.30.Et, 76.60.–k http://dspace.nbuv.gov.ua/handle/123456789/117267 en Физика низких температур Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України
institution Digital Library of Periodicals of National Academy of Sciences of Ukraine
collection DSpace DC
language English
topic Магнетизм
Магнетизм
spellingShingle Магнетизм
Магнетизм
Ghosh, M.
Ghoshray, K.
The nature of spin trimer in Ca₃Cu₂Ni(PO₄)₄
Физика низких температур
description The nature of spin trimer and 3d spin dynamics in Ca₃Cu₂Ni(PO₄)₄ was studied using ³¹P NMR measurements. This material is obtained replacing one of the Cu ions by a Ni ion in one dimensional spin trimer compound Ca₃Cu₃(PO₄)₄. NMR spectrum suggests the presence of two types of magnetically inequivalent phosphorous atoms as in the parent compound. This finding reveals the presence of only one type of trimer viz. Cu₂–Ni–Cu₂ rather than three types viz., Cu₂–Cu₁–Cu₂, Cu₂–Cu₁–Ni and Ni–Cu₁–Ni as suggested from neutron scattering. Hence the ground state of Ca3Cu2Ni(PO4)4 appears to be a quintet. The present finding also explains the magnetic susceptibility behavior showing no indication of the reduction of net spin of a trimer in Ca₃Cu₂Ni(PO₄)₄, as expected for JNi–Cu = – 0.85 meV compared to JCu–Cu = – 4.74 meV, reported from neutron scattering. The spin lattice relaxation rate suggests that the three magnon mediated scattering process, dominant in Ca₃Cu₃(PO₄)₄, is reduced in Ca₃Cu₂Ni(PO₄)₄.
format Article
author Ghosh, M.
Ghoshray, K.
author_facet Ghosh, M.
Ghoshray, K.
author_sort Ghosh, M.
title The nature of spin trimer in Ca₃Cu₂Ni(PO₄)₄
title_short The nature of spin trimer in Ca₃Cu₂Ni(PO₄)₄
title_full The nature of spin trimer in Ca₃Cu₂Ni(PO₄)₄
title_fullStr The nature of spin trimer in Ca₃Cu₂Ni(PO₄)₄
title_full_unstemmed The nature of spin trimer in Ca₃Cu₂Ni(PO₄)₄
title_sort nature of spin trimer in ca₃cu₂ni(po₄)₄
publisher Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України
publishDate 2012
topic_facet Магнетизм
url http://dspace.nbuv.gov.ua/handle/123456789/117267
citation_txt The nature of spin trimer in Ca₃Cu₂Ni(PO₄)₄ / M. Ghosh, K. Ghoshray // Физика низких температур. — 2012. — Т. 38, № 7. — С. 815-820. — Бібліогр.: 18 назв. — англ.
series Физика низких температур
work_keys_str_mv AT ghoshm thenatureofspintrimerinca3cu2nipo44
AT ghoshrayk thenatureofspintrimerinca3cu2nipo44
AT ghoshm natureofspintrimerinca3cu2nipo44
AT ghoshrayk natureofspintrimerinca3cu2nipo44
first_indexed 2023-10-18T20:29:24Z
last_indexed 2023-10-18T20:29:24Z
_version_ 1796150335401623552