Photodissociation and photochemistry of V⁺ (H₂O)n, n = 1–4, in the 360–680 nm region
The photodissociation and photochemistry of V⁺ (H₂O)n, n = 1–4, was studied in the 360–680 nm region in a Fourier transform ion cyclotron resonance mass spectrometer. The light of a high pressure mercury arc lamp was filtered with band pass filters, with center wavelengths from 360 to 680 nm in st...
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| Дата: | 2012 |
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| Автори: | , , , , , |
| Формат: | Стаття |
| Мова: | English |
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Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України
2012
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| Назва видання: | Физика низких температур |
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| Онлайн доступ: | http://dspace.nbuv.gov.ua/handle/123456789/117423 |
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| Назва журналу: | Digital Library of Periodicals of National Academy of Sciences of Ukraine |
| Цитувати: | Photodissociation and photochemistry of V⁺ (H₂O)n, n = 1–4, in the 360–680 nm region / B. Scharfschwerdt, C. van der Linde, O.P. Balaj, I. Herber, D. Schütze, M.K. Beyer // Физика низких температур. — 2012. — Т. 38, № 8. — С. 905-911 . — Бібліогр.: 47 назв. — англ. |
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Digital Library of Periodicals of National Academy of Sciences of Ukraine| id |
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irk-123456789-1174232017-05-24T03:04:20Z Photodissociation and photochemistry of V⁺ (H₂O)n, n = 1–4, in the 360–680 nm region Scharfschwerdt, B. van der Linde, C. Balaj, O.P. Herber, I. Schütze, D. Beyer, M.K. Low Temperature Spectroscopy and Radiation Effects The photodissociation and photochemistry of V⁺ (H₂O)n, n = 1–4, was studied in the 360–680 nm region in a Fourier transform ion cyclotron resonance mass spectrometer. The light of a high pressure mercury arc lamp was filtered with band pass filters, with center wavelengths from 360 to 680 nm in steps of 20 nm. The bandwidth of the filters, defined as full width at half maximum, was 10 nm. Photodissociation channels are loss of water molecules, as well as loss of atomic or molecular hydrogen, which may be accompanied by loss of water molecules. The most intense absorptions are red shifted with increasing hydration. Theoretical spectra are calculated with time dependent density functional theory. Calculations reproduce all features of the experimental spectra, including the red shift with increasing hydration shell and the overall pattern of strong and weak absorptions. 2012 Article Photodissociation and photochemistry of V⁺ (H₂O)n, n = 1–4, in the 360–680 nm region / B. Scharfschwerdt, C. van der Linde, O.P. Balaj, I. Herber, D. Schütze, M.K. Beyer // Физика низких температур. — 2012. — Т. 38, № 8. — С. 905-911 . — Бібліогр.: 47 назв. — англ. 0132-6414 PACS: 36.40.–c, 36.40.Mr, 36.40.Qv http://dspace.nbuv.gov.ua/handle/123456789/117423 en Физика низких температур Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України |
| institution |
Digital Library of Periodicals of National Academy of Sciences of Ukraine |
| collection |
DSpace DC |
| language |
English |
| topic |
Low Temperature Spectroscopy and Radiation Effects Low Temperature Spectroscopy and Radiation Effects |
| spellingShingle |
Low Temperature Spectroscopy and Radiation Effects Low Temperature Spectroscopy and Radiation Effects Scharfschwerdt, B. van der Linde, C. Balaj, O.P. Herber, I. Schütze, D. Beyer, M.K. Photodissociation and photochemistry of V⁺ (H₂O)n, n = 1–4, in the 360–680 nm region Физика низких температур |
| description |
The photodissociation and photochemistry of V⁺ (H₂O)n, n = 1–4, was studied in the 360–680 nm region in
a Fourier transform ion cyclotron resonance mass spectrometer. The light of a high pressure mercury arc lamp was
filtered with band pass filters, with center wavelengths from 360 to 680 nm in steps of 20 nm. The bandwidth of
the filters, defined as full width at half maximum, was 10 nm. Photodissociation channels are loss of water molecules,
as well as loss of atomic or molecular hydrogen, which may be accompanied by loss of water molecules.
The most intense absorptions are red shifted with increasing hydration. Theoretical spectra are calculated with
time dependent density functional theory. Calculations reproduce all features of the experimental spectra, including
the red shift with increasing hydration shell and the overall pattern of strong and weak absorptions. |
| format |
Article |
| author |
Scharfschwerdt, B. van der Linde, C. Balaj, O.P. Herber, I. Schütze, D. Beyer, M.K. |
| author_facet |
Scharfschwerdt, B. van der Linde, C. Balaj, O.P. Herber, I. Schütze, D. Beyer, M.K. |
| author_sort |
Scharfschwerdt, B. |
| title |
Photodissociation and photochemistry of V⁺ (H₂O)n, n = 1–4, in the 360–680 nm region |
| title_short |
Photodissociation and photochemistry of V⁺ (H₂O)n, n = 1–4, in the 360–680 nm region |
| title_full |
Photodissociation and photochemistry of V⁺ (H₂O)n, n = 1–4, in the 360–680 nm region |
| title_fullStr |
Photodissociation and photochemistry of V⁺ (H₂O)n, n = 1–4, in the 360–680 nm region |
| title_full_unstemmed |
Photodissociation and photochemistry of V⁺ (H₂O)n, n = 1–4, in the 360–680 nm region |
| title_sort |
photodissociation and photochemistry of v⁺ (h₂o)n, n = 1–4, in the 360–680 nm region |
| publisher |
Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України |
| publishDate |
2012 |
| topic_facet |
Low Temperature Spectroscopy and Radiation Effects |
| url |
http://dspace.nbuv.gov.ua/handle/123456789/117423 |
| citation_txt |
Photodissociation and photochemistry of V⁺ (H₂O)n, n = 1–4, in the 360–680 nm region / B. Scharfschwerdt, C. van der Linde, O.P. Balaj,
I. Herber, D. Schütze, M.K. Beyer // Физика низких температур. — 2012. — Т. 38, № 8. — С. 905-911 . — Бібліогр.: 47 назв. — англ. |
| series |
Физика низких температур |
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2023-10-18T20:29:45Z |
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