The radiation-induced chemistry in solid xenon matrices
The paper presents an overview of recent studies on the radiation-chemical transformations of guest molecules in solid xenon induced by fast electrons and x-ray irradiation. Specific features of the experimental approach based on combination of matrix isolation IR and EPR spectroscopy are briefly...
Збережено в:
| Дата: | 2012 |
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| Автори: | , , , |
| Формат: | Стаття |
| Мова: | English |
| Опубліковано: |
Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України
2012
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| Назва видання: | Физика низких температур |
| Теми: | |
| Онлайн доступ: | http://dspace.nbuv.gov.ua/handle/123456789/117432 |
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| Назва журналу: | Digital Library of Periodicals of National Academy of Sciences of Ukraine |
| Цитувати: | The radiation-induced chemistry in solid xenon matrices / V.I. Feldman, A.V. Kobzarenko, A.Y. Orlov, F.F. Sukhov // Физика низких температур. — 2012. — Т. 38, № 8. — С. 961-969. — Бібліогр.: 63 назв. — англ. |
Репозиторії
Digital Library of Periodicals of National Academy of Sciences of Ukraine| Резюме: | The paper presents an overview of recent studies on the radiation-chemical transformations of guest molecules
in solid xenon induced by fast electrons and x-ray irradiation. Specific features of the experimental approach
based on combination of matrix isolation IR and EPR spectroscopy are briefly outlined (with particular
impact on using monoisotopic and isotopically enriched xenon matrices). The results reveal rich and diverse radiation-induced
chemistry in solid xenon, which is considered in the following major aspects: (1) matrix-induced
and matrix assisted transformations of the primary guest radical cations; (2) production and dynamics of hydrogen
atoms; (3) formation of xenon hydrides. Finally, preliminary results on the radiation-induced generation of
oxygen atoms and ions in solid xenon are presented. |
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