Thin-film heterostructures based on conducting polymers and organic semiconductors

We have carried out the experimental verification of a possibility to produce organic heterostructures by using films of organic semiconductors (OS) which are photosensitive in a wide spectral region, absorb light, and generate charge carriers in the region of transparency of films of conducting...

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Дата:2009
Автори: Vertsimakha, Ya.I., Aksimentyeva, O.I., Perminov, R.J., Poliovyi, D.O.
Формат: Стаття
Мова:English
Опубліковано: Інститут фізики напівпровідників імені В.Є. Лашкарьова НАН України 2009
Назва видання:Semiconductor Physics Quantum Electronics & Optoelectronics
Онлайн доступ:http://dspace.nbuv.gov.ua/handle/123456789/118865
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Назва журналу:Digital Library of Periodicals of National Academy of Sciences of Ukraine
Цитувати:Thin-film heterostructures based on conducting polymers and organic semiconductors / Ya.I. Vertsimakha, O.I. Aksimentyeva, R.J. Perminov, D.O. Poliovyi // Semiconductor Physics Quantum Electronics & Optoelectronics. — 2009. — Т. 12, № 3. — С. 218-223. — Бібліогр.: 9 назв. — англ.

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Digital Library of Periodicals of National Academy of Sciences of Ukraine
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spelling irk-123456789-1188652017-06-01T03:04:27Z Thin-film heterostructures based on conducting polymers and organic semiconductors Vertsimakha, Ya.I. Aksimentyeva, O.I. Perminov, R.J. Poliovyi, D.O. We have carried out the experimental verification of a possibility to produce organic heterostructures by using films of organic semiconductors (OS) which are photosensitive in a wide spectral region, absorb light, and generate charge carriers in the region of transparency of films of conducting polymers – electrochemically synthesized polyaniline (PAN) and poly-3,4-ethylenedioxythiophene (PEDOT) stabilized by polystyrenesulfone acid (PSS). As components for the fabrication of these heterostuctures, we chose photosensitive organic semiconductors of the n-type, N,N`- dimethyl-3,4,9,10-perylenetetracarboxydiimide (МРР), and of the р-type, pentacene (Pn), which were thermally sprayed on thin layers of PAN and PEDOT. The photovoltage of heterostuctures produced at the temperature of substrates 370 K is several times greater than that of components, reaches its maximum in the region of strong light absorption in OS layers, but is one order less in the region of strong absorption in polymers. This testifies to the appearance of an internal electric field near the polymer/OS boundary which enhances the efficiency of separation of photogenerated charge carriers, whereas the efficiency inherent to photogeneration of carriers in the layers with PAN and PEDOT-PSS is insufficient yet. 2009 Article Thin-film heterostructures based on conducting polymers and organic semiconductors / Ya.I. Vertsimakha, O.I. Aksimentyeva, R.J. Perminov, D.O. Poliovyi // Semiconductor Physics Quantum Electronics & Optoelectronics. — 2009. — Т. 12, № 3. — С. 218-223. — Бібліогр.: 9 назв. — англ. 1560-8034 PACS 72.80.Le, 73.50.Pz http://dspace.nbuv.gov.ua/handle/123456789/118865 en Semiconductor Physics Quantum Electronics & Optoelectronics Інститут фізики напівпровідників імені В.Є. Лашкарьова НАН України
institution Digital Library of Periodicals of National Academy of Sciences of Ukraine
collection DSpace DC
language English
description We have carried out the experimental verification of a possibility to produce organic heterostructures by using films of organic semiconductors (OS) which are photosensitive in a wide spectral region, absorb light, and generate charge carriers in the region of transparency of films of conducting polymers – electrochemically synthesized polyaniline (PAN) and poly-3,4-ethylenedioxythiophene (PEDOT) stabilized by polystyrenesulfone acid (PSS). As components for the fabrication of these heterostuctures, we chose photosensitive organic semiconductors of the n-type, N,N`- dimethyl-3,4,9,10-perylenetetracarboxydiimide (МРР), and of the р-type, pentacene (Pn), which were thermally sprayed on thin layers of PAN and PEDOT. The photovoltage of heterostuctures produced at the temperature of substrates 370 K is several times greater than that of components, reaches its maximum in the region of strong light absorption in OS layers, but is one order less in the region of strong absorption in polymers. This testifies to the appearance of an internal electric field near the polymer/OS boundary which enhances the efficiency of separation of photogenerated charge carriers, whereas the efficiency inherent to photogeneration of carriers in the layers with PAN and PEDOT-PSS is insufficient yet.
format Article
author Vertsimakha, Ya.I.
Aksimentyeva, O.I.
Perminov, R.J.
Poliovyi, D.O.
spellingShingle Vertsimakha, Ya.I.
Aksimentyeva, O.I.
Perminov, R.J.
Poliovyi, D.O.
Thin-film heterostructures based on conducting polymers and organic semiconductors
Semiconductor Physics Quantum Electronics & Optoelectronics
author_facet Vertsimakha, Ya.I.
Aksimentyeva, O.I.
Perminov, R.J.
Poliovyi, D.O.
author_sort Vertsimakha, Ya.I.
title Thin-film heterostructures based on conducting polymers and organic semiconductors
title_short Thin-film heterostructures based on conducting polymers and organic semiconductors
title_full Thin-film heterostructures based on conducting polymers and organic semiconductors
title_fullStr Thin-film heterostructures based on conducting polymers and organic semiconductors
title_full_unstemmed Thin-film heterostructures based on conducting polymers and organic semiconductors
title_sort thin-film heterostructures based on conducting polymers and organic semiconductors
publisher Інститут фізики напівпровідників імені В.Є. Лашкарьова НАН України
publishDate 2009
url http://dspace.nbuv.gov.ua/handle/123456789/118865
citation_txt Thin-film heterostructures based on conducting polymers and organic semiconductors / Ya.I. Vertsimakha, O.I. Aksimentyeva, R.J. Perminov, D.O. Poliovyi // Semiconductor Physics Quantum Electronics & Optoelectronics. — 2009. — Т. 12, № 3. — С. 218-223. — Бібліогр.: 9 назв. — англ.
series Semiconductor Physics Quantum Electronics & Optoelectronics
work_keys_str_mv AT vertsimakhayai thinfilmheterostructuresbasedonconductingpolymersandorganicsemiconductors
AT aksimentyevaoi thinfilmheterostructuresbasedonconductingpolymersandorganicsemiconductors
AT perminovrj thinfilmheterostructuresbasedonconductingpolymersandorganicsemiconductors
AT poliovyido thinfilmheterostructuresbasedonconductingpolymersandorganicsemiconductors
first_indexed 2023-10-18T20:33:11Z
last_indexed 2023-10-18T20:33:11Z
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