Liquid-gas phase behavior of Stockmayer fluid with high dipolar moment

A multi-density version of the thermodynamic perturbation theory for associative fluids with central force associative potential is developed. The theory is used to describe the liquid-gas phase behavior of Stochmayer fluid with different values of the dipole moment ranging from low to high. Resul...

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Бібліографічні деталі
Дата:2007
Автори: Kalyuzhnyi, Yu.V., Protsykevitch, I.A., Cummings, P.T.
Формат: Стаття
Мова:English
Опубліковано: Інститут фізики конденсованих систем НАН України 2007
Назва видання:Condensed Matter Physics
Онлайн доступ:http://dspace.nbuv.gov.ua/handle/123456789/118900
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Назва журналу:Digital Library of Periodicals of National Academy of Sciences of Ukraine
Цитувати:Liquid-gas phase behavior of Stockmayer fluid with high dipolar moment / Yu.V. Kalyuzhnyi, I.A. Protsykevitch, P.T. Cummings // Condensed Matter Physics. — 2007. — Т. 10, № 4(52). — С. 553-562. — Бібліогр.: 22 назв. — англ.

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Digital Library of Periodicals of National Academy of Sciences of Ukraine
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Резюме:A multi-density version of the thermodynamic perturbation theory for associative fluids with central force associative potential is developed. The theory is used to describe the liquid-gas phase behavior of Stochmayer fluid with different values of the dipole moment ranging from low to high. Results of the theory are in a reasonable agreement with corresponding computer simulation results in a whole range of the dipole moment values studied. Contrary to previous computer simulation findings our calculations predict the occurrence of the liquid-gas phase coexistence for the soft-sphere dipole fluid model.