Liquid-gas phase behavior of Stockmayer fluid with high dipolar moment
A multi-density version of the thermodynamic perturbation theory for associative fluids with central force associative potential is developed. The theory is used to describe the liquid-gas phase behavior of Stochmayer fluid with different values of the dipole moment ranging from low to high. Resul...
Збережено в:
Дата: | 2007 |
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Автори: | , , |
Формат: | Стаття |
Мова: | English |
Опубліковано: |
Інститут фізики конденсованих систем НАН України
2007
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Назва видання: | Condensed Matter Physics |
Онлайн доступ: | http://dspace.nbuv.gov.ua/handle/123456789/118900 |
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Назва журналу: | Digital Library of Periodicals of National Academy of Sciences of Ukraine |
Цитувати: | Liquid-gas phase behavior of Stockmayer fluid with high dipolar moment / Yu.V. Kalyuzhnyi, I.A. Protsykevitch, P.T. Cummings // Condensed Matter Physics. — 2007. — Т. 10, № 4(52). — С. 553-562. — Бібліогр.: 22 назв. — англ. |
Репозиторії
Digital Library of Periodicals of National Academy of Sciences of UkraineРезюме: | A multi-density version of the thermodynamic perturbation theory for associative fluids with central force associative
potential is developed. The theory is used to describe the liquid-gas phase behavior of Stochmayer
fluid with different values of the dipole moment ranging from low to high. Results of the theory are in a reasonable
agreement with corresponding computer simulation results in a whole range of the dipole moment
values studied. Contrary to previous computer simulation findings our calculations predict the occurrence of
the liquid-gas phase coexistence for the soft-sphere dipole fluid model. |
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