Analytical solution of the associative mean spherical approximation for the ion-dipole model
A simple electrolyte in a polar solvent is modelled by a mixture of polar hard spheres and equal diameter charged hard spheres with the possibility of ionic dimerization. The analytical solution of the associative mean spherical approximation (AMSA) for this model is derived to its full extent. E...
Збережено в:
| Дата: | 1998 |
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| Автори: | , |
| Формат: | Стаття |
| Мова: | English |
| Опубліковано: |
Інститут фізики конденсованих систем НАН України
1998
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| Назва видання: | Condensed Matter Physics |
| Онлайн доступ: | http://dspace.nbuv.gov.ua/handle/123456789/118929 |
| Теги: |
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| Назва журналу: | Digital Library of Periodicals of National Academy of Sciences of Ukraine |
| Цитувати: | Analytical solution of the associative mean spherical approximation for the ion-dipole model / M.F. Holovko, V. Kapko // Condensed Matter Physics. — 1998. — Т. 1, № 2(14). — С. 239-255. — Бібліогр.: 44 назв. — англ. |
Репозитарії
Digital Library of Periodicals of National Academy of Sciences of Ukraine| Резюме: | A simple electrolyte in a polar solvent is modelled by a mixture of polar hard
spheres and equal diameter charged hard spheres with the possibility of
ionic dimerization. The analytical solution of the associative mean spherical
approximation (AMSA) for this model is derived to its full extent. Explicit
expressions for pair correlation functions and dielectric constant in terms
of the AMSA are established. Some numerical calculations illustrate the
role of ionic association. |
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