Analytical solution of the associative mean spherical approximation for the ion-dipole model
A simple electrolyte in a polar solvent is modelled by a mixture of polar hard spheres and equal diameter charged hard spheres with the possibility of ionic dimerization. The analytical solution of the associative mean spherical approximation (AMSA) for this model is derived to its full extent. E...
Збережено в:
| Дата: | 1998 |
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| Автори: | , |
| Формат: | Стаття |
| Мова: | English |
| Опубліковано: |
Інститут фізики конденсованих систем НАН України
1998
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| Назва видання: | Condensed Matter Physics |
| Онлайн доступ: | http://dspace.nbuv.gov.ua/handle/123456789/118929 |
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| Назва журналу: | Digital Library of Periodicals of National Academy of Sciences of Ukraine |
| Цитувати: | Analytical solution of the associative mean spherical approximation for the ion-dipole model / M.F. Holovko, V. Kapko // Condensed Matter Physics. — 1998. — Т. 1, № 2(14). — С. 239-255. — Бібліогр.: 44 назв. — англ. |
Репозитарії
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irk-123456789-1189292017-06-02T03:03:25Z Analytical solution of the associative mean spherical approximation for the ion-dipole model Holovko, M.F. Kapko, V. A simple electrolyte in a polar solvent is modelled by a mixture of polar hard spheres and equal diameter charged hard spheres with the possibility of ionic dimerization. The analytical solution of the associative mean spherical approximation (AMSA) for this model is derived to its full extent. Explicit expressions for pair correlation functions and dielectric constant in terms of the AMSA are established. Some numerical calculations illustrate the role of ionic association. Простий електроліт моделюється в полярному розчиннику сумішшю полярних твердих сфер і однакового розміру заряджених твердих сфер із можливою іонною димеризацією. Подано аналітичний розв’язок асоціативного середньо-сферичного наближення для цієї моделі (АССН). Приводяться точні вирази для парних кореляційних функцій і діелектричної константи в термінах АССН. Роль іонної асоціативності ілюструється числовими результатами. 1998 Article Analytical solution of the associative mean spherical approximation for the ion-dipole model / M.F. Holovko, V. Kapko // Condensed Matter Physics. — 1998. — Т. 1, № 2(14). — С. 239-255. — Бібліогр.: 44 назв. — англ. 1607-324X DOI:10.5488/CMP.1.2.239 PACS: 05.20.-y http://dspace.nbuv.gov.ua/handle/123456789/118929 en Condensed Matter Physics Інститут фізики конденсованих систем НАН України |
| institution |
Digital Library of Periodicals of National Academy of Sciences of Ukraine |
| collection |
DSpace DC |
| language |
English |
| description |
A simple electrolyte in a polar solvent is modelled by a mixture of polar hard
spheres and equal diameter charged hard spheres with the possibility of
ionic dimerization. The analytical solution of the associative mean spherical
approximation (AMSA) for this model is derived to its full extent. Explicit
expressions for pair correlation functions and dielectric constant in terms
of the AMSA are established. Some numerical calculations illustrate the
role of ionic association. |
| format |
Article |
| author |
Holovko, M.F. Kapko, V. |
| spellingShingle |
Holovko, M.F. Kapko, V. Analytical solution of the associative mean spherical approximation for the ion-dipole model Condensed Matter Physics |
| author_facet |
Holovko, M.F. Kapko, V. |
| author_sort |
Holovko, M.F. |
| title |
Analytical solution of the associative mean spherical approximation for the ion-dipole model |
| title_short |
Analytical solution of the associative mean spherical approximation for the ion-dipole model |
| title_full |
Analytical solution of the associative mean spherical approximation for the ion-dipole model |
| title_fullStr |
Analytical solution of the associative mean spherical approximation for the ion-dipole model |
| title_full_unstemmed |
Analytical solution of the associative mean spherical approximation for the ion-dipole model |
| title_sort |
analytical solution of the associative mean spherical approximation for the ion-dipole model |
| publisher |
Інститут фізики конденсованих систем НАН України |
| publishDate |
1998 |
| url |
http://dspace.nbuv.gov.ua/handle/123456789/118929 |
| citation_txt |
Analytical solution of the associative mean spherical approximation for the ion-dipole model / M.F. Holovko, V. Kapko // Condensed Matter Physics. — 1998. — Т. 1, № 2(14). — С. 239-255. — Бібліогр.: 44 назв. — англ. |
| series |
Condensed Matter Physics |
| work_keys_str_mv |
AT holovkomf analyticalsolutionoftheassociativemeansphericalapproximationfortheiondipolemodel AT kapkov analyticalsolutionoftheassociativemeansphericalapproximationfortheiondipolemodel |
| first_indexed |
2023-10-18T20:33:20Z |
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2023-10-18T20:33:20Z |
| _version_ |
1796150506686513152 |