Models of the adsorbtion-catalytic centers on transition metals
The models of adsorbo-catalitic centers for transition metals, which use the peculiarities of the electron-orbital structures as insulated and bounded atoms, have been analized. The important role of the unfilled d-orbitals, their orientation, changing of the occupation of d-shalls, and influence...
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| Date: | 1998 |
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| Main Author: | |
| Format: | Article |
| Language: | English |
| Published: |
Інститут фізики конденсованих систем НАН України
1998
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| Series: | Condensed Matter Physics |
| Online Access: | http://dspace.nbuv.gov.ua/handle/123456789/118932 |
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| Journal Title: | Digital Library of Periodicals of National Academy of Sciences of Ukraine |
| Cite this: | Models of the adsorbtion-catalytic centers on transition metals / V.G. Litovchenko // Condensed Matter Physics. — 1998. — Т. 1, № 2(14). — С. 383-388. — Бібліогр.: 8 назв. — англ. |
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Digital Library of Periodicals of National Academy of Sciences of Ukraine| Summary: | The models of adsorbo-catalitic centers for transition metals, which use the
peculiarities of the electron-orbital structures as insulated and bounded
atoms, have been analized. The important role of the unfilled d-orbitals,
their orientation, changing of the occupation of d-shalls, and influence of
the ligands with completely occupied d-orbitals were considered in connection
with the catalytic activity of the transient metals. The new approach for
enhanced catalytic properties, based on the film alloys of catalytic metals,
was proposed. |
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