Effect of L-arginine on the optical properties, crystalline perfection and laser damage threshold of KDP crystals

• Дата: 2015
• Автори: Kostenyukova, E.I., Bezkrovnaya, O.N., Tkachenko, V.F., Kolybaeva, M.I., Sofronov, D.S., Dolzhenkova, E.F., Lopin, A.V., Pritula, I.M.
• Формат: Стаття
• Мова: English
• Опубліковано: НТК «Інститут монокристалів» НАН України 2015
• Назва видання: Functional Materials
• Теми: Characterization and properties
• Онлайн доступ: http://dspace.nbuv.gov.ua/handle/123456789/119373
• Назва журналу: Digital Library of Periodicals of National Academy of Sciences of Ukraine
• Цитувати: Effect of L-arginine on the optical properties, crystalline perfection and laser damage threshold of KDP crystals / E.I. Kostenyukova, O.N. Bezkrovnaya, V.F. Tkachenko, M.I. Kolybaeva, D.S. Sofronov, E.F. Dolzhenkova, A.V. Lopin, I.M. Pritula // Functional Materials. — 2015. — Т. 22, № 3. — С. 309-315. — Бібліогр.: 27 назв. — англ.

Potassium dihydrogen phosphate (KDP) single crystals doped with L-arginine amino acid were grown from aqueous solutions onto a point seed using the temperature reduction method. The incorporation of L-arg molecules into the crystal was verified by the methods of UV-vis-IR and FTIR spectroscopy. It was shown that the entering of L-arg into the matrix was accompanied with the increase of the volume of KDP:L-arg elementary cell by ~ 2·10⁻²Å³ with respect to the one of the pure crystal. There was analyzed the influence of L-arg molecules on the value of laser damage threshold for different growth sectors of KDP crystal. The laser damage threshold of KDP:L-arg crystal was found to rise for the growth sector {101} and to diminish for the growth sector {100} with respect to the corresponding parameter of the pure crystal.