Electrical conductivity of solid solution of Co(II)-Zn dihydrophosphate and its thermolysis products
Dependence of the specific electrical conductivity value of the solid solution with composition Co₁-xZnx(H₂PO₄)₂•H₂O(0 < x < 1.0) and products of its partial or complete dehydration from temperature and duration of heat treatment has been investigated. It has been established that they have co...
Збережено в:
| Видавець: | НТК «Інститут монокристалів» НАН України |
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| Дата: | 2015 |
| Автори: | , , |
| Формат: | Стаття |
| Мова: | English |
| Опубліковано: |
НТК «Інститут монокристалів» НАН України
2015
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| Назва видання: | Functional Materials |
| Теми: | |
| Онлайн доступ: | http://dspace.nbuv.gov.ua/handle/123456789/119376 |
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| Цитувати: | Electrical conductivity of solid solution of Co(II)-Zn dihydrophosphate and its thermolysis products / N.M. Antraptseva, N.V. Solod, V.A. Povshuk // Functional Materials. — 2015. — Т. 22, № 3. — С. 322-326. — Бібліогр.: 8 назв. — англ. |
Репозиторії
Digital Library of Periodicals of National Academy of Sciences of Ukraine| Резюме: | Dependence of the specific electrical conductivity value of the solid solution with composition Co₁-xZnx(H₂PO₄)₂•H₂O(0 < x < 1.0) and products of its partial or complete dehydration from temperature and duration of heat treatment has been investigated. It has been established that they have considerable proton conductivity (from 1.01•10⁻⁰² - 1.18•10⁻² Ohm⁻¹cm⁻¹ to 7.51•10⁻³ - 9.57•10⁻³ Ohm⁻¹cm⁻¹) in a wide temperature range (80-270°C). The main contribution to their proton conductivity has made mobile protons of the phosphate anion P-OH groups and free phosphoric acid protons, which have produced in the intermediate thermolysis products according to PMR and ³¹P NMR spectrum analysis of Co(II)-Zn dihydrophosphates heat treatment products. Contribution of crystal water protons is minimal. |
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