Electroconductivity of anion-radical TCNQ salts containing cations [M(bipy)₃]²⁺ (M-Fe, Ni or Zn)
Electrical resistance temperature dependence of three TCNQ anion-radical salts of complex composition containing cations [M||(bipy)₃]²⁺ (M-Fe, Ni or Zn, bipy - 2,2′-dipyridil) have been studied. Measurements have been performed in the range 180-300 K on tableted samples. The compound exhibit semico...
Збережено в:
Дата: | 2015 |
---|---|
Автори: | , , , , , , |
Формат: | Стаття |
Мова: | English |
Опубліковано: |
НТК «Інститут монокристалів» НАН України
2015
|
Назва видання: | Functional Materials |
Теми: | |
Онлайн доступ: | http://dspace.nbuv.gov.ua/handle/123456789/119379 |
Теги: |
Додати тег
Немає тегів, Будьте першим, хто поставить тег для цього запису!
|
Назва журналу: | Digital Library of Periodicals of National Academy of Sciences of Ukraine |
Цитувати: | Electroconductivity of anion-radical TCNQ salts containing cations [M(bipy)₃]²⁺ (M-Fe, Ni or Zn) / G.Y. Vasylets, A.V. Khotkevich, A.S. Bukrinev, A.S. Krasnyi, V.A. Starodub, A.A. Kravchenko, V.V. Medviediev // Functional Materials. — 2015. — Т. 22, № 3. — С. 338-341. — Бібліогр.: 14 назв. — англ. |
Репозитарії
Digital Library of Periodicals of National Academy of Sciences of Ukraineid |
irk-123456789-119379 |
---|---|
record_format |
dspace |
spelling |
irk-123456789-1193792017-06-07T03:04:37Z Electroconductivity of anion-radical TCNQ salts containing cations [M(bipy)₃]²⁺ (M-Fe, Ni or Zn) Vasylets, G.Y. Khotkevich, A.V. Bukrinev, A.S. Krasnyi, A.S. Starodub, V.A. Starodub, V.A. Kravchenko, A.A. Medviediev, V.V. Characterization and properties Electrical resistance temperature dependence of three TCNQ anion-radical salts of complex composition containing cations [M||(bipy)₃]²⁺ (M-Fe, Ni or Zn, bipy - 2,2′-dipyridil) have been studied. Measurements have been performed in the range 180-300 K on tableted samples. The compound exhibit semiconducting properties and undergo the Peierls transition. Specific resistance at room temperature is of 7.7 Ω·cm for Fe containing salt and 2.3·10⁻² Ω·cm and 2.5·10⁻² Ω·cm for salts containing Ni and Zn, respectively. 2015 Article Electroconductivity of anion-radical TCNQ salts containing cations [M(bipy)₃]²⁺ (M-Fe, Ni or Zn) / G.Y. Vasylets, A.V. Khotkevich, A.S. Bukrinev, A.S. Krasnyi, V.A. Starodub, A.A. Kravchenko, V.V. Medviediev // Functional Materials. — 2015. — Т. 22, № 3. — С. 338-341. — Бібліогр.: 14 назв. — англ. 1027-5495 DOI: http://dx.doi.org/10.15407/fm22.03.338 http://dspace.nbuv.gov.ua/handle/123456789/119379 en Functional Materials НТК «Інститут монокристалів» НАН України |
institution |
Digital Library of Periodicals of National Academy of Sciences of Ukraine |
collection |
DSpace DC |
language |
English |
topic |
Characterization and properties Characterization and properties |
spellingShingle |
Characterization and properties Characterization and properties Vasylets, G.Y. Khotkevich, A.V. Bukrinev, A.S. Krasnyi, A.S. Starodub, V.A. Starodub, V.A. Kravchenko, A.A. Medviediev, V.V. Electroconductivity of anion-radical TCNQ salts containing cations [M(bipy)₃]²⁺ (M-Fe, Ni or Zn) Functional Materials |
description |
Electrical resistance temperature dependence of three TCNQ anion-radical salts of complex composition containing cations [M||(bipy)₃]²⁺ (M-Fe, Ni or Zn, bipy - 2,2′-dipyridil) have been studied. Measurements have been performed in the range 180-300 K on tableted samples. The compound exhibit semiconducting properties and undergo the Peierls transition. Specific resistance at room temperature is of 7.7 Ω·cm for Fe containing salt and 2.3·10⁻² Ω·cm and 2.5·10⁻² Ω·cm for salts containing Ni and Zn, respectively. |
format |
Article |
author |
Vasylets, G.Y. Khotkevich, A.V. Bukrinev, A.S. Krasnyi, A.S. Starodub, V.A. Starodub, V.A. Kravchenko, A.A. Medviediev, V.V. |
author_facet |
Vasylets, G.Y. Khotkevich, A.V. Bukrinev, A.S. Krasnyi, A.S. Starodub, V.A. Starodub, V.A. Kravchenko, A.A. Medviediev, V.V. |
author_sort |
Vasylets, G.Y. |
title |
Electroconductivity of anion-radical TCNQ salts containing cations [M(bipy)₃]²⁺ (M-Fe, Ni or Zn) |
title_short |
Electroconductivity of anion-radical TCNQ salts containing cations [M(bipy)₃]²⁺ (M-Fe, Ni or Zn) |
title_full |
Electroconductivity of anion-radical TCNQ salts containing cations [M(bipy)₃]²⁺ (M-Fe, Ni or Zn) |
title_fullStr |
Electroconductivity of anion-radical TCNQ salts containing cations [M(bipy)₃]²⁺ (M-Fe, Ni or Zn) |
title_full_unstemmed |
Electroconductivity of anion-radical TCNQ salts containing cations [M(bipy)₃]²⁺ (M-Fe, Ni or Zn) |
title_sort |
electroconductivity of anion-radical tcnq salts containing cations [m(bipy)₃]²⁺ (m-fe, ni or zn) |
publisher |
НТК «Інститут монокристалів» НАН України |
publishDate |
2015 |
topic_facet |
Characterization and properties |
url |
http://dspace.nbuv.gov.ua/handle/123456789/119379 |
citation_txt |
Electroconductivity of anion-radical TCNQ salts containing cations [M(bipy)₃]²⁺ (M-Fe, Ni or Zn) / G.Y. Vasylets, A.V. Khotkevich, A.S. Bukrinev, A.S. Krasnyi, V.A. Starodub, A.A. Kravchenko, V.V. Medviediev // Functional Materials. — 2015. — Т. 22, № 3. — С. 338-341. — Бібліогр.: 14 назв. — англ. |
series |
Functional Materials |
work_keys_str_mv |
AT vasyletsgy electroconductivityofanionradicaltcnqsaltscontainingcationsmbipy32mfeniorzn AT khotkevichav electroconductivityofanionradicaltcnqsaltscontainingcationsmbipy32mfeniorzn AT bukrinevas electroconductivityofanionradicaltcnqsaltscontainingcationsmbipy32mfeniorzn AT krasnyias electroconductivityofanionradicaltcnqsaltscontainingcationsmbipy32mfeniorzn AT starodubva electroconductivityofanionradicaltcnqsaltscontainingcationsmbipy32mfeniorzn AT starodubva electroconductivityofanionradicaltcnqsaltscontainingcationsmbipy32mfeniorzn AT kravchenkoaa electroconductivityofanionradicaltcnqsaltscontainingcationsmbipy32mfeniorzn AT medviedievvv electroconductivityofanionradicaltcnqsaltscontainingcationsmbipy32mfeniorzn |
first_indexed |
2023-10-18T20:34:25Z |
last_indexed |
2023-10-18T20:34:25Z |
_version_ |
1796150554027622400 |