Phase transitions in the nanopowders KTa₀.₅Nb₀.₅O₃ studied by Raman spectroscopy
Raman spectra of KTa₀.₅Nb₀.₅O₃ nanopowder solid solution were obtained at the temperatures from –190°C to 600°C and investigated for the first time. The compound was synthesized by a new technology. Temperature dependences of the intensity, width and frequency of the B₁(TO₂), A₁(TO₁), B₁(TO₃), A₁(TO...
Збережено в:
| Дата: | 2013 |
|---|---|
| Автори: | , , , |
| Формат: | Стаття |
| Мова: | English |
| Опубліковано: |
НТК «Інститут монокристалів» НАН України
2013
|
| Назва видання: | Functional Materials |
| Теми: | |
| Онлайн доступ: | http://dspace.nbuv.gov.ua/handle/123456789/119908 |
| Теги: |
Додати тег
Немає тегів, Будьте першим, хто поставить тег для цього запису!
|
| Назва журналу: | Digital Library of Periodicals of National Academy of Sciences of Ukraine |
| Цитувати: | Phase transitions in the nanopowders KTa₀.₅Nb₀.₅O₃ studied by Raman spectroscopy / I.S. Golovina, V.P. Bryksa, V.V. Strelchuk, I.N. Geifman // Functional Materials. — 2013. — Т. 20, № 1. — С. 75-80. — Бібліогр.: 20 назв. — англ. |
Репозитарії
Digital Library of Periodicals of National Academy of Sciences of Ukraine| id |
irk-123456789-119908 |
|---|---|
| record_format |
dspace |
| spelling |
irk-123456789-1199082017-06-11T03:03:04Z Phase transitions in the nanopowders KTa₀.₅Nb₀.₅O₃ studied by Raman spectroscopy Golovina, I.S. Bryksa, V.P. Strelchuk, V.V. Geifman, I.N. Characterization and properties Raman spectra of KTa₀.₅Nb₀.₅O₃ nanopowder solid solution were obtained at the temperatures from –190°C to 600°C and investigated for the first time. The compound was synthesized by a new technology. Temperature dependences of the intensity, width and frequency of the B₁(TO₂), A₁(TO₁), B₁(TO₃), A₁(TO₃) and B₂(TO₃) modes are thoroughly analyzed. A significant expanding of the temperature ranges of all phase transitions, correlated with a spread of particle sizes is registered. It was found that an average temperature of each of the phase transitions is shifted in different way, in particular: a low-temperature transition at 30 degrees higher, the middle transition at 10 degrees higher, and the ferroelectric phase transition occurs at 20 degrees lower than the temperature of the corresponding transitions in single-crystal KTa₀.₅Nb₀.₅O₃. 2013 Article Phase transitions in the nanopowders KTa₀.₅Nb₀.₅O₃ studied by Raman spectroscopy / I.S. Golovina, V.P. Bryksa, V.V. Strelchuk, I.N. Geifman // Functional Materials. — 2013. — Т. 20, № 1. — С. 75-80. — Бібліогр.: 20 назв. — англ. 1027-5495 DOI: dx.doi.org/10.15407/fm20.01.075 http://dspace.nbuv.gov.ua/handle/123456789/119908 en Functional Materials НТК «Інститут монокристалів» НАН України |
| institution |
Digital Library of Periodicals of National Academy of Sciences of Ukraine |
| collection |
DSpace DC |
| language |
English |
| topic |
Characterization and properties Characterization and properties |
| spellingShingle |
Characterization and properties Characterization and properties Golovina, I.S. Bryksa, V.P. Strelchuk, V.V. Geifman, I.N. Phase transitions in the nanopowders KTa₀.₅Nb₀.₅O₃ studied by Raman spectroscopy Functional Materials |
| description |
Raman spectra of KTa₀.₅Nb₀.₅O₃ nanopowder solid solution were obtained at the temperatures from –190°C to 600°C and investigated for the first time. The compound was synthesized by a new technology. Temperature dependences of the intensity, width and frequency of the B₁(TO₂), A₁(TO₁), B₁(TO₃), A₁(TO₃) and B₂(TO₃) modes are thoroughly analyzed. A significant expanding of the temperature ranges of all phase transitions, correlated with a spread of particle sizes is registered. It was found that an average temperature of each of the phase transitions is shifted in different way, in particular: a low-temperature transition at 30 degrees higher, the middle transition at 10 degrees higher, and the ferroelectric phase transition occurs at 20 degrees lower than the temperature of the corresponding transitions in single-crystal KTa₀.₅Nb₀.₅O₃. |
| format |
Article |
| author |
Golovina, I.S. Bryksa, V.P. Strelchuk, V.V. Geifman, I.N. |
| author_facet |
Golovina, I.S. Bryksa, V.P. Strelchuk, V.V. Geifman, I.N. |
| author_sort |
Golovina, I.S. |
| title |
Phase transitions in the nanopowders KTa₀.₅Nb₀.₅O₃ studied by Raman spectroscopy |
| title_short |
Phase transitions in the nanopowders KTa₀.₅Nb₀.₅O₃ studied by Raman spectroscopy |
| title_full |
Phase transitions in the nanopowders KTa₀.₅Nb₀.₅O₃ studied by Raman spectroscopy |
| title_fullStr |
Phase transitions in the nanopowders KTa₀.₅Nb₀.₅O₃ studied by Raman spectroscopy |
| title_full_unstemmed |
Phase transitions in the nanopowders KTa₀.₅Nb₀.₅O₃ studied by Raman spectroscopy |
| title_sort |
phase transitions in the nanopowders kta₀.₅nb₀.₅o₃ studied by raman spectroscopy |
| publisher |
НТК «Інститут монокристалів» НАН України |
| publishDate |
2013 |
| topic_facet |
Characterization and properties |
| url |
http://dspace.nbuv.gov.ua/handle/123456789/119908 |
| citation_txt |
Phase transitions in the nanopowders KTa₀.₅Nb₀.₅O₃ studied by Raman spectroscopy / I.S. Golovina, V.P. Bryksa, V.V. Strelchuk, I.N. Geifman // Functional Materials. — 2013. — Т. 20, № 1. — С. 75-80. — Бібліогр.: 20 назв. — англ. |
| series |
Functional Materials |
| work_keys_str_mv |
AT golovinais phasetransitionsinthenanopowderskta05nb05o3studiedbyramanspectroscopy AT bryksavp phasetransitionsinthenanopowderskta05nb05o3studiedbyramanspectroscopy AT strelchukvv phasetransitionsinthenanopowderskta05nb05o3studiedbyramanspectroscopy AT geifmanin phasetransitionsinthenanopowderskta05nb05o3studiedbyramanspectroscopy |
| first_indexed |
2023-10-18T20:35:44Z |
| last_indexed |
2023-10-18T20:35:44Z |
| _version_ |
1796150610664357888 |