Quantum mechanic tunneling and efficiency of Faraday current-generating process in porous nanostructures
Thermodynamics and kinetics of lithium intercalation into C-SiO₂ nanocomposites are investigated. Dependencies of both differential capacity and intercalation kinetics on the nanocomposite size are established. The processes are analyzed in terms of the impedance model. The obtained results are expl...
Збережено в:
| Дата: | 2011 |
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| Автори: | , , |
| Формат: | Стаття |
| Мова: | English |
| Опубліковано: |
Інститут фізики конденсованих систем НАН України
2011
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| Назва видання: | Condensed Matter Physics |
| Онлайн доступ: | http://dspace.nbuv.gov.ua/handle/123456789/120005 |
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| Назва журналу: | Digital Library of Periodicals of National Academy of Sciences of Ukraine |
| Цитувати: | Quantum mechanic tunneling and efficiency of Faraday current-generating process in porous nanostructures / B.A. Lukiyanets, D.V. Matulka, I.I. Grygorchak // Condensed Matter Physics. — 2011. — Т. 14, № 2. — С. 23705:1-12. — Бібліогр.: 17 назв. — англ. |
Репозитарії
Digital Library of Periodicals of National Academy of Sciences of Ukraine| Резюме: | Thermodynamics and kinetics of lithium intercalation into C-SiO₂ nanocomposites are investigated. Dependencies of both differential capacity and intercalation kinetics on the nanocomposite size are established. The processes are analyzed in terms of the impedance model. The obtained results are explained based on the quantum effect of interference blockade of electron tunneling into a nonmetallic nanoparticle. Propositions for the new electrochemical energy storage technology are presented. |
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