Quantum mechanic tunneling and efficiency of Faraday current-generating process in porous nanostructures
Thermodynamics and kinetics of lithium intercalation into C-SiO₂ nanocomposites are investigated. Dependencies of both differential capacity and intercalation kinetics on the nanocomposite size are established. The processes are analyzed in terms of the impedance model. The obtained results are expl...
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| Дата: | 2011 |
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| Автори: | , , |
| Формат: | Стаття |
| Мова: | English |
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Інститут фізики конденсованих систем НАН України
2011
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| Назва видання: | Condensed Matter Physics |
| Онлайн доступ: | http://dspace.nbuv.gov.ua/handle/123456789/120005 |
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| Назва журналу: | Digital Library of Periodicals of National Academy of Sciences of Ukraine |
| Цитувати: | Quantum mechanic tunneling and efficiency of Faraday current-generating process in porous nanostructures / B.A. Lukiyanets, D.V. Matulka, I.I. Grygorchak // Condensed Matter Physics. — 2011. — Т. 14, № 2. — С. 23705:1-12. — Бібліогр.: 17 назв. — англ. |
Репозитарії
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irk-123456789-1200052017-06-11T03:04:50Z Quantum mechanic tunneling and efficiency of Faraday current-generating process in porous nanostructures Lukiyanets, B.A. Matulka, D.V. Grygorchak, I.I. Thermodynamics and kinetics of lithium intercalation into C-SiO₂ nanocomposites are investigated. Dependencies of both differential capacity and intercalation kinetics on the nanocomposite size are established. The processes are analyzed in terms of the impedance model. The obtained results are explained based on the quantum effect of interference blockade of electron tunneling into a nonmetallic nanoparticle. Propositions for the new electrochemical energy storage technology are presented. В роботi дослiджено термодинамiчнi та кiнетичнi закономiрностi процесу лiтiєвої iнтеркаляцiї C-SiO₂ нанокомпозитiв. Встановлена залежнiсть як для диференцiйної ємностi, такi для кiнетичних параметрiв процесу вiд розмiрiв нанокомпозитiв. Згiдно з результатами теоретичного аналiзу, отриманi залежностi є наслiдком квантово-механiчного ефекту iнтерференцiйної блокади електронного тунелювання в неметалiчну наночастинку. Наведена iмпедансна модель процесiв та параметрична iдентифiкацiя. Представлена нова технологiя електрохiмiчних генераторiв енергiї. 2011 Article Quantum mechanic tunneling and efficiency of Faraday current-generating process in porous nanostructures / B.A. Lukiyanets, D.V. Matulka, I.I. Grygorchak // Condensed Matter Physics. — 2011. — Т. 14, № 2. — С. 23705:1-12. — Бібліогр.: 17 назв. — англ. 1607-324X PACS: 71.20, 71.24, 73.40, 73.63 DOI:10.5488/CMP.14.23705 arXiv:1106.5142 http://dspace.nbuv.gov.ua/handle/123456789/120005 en Condensed Matter Physics Інститут фізики конденсованих систем НАН України |
| institution |
Digital Library of Periodicals of National Academy of Sciences of Ukraine |
| collection |
DSpace DC |
| language |
English |
| description |
Thermodynamics and kinetics of lithium intercalation into C-SiO₂ nanocomposites are investigated. Dependencies of both differential capacity and intercalation kinetics on the nanocomposite size are established. The processes are analyzed in terms of the impedance model. The obtained results are explained based on the quantum effect of interference blockade of electron tunneling into a nonmetallic nanoparticle. Propositions for the new electrochemical energy storage technology are presented. |
| format |
Article |
| author |
Lukiyanets, B.A. Matulka, D.V. Grygorchak, I.I. |
| spellingShingle |
Lukiyanets, B.A. Matulka, D.V. Grygorchak, I.I. Quantum mechanic tunneling and efficiency of Faraday current-generating process in porous nanostructures Condensed Matter Physics |
| author_facet |
Lukiyanets, B.A. Matulka, D.V. Grygorchak, I.I. |
| author_sort |
Lukiyanets, B.A. |
| title |
Quantum mechanic tunneling and efficiency of Faraday current-generating process in porous nanostructures |
| title_short |
Quantum mechanic tunneling and efficiency of Faraday current-generating process in porous nanostructures |
| title_full |
Quantum mechanic tunneling and efficiency of Faraday current-generating process in porous nanostructures |
| title_fullStr |
Quantum mechanic tunneling and efficiency of Faraday current-generating process in porous nanostructures |
| title_full_unstemmed |
Quantum mechanic tunneling and efficiency of Faraday current-generating process in porous nanostructures |
| title_sort |
quantum mechanic tunneling and efficiency of faraday current-generating process in porous nanostructures |
| publisher |
Інститут фізики конденсованих систем НАН України |
| publishDate |
2011 |
| url |
http://dspace.nbuv.gov.ua/handle/123456789/120005 |
| citation_txt |
Quantum mechanic tunneling and efficiency of Faraday current-generating process in porous nanostructures / B.A. Lukiyanets, D.V. Matulka, I.I. Grygorchak // Condensed Matter Physics. — 2011. — Т. 14, № 2. — С. 23705:1-12. — Бібліогр.: 17 назв. — англ. |
| series |
Condensed Matter Physics |
| work_keys_str_mv |
AT lukiyanetsba quantummechanictunnelingandefficiencyoffaradaycurrentgeneratingprocessinporousnanostructures AT matulkadv quantummechanictunnelingandefficiencyoffaradaycurrentgeneratingprocessinporousnanostructures AT grygorchakii quantummechanictunnelingandefficiencyoffaradaycurrentgeneratingprocessinporousnanostructures |
| first_indexed |
2023-10-18T20:36:00Z |
| last_indexed |
2023-10-18T20:36:00Z |
| _version_ |
1796150620646801408 |