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Time-resolved luminescence spectroscopy study of CsI:Eu crystal

This paper studies the spectral-kinetic properties of CsI:0.8·10⁻⁴ % Eu, CsI:1·10⁻² % Eu and CsI:3.9·10⁻¹ % Eu crystals. It has been found that spectrum and decay kinetics of photoluminescence depend on concentration of an activator and degree of thermal-dynamic disbalance of CsI:Eu. The emission of...

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Main Authors: Yakovlev, V., Trefilova, L., Karnaukhova, A., Ovcharenko, N., Kisilc, E.
Format: Article
Language:English
Published: НТК «Інститут монокристалів» НАН України 2013
Series:Functional Materials
Subjects:
Online Access:http://dspace.nbuv.gov.ua/handle/123456789/120109
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spelling irk-123456789-1201092017-06-12T03:02:58Z Time-resolved luminescence spectroscopy study of CsI:Eu crystal Yakovlev, V. Trefilova, L. Karnaukhova, A. Ovcharenko, N. Kisilc, E. Characterization and properties This paper studies the spectral-kinetic properties of CsI:0.8·10⁻⁴ % Eu, CsI:1·10⁻² % Eu and CsI:3.9·10⁻¹ % Eu crystals. It has been found that spectrum and decay kinetics of photoluminescence depend on concentration of an activator and degree of thermal-dynamic disbalance of CsI:Eu. The emission of all the crystals decays exponentially, but each crystal differs from each other in temperature behavior of the emission decay kinetics. Possible types of the emission centers have been suggested such as single dipole Eu²⁺–vc, two- and three-dipole clusters of Eu²⁺–vc– which are responsible for the bands with maxima at 2.69, 2.78 and 2.67 eV, respectively. Criterion for discrimination of the emission centers in CsI:Eu is the temperature behavior of their emission decay kinetics. 2013 Article Time-resolved luminescence spectroscopy study of CsI:Eu crystal / V. Yakovlev, L. Trefilova, A. Karnaukhova, N. Ovcharenko, E. Kisilc // Functional Materials. — 2013. — Т. 20, № 4. — С. 451-456. — Бібліогр.: 12 назв. — англ. 1027-5495 DOI: dx.doi.org/10.15407/fm20.04.451 http://dspace.nbuv.gov.ua/handle/123456789/120109 en Functional Materials НТК «Інститут монокристалів» НАН України
institution Digital Library of Periodicals of National Academy of Sciences of Ukraine
collection DSpace DC
language English
topic Characterization and properties
Characterization and properties
spellingShingle Characterization and properties
Characterization and properties
Yakovlev, V.
Trefilova, L.
Karnaukhova, A.
Ovcharenko, N.
Kisilc, E.
Time-resolved luminescence spectroscopy study of CsI:Eu crystal
Functional Materials
description This paper studies the spectral-kinetic properties of CsI:0.8·10⁻⁴ % Eu, CsI:1·10⁻² % Eu and CsI:3.9·10⁻¹ % Eu crystals. It has been found that spectrum and decay kinetics of photoluminescence depend on concentration of an activator and degree of thermal-dynamic disbalance of CsI:Eu. The emission of all the crystals decays exponentially, but each crystal differs from each other in temperature behavior of the emission decay kinetics. Possible types of the emission centers have been suggested such as single dipole Eu²⁺–vc, two- and three-dipole clusters of Eu²⁺–vc– which are responsible for the bands with maxima at 2.69, 2.78 and 2.67 eV, respectively. Criterion for discrimination of the emission centers in CsI:Eu is the temperature behavior of their emission decay kinetics.
format Article
author Yakovlev, V.
Trefilova, L.
Karnaukhova, A.
Ovcharenko, N.
Kisilc, E.
author_facet Yakovlev, V.
Trefilova, L.
Karnaukhova, A.
Ovcharenko, N.
Kisilc, E.
author_sort Yakovlev, V.
title Time-resolved luminescence spectroscopy study of CsI:Eu crystal
title_short Time-resolved luminescence spectroscopy study of CsI:Eu crystal
title_full Time-resolved luminescence spectroscopy study of CsI:Eu crystal
title_fullStr Time-resolved luminescence spectroscopy study of CsI:Eu crystal
title_full_unstemmed Time-resolved luminescence spectroscopy study of CsI:Eu crystal
title_sort time-resolved luminescence spectroscopy study of csi:eu crystal
publisher НТК «Інститут монокристалів» НАН України
publishDate 2013
topic_facet Characterization and properties
url http://dspace.nbuv.gov.ua/handle/123456789/120109
citation_txt Time-resolved luminescence spectroscopy study of CsI:Eu crystal / V. Yakovlev, L. Trefilova, A. Karnaukhova, N. Ovcharenko, E. Kisilc // Functional Materials. — 2013. — Т. 20, № 4. — С. 451-456. — Бібліогр.: 12 назв. — англ.
series Functional Materials
work_keys_str_mv AT yakovlevv timeresolvedluminescencespectroscopystudyofcsieucrystal
AT trefiloval timeresolvedluminescencespectroscopystudyofcsieucrystal
AT karnaukhovaa timeresolvedluminescencespectroscopystudyofcsieucrystal
AT ovcharenkon timeresolvedluminescencespectroscopystudyofcsieucrystal
AT kisilce timeresolvedluminescencespectroscopystudyofcsieucrystal
first_indexed 2023-10-18T20:36:14Z
last_indexed 2023-10-18T20:36:14Z
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