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Adsorbate-induced distortion of solid surfaces. Application to HCl on ice at stratospheric conditions
It is shown that the adsorption of HCl molecules at the surface of ice increases, if the HCl binding energy increases with the distortion amplitude of the oxygen sites of ice. At the same time, the adsorption stimulates an increase of the Lindemann parameter for the ice lattice, driving its melti...
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Main Authors: | , , |
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Format: | Article |
Language: | English |
Published: |
Інститут фізики конденсованих систем НАН України
2001
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Series: | Condensed Matter Physics |
Online Access: | http://dspace.nbuv.gov.ua/handle/123456789/120400 |
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Summary: | It is shown that the adsorption of HCl molecules at the surface of ice increases,
if the HCl binding energy increases with the distortion amplitude
of the oxygen sites of ice. At the same time, the adsorption stimulates an increase
of the Lindemann parameter for the ice lattice, driving its melting at
temperatures (T = 190 K) relevant to the polar stratosphere. Similar effects
take place when the lateral interaction between HCl molecules becomes
more attractive due to the coupling through the ice lattice. |
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