Adsorbate-induced distortion of solid surfaces. Application to HCl on ice at stratospheric conditions
It is shown that the adsorption of HCl molecules at the surface of ice increases, if the HCl binding energy increases with the distortion amplitude of the oxygen sites of ice. At the same time, the adsorption stimulates an increase of the Lindemann parameter for the ice lattice, driving its melti...
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| Дата: | 2001 |
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| Автори: | , , |
| Формат: | Стаття |
| Мова: | English |
| Опубліковано: |
Інститут фізики конденсованих систем НАН України
2001
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| Назва видання: | Condensed Matter Physics |
| Онлайн доступ: | http://dspace.nbuv.gov.ua/handle/123456789/120400 |
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| Назва журналу: | Digital Library of Periodicals of National Academy of Sciences of Ukraine |
| Цитувати: | Adsorbate-induced distortion of solid surfaces. Application to HCl on ice at stratospheric conditions / E.V. Vakarin, M.F. Holovko, J.P. Badiali // Condensed Matter Physics. — 2001. — Т. 4, № 2(26). — С. 251-260. — Бібліогр.: 22 назв. — англ. |
Репозитарії
Digital Library of Periodicals of National Academy of Sciences of Ukraine| id |
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irk-123456789-1204002017-06-13T03:04:44Z Adsorbate-induced distortion of solid surfaces. Application to HCl on ice at stratospheric conditions Vakarin, E.V. Holovko, M.F. Badiali, J.P. It is shown that the adsorption of HCl molecules at the surface of ice increases, if the HCl binding energy increases with the distortion amplitude of the oxygen sites of ice. At the same time, the adsorption stimulates an increase of the Lindemann parameter for the ice lattice, driving its melting at temperatures (T = 190 K) relevant to the polar stratosphere. Similar effects take place when the lateral interaction between HCl molecules becomes more attractive due to the coupling through the ice lattice. Показано, що адсорбція молекул HCl на поверхню льоду зростає, якщо зростає енергія зв’язку молекул HCl при збільшенні амплітуди спотворення кисневих вузлів льоду. В той же час адсорбція стимулює зростання параметра Ліндемана для гратки льоду, приводячи до її плавлення при температурах (T = 190 K), відповідних до полярної стратосфери. Подібні ефекти спостерігаються, коли латеральна взаємодія між молекулами HCl стає більш притягальною внаслідок з’єднання через гратку льоду. 2001 Article Adsorbate-induced distortion of solid surfaces. Application to HCl on ice at stratospheric conditions / E.V. Vakarin, M.F. Holovko, J.P. Badiali // Condensed Matter Physics. — 2001. — Т. 4, № 2(26). — С. 251-260. — Бібліогр.: 22 назв. — англ. 1607-324X PACS: 05.70.Np, 68.45.Da, 92.60.Jq DOI:10.5488/CMP.4.2.251 http://dspace.nbuv.gov.ua/handle/123456789/120400 en Condensed Matter Physics Інститут фізики конденсованих систем НАН України |
| institution |
Digital Library of Periodicals of National Academy of Sciences of Ukraine |
| collection |
DSpace DC |
| language |
English |
| description |
It is shown that the adsorption of HCl molecules at the surface of ice increases,
if the HCl binding energy increases with the distortion amplitude
of the oxygen sites of ice. At the same time, the adsorption stimulates an increase
of the Lindemann parameter for the ice lattice, driving its melting at
temperatures (T = 190 K) relevant to the polar stratosphere. Similar effects
take place when the lateral interaction between HCl molecules becomes
more attractive due to the coupling through the ice lattice. |
| format |
Article |
| author |
Vakarin, E.V. Holovko, M.F. Badiali, J.P. |
| spellingShingle |
Vakarin, E.V. Holovko, M.F. Badiali, J.P. Adsorbate-induced distortion of solid surfaces. Application to HCl on ice at stratospheric conditions Condensed Matter Physics |
| author_facet |
Vakarin, E.V. Holovko, M.F. Badiali, J.P. |
| author_sort |
Vakarin, E.V. |
| title |
Adsorbate-induced distortion of solid surfaces. Application to HCl on ice at stratospheric conditions |
| title_short |
Adsorbate-induced distortion of solid surfaces. Application to HCl on ice at stratospheric conditions |
| title_full |
Adsorbate-induced distortion of solid surfaces. Application to HCl on ice at stratospheric conditions |
| title_fullStr |
Adsorbate-induced distortion of solid surfaces. Application to HCl on ice at stratospheric conditions |
| title_full_unstemmed |
Adsorbate-induced distortion of solid surfaces. Application to HCl on ice at stratospheric conditions |
| title_sort |
adsorbate-induced distortion of solid surfaces. application to hcl on ice at stratospheric conditions |
| publisher |
Інститут фізики конденсованих систем НАН України |
| publishDate |
2001 |
| url |
http://dspace.nbuv.gov.ua/handle/123456789/120400 |
| citation_txt |
Adsorbate-induced distortion of solid
surfaces. Application to HCl on ice at
stratospheric conditions / E.V. Vakarin, M.F. Holovko, J.P. Badiali // Condensed Matter Physics. — 2001. — Т. 4, № 2(26). — С. 251-260. — Бібліогр.: 22 назв. — англ. |
| series |
Condensed Matter Physics |
| work_keys_str_mv |
AT vakarinev adsorbateinduceddistortionofsolidsurfacesapplicationtohcloniceatstratosphericconditions AT holovkomf adsorbateinduceddistortionofsolidsurfacesapplicationtohcloniceatstratosphericconditions AT badialijp adsorbateinduceddistortionofsolidsurfacesapplicationtohcloniceatstratosphericconditions |
| first_indexed |
2023-10-18T20:36:58Z |
| last_indexed |
2023-10-18T20:36:58Z |
| _version_ |
1796150668015173632 |