Statistical theory of diffusion-reaction processes in the system “metal-adsorbate-gas”
We present a statistical theory for diffusion-reaction processes of gaseous mixture in the system “metal-adsorbate-gas”. The theory is based on an equal consideration of electron-electron, electron-atom and atom-atom interactions between adsorbed, non-adsorbed atoms and atoms of metal surface. O...
Збережено в:
| Дата: | 2001 |
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| Автори: | , , , |
| Формат: | Стаття |
| Мова: | English |
| Опубліковано: |
Інститут фізики конденсованих систем НАН України
2001
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| Назва видання: | Condensed Matter Physics |
| Онлайн доступ: | http://dspace.nbuv.gov.ua/handle/123456789/120416 |
| Теги: |
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| Назва журналу: | Digital Library of Periodicals of National Academy of Sciences of Ukraine |
| Цитувати: | Statistical theory of diffusion-reaction processes in the system “metal-adsorbate-gas” / P.P. Kostrobii, B.M. Markovych, Yu.K. Rudavskii, M.V. Tokarchuk // Condensed Matter Physics. — 2001. — Т. 4, № 3(27). — С. 407-430. — Бібліогр.: 25 назв. — англ. |
Репозитарії
Digital Library of Periodicals of National Academy of Sciences of Ukraine| Резюме: | We present a statistical theory for diffusion-reaction processes of gaseous
mixture in the system “metal-adsorbate-gas”. The theory is based on an
equal consideration of electron-electron, electron-atom and atom-atom interactions
between adsorbed, non-adsorbed atoms and atoms of metal
surface. On a metal surface, the bimolecular reactions of the A + B ↔ AB
type are possible between the adsorbed atoms which is typical of catalytic
processes. By means of Zubarev nonequilibrium statistical operator, the
system of transport equations is obtained for a consistent description of
electronic kinetic and diffusion-reaction atomic processes. |
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