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NMR study of gallosilicate natrolite

Solid-state ²⁹Si, ²⁷Al and ⁷¹Ga NMR MAS spectroscopy was used to study the natural mineral - natrolite (Na₁₆Al₁₆Si₂₄O₈₀⋅ 16H₂O) and gallosilicate Na₁₆Al₁₆Si₂₄O₈₀⋅ 16H₂O (Ga-natrolite). It has been shown that these natrolites form have sufficiently well-ordered structure also and contain Si(MO₄)₃(SiO...

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Main Authors: Sapiga, A.A., Olszewski, M., Paczwa, M., Sapiga, A.V., Sergeev, N.A.
Format: Article
Language:English
Published: НТК «Інститут монокристалів» НАН України 2014
Series:Functional Materials
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Online Access:http://dspace.nbuv.gov.ua/handle/123456789/120417
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spelling irk-123456789-1204172017-06-13T03:02:32Z NMR study of gallosilicate natrolite Sapiga, A.A. Olszewski, M. Paczwa, M. Sapiga, A.V. Sergeev, N.A. Characterization and properties Solid-state ²⁹Si, ²⁷Al and ⁷¹Ga NMR MAS spectroscopy was used to study the natural mineral - natrolite (Na₁₆Al₁₆Si₂₄O₈₀⋅ 16H₂O) and gallosilicate Na₁₆Al₁₆Si₂₄O₈₀⋅ 16H₂O (Ga-natrolite). It has been shown that these natrolites form have sufficiently well-ordered structure also and contain Si(MO₄)₃(SiO₄) and Si(MO₄)₂(SiO₄)₂ (where M = Al or Ga) structural units mainly. Our ⁷¹Ga NMR MAS results indicate that in Ga-natrolite there are at least two different Ga cations with ratio (10:1). 2014 Article NMR study of gallosilicate natrolite / A.A. Sapiga, M. Olszewski, M. Paczwa, A.V. Sapiga, N.A. Sergeev // Functional Materials. — 2014. — Т. 21, № 2. — С. 181-185. — Бібліогр.: 14 назв. — англ. 1027-5495 DOI: dx.doi.org/10.15407/fm21.02.181 http://dspace.nbuv.gov.ua/handle/123456789/120417 en Functional Materials НТК «Інститут монокристалів» НАН України
institution Digital Library of Periodicals of National Academy of Sciences of Ukraine
collection DSpace DC
language English
topic Characterization and properties
Characterization and properties
spellingShingle Characterization and properties
Characterization and properties
Sapiga, A.A.
Olszewski, M.
Paczwa, M.
Sapiga, A.V.
Sergeev, N.A.
NMR study of gallosilicate natrolite
Functional Materials
description Solid-state ²⁹Si, ²⁷Al and ⁷¹Ga NMR MAS spectroscopy was used to study the natural mineral - natrolite (Na₁₆Al₁₆Si₂₄O₈₀⋅ 16H₂O) and gallosilicate Na₁₆Al₁₆Si₂₄O₈₀⋅ 16H₂O (Ga-natrolite). It has been shown that these natrolites form have sufficiently well-ordered structure also and contain Si(MO₄)₃(SiO₄) and Si(MO₄)₂(SiO₄)₂ (where M = Al or Ga) structural units mainly. Our ⁷¹Ga NMR MAS results indicate that in Ga-natrolite there are at least two different Ga cations with ratio (10:1).
format Article
author Sapiga, A.A.
Olszewski, M.
Paczwa, M.
Sapiga, A.V.
Sergeev, N.A.
author_facet Sapiga, A.A.
Olszewski, M.
Paczwa, M.
Sapiga, A.V.
Sergeev, N.A.
author_sort Sapiga, A.A.
title NMR study of gallosilicate natrolite
title_short NMR study of gallosilicate natrolite
title_full NMR study of gallosilicate natrolite
title_fullStr NMR study of gallosilicate natrolite
title_full_unstemmed NMR study of gallosilicate natrolite
title_sort nmr study of gallosilicate natrolite
publisher НТК «Інститут монокристалів» НАН України
publishDate 2014
topic_facet Characterization and properties
url http://dspace.nbuv.gov.ua/handle/123456789/120417
citation_txt NMR study of gallosilicate natrolite / A.A. Sapiga, M. Olszewski, M. Paczwa, A.V. Sapiga, N.A. Sergeev // Functional Materials. — 2014. — Т. 21, № 2. — С. 181-185. — Бібліогр.: 14 назв. — англ.
series Functional Materials
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AT olszewskim nmrstudyofgallosilicatenatrolite
AT paczwam nmrstudyofgallosilicatenatrolite
AT sapigaav nmrstudyofgallosilicatenatrolite
AT sergeevna nmrstudyofgallosilicatenatrolite
first_indexed 2023-10-18T20:37:00Z
last_indexed 2023-10-18T20:37:00Z
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