Synthesis, characterization and electrical properties of Pb(₈₋x)Na₂Ndx(VO₄)₆O(x/₂) solid solutions
Substitution of neodymium for lead in the apatite structure in accordance to scheme 2Pb²⁺ +□ o→ 2Nd³⁺ + O²⁻ has been investigated by X-ray powder diffraction, scanning electron microscopy, IR spectroscopy and the measurement of electrical conductivity. It was established that single phase solid solu...
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| Дата: | 2014 |
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| Автори: | , , , , , |
| Формат: | Стаття |
| Мова: | English |
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НТК «Інститут монокристалів» НАН України
2014
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| Назва видання: | Functional Materials |
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| Онлайн доступ: | http://dspace.nbuv.gov.ua/handle/123456789/120455 |
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| Назва журналу: | Digital Library of Periodicals of National Academy of Sciences of Ukraine |
| Цитувати: | Synthesis, characterization and electrical properties of Pb(₈₋x)Na₂Ndx(VO₄)₆O(x/₂) solid solutions / E.I. Getman, T.M. Savankova, A.V. Ignatov, K.G. Didorenko, A.Y. Talykova, L.I. Ardanova // Functional Materials. — 2014. — Т. 21, № 3. — С. 247-253. — Бібліогр.: 28 назв. — англ. |
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Digital Library of Periodicals of National Academy of Sciences of Ukraine| id |
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irk-123456789-1204552017-06-13T03:02:44Z Synthesis, characterization and electrical properties of Pb(₈₋x)Na₂Ndx(VO₄)₆O(x/₂) solid solutions Getman, E.I. Savankova, T.M. Ignatov, A.V. Didorenko, K.G. Talykova, A.Y. Ardanova, L.I. Characterization and properties Substitution of neodymium for lead in the apatite structure in accordance to scheme 2Pb²⁺ +□ o→ 2Nd³⁺ + O²⁻ has been investigated by X-ray powder diffraction, scanning electron microscopy, IR spectroscopy and the measurement of electrical conductivity. It was established that single phase solid solutions Pb(₈₋x)Na₂Ndx(VO₄)₆O(x/₂) are formed in the range of x = 0-0.25. The crystal structure features of some samples have been refined by the Rietveld method. It was shown that ions Nd³⁺ preferably occupy M(1) site. Influence of the composition x on the electrical conductivity and activation energy has been investigated. 2014 Article Synthesis, characterization and electrical properties of Pb(₈₋x)Na₂Ndx(VO₄)₆O(x/₂) solid solutions / E.I. Getman, T.M. Savankova, A.V. Ignatov, K.G. Didorenko, A.Y. Talykova, L.I. Ardanova // Functional Materials. — 2014. — Т. 21, № 3. — С. 247-253. — Бібліогр.: 28 назв. — англ. 1027-5495 DOI: dx.doi.org/10.15407/fm21.03.247 http://dspace.nbuv.gov.ua/handle/123456789/120455 en Functional Materials НТК «Інститут монокристалів» НАН України |
| institution |
Digital Library of Periodicals of National Academy of Sciences of Ukraine |
| collection |
DSpace DC |
| language |
English |
| topic |
Characterization and properties Characterization and properties |
| spellingShingle |
Characterization and properties Characterization and properties Getman, E.I. Savankova, T.M. Ignatov, A.V. Didorenko, K.G. Talykova, A.Y. Ardanova, L.I. Synthesis, characterization and electrical properties of Pb(₈₋x)Na₂Ndx(VO₄)₆O(x/₂) solid solutions Functional Materials |
| description |
Substitution of neodymium for lead in the apatite structure in accordance to scheme 2Pb²⁺ +□ o→ 2Nd³⁺ + O²⁻ has been investigated by X-ray powder diffraction, scanning electron microscopy, IR spectroscopy and the measurement of electrical conductivity. It was established that single phase solid solutions Pb(₈₋x)Na₂Ndx(VO₄)₆O(x/₂) are formed in the range of x = 0-0.25. The crystal structure features of some samples have been refined by the Rietveld method. It was shown that ions Nd³⁺ preferably occupy M(1) site. Influence of the composition x on the electrical conductivity and activation energy has been investigated. |
| format |
Article |
| author |
Getman, E.I. Savankova, T.M. Ignatov, A.V. Didorenko, K.G. Talykova, A.Y. Ardanova, L.I. |
| author_facet |
Getman, E.I. Savankova, T.M. Ignatov, A.V. Didorenko, K.G. Talykova, A.Y. Ardanova, L.I. |
| author_sort |
Getman, E.I. |
| title |
Synthesis, characterization and electrical properties of Pb(₈₋x)Na₂Ndx(VO₄)₆O(x/₂) solid solutions |
| title_short |
Synthesis, characterization and electrical properties of Pb(₈₋x)Na₂Ndx(VO₄)₆O(x/₂) solid solutions |
| title_full |
Synthesis, characterization and electrical properties of Pb(₈₋x)Na₂Ndx(VO₄)₆O(x/₂) solid solutions |
| title_fullStr |
Synthesis, characterization and electrical properties of Pb(₈₋x)Na₂Ndx(VO₄)₆O(x/₂) solid solutions |
| title_full_unstemmed |
Synthesis, characterization and electrical properties of Pb(₈₋x)Na₂Ndx(VO₄)₆O(x/₂) solid solutions |
| title_sort |
synthesis, characterization and electrical properties of pb(₈₋x)na₂ndx(vo₄)₆o(x/₂) solid solutions |
| publisher |
НТК «Інститут монокристалів» НАН України |
| publishDate |
2014 |
| topic_facet |
Characterization and properties |
| url |
http://dspace.nbuv.gov.ua/handle/123456789/120455 |
| citation_txt |
Synthesis, characterization and electrical properties of Pb(₈₋x)Na₂Ndx(VO₄)₆O(x/₂) solid solutions / E.I. Getman, T.M. Savankova, A.V. Ignatov, K.G. Didorenko, A.Y. Talykova, L.I. Ardanova // Functional Materials. — 2014. — Т. 21, № 3. — С. 247-253. — Бібліогр.: 28 назв. — англ. |
| series |
Functional Materials |
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