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Synthesis, characterization and electrical properties of Pb(₈₋x)Na₂Ndx(VO₄)₆O(x/₂) solid solutions

Substitution of neodymium for lead in the apatite structure in accordance to scheme 2Pb²⁺ +□ o→ 2Nd³⁺ + O²⁻ has been investigated by X-ray powder diffraction, scanning electron microscopy, IR spectroscopy and the measurement of electrical conductivity. It was established that single phase solid solu...

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Main Authors: Getman, E.I., Savankova, T.M., Ignatov, A.V., Didorenko, K.G., Talykova, A.Y., Ardanova, L.I.
Format: Article
Language:English
Published: НТК «Інститут монокристалів» НАН України 2014
Series:Functional Materials
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Online Access:http://dspace.nbuv.gov.ua/handle/123456789/120455
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spelling irk-123456789-1204552017-06-13T03:02:44Z Synthesis, characterization and electrical properties of Pb(₈₋x)Na₂Ndx(VO₄)₆O(x/₂) solid solutions Getman, E.I. Savankova, T.M. Ignatov, A.V. Didorenko, K.G. Talykova, A.Y. Ardanova, L.I. Characterization and properties Substitution of neodymium for lead in the apatite structure in accordance to scheme 2Pb²⁺ +□ o→ 2Nd³⁺ + O²⁻ has been investigated by X-ray powder diffraction, scanning electron microscopy, IR spectroscopy and the measurement of electrical conductivity. It was established that single phase solid solutions Pb(₈₋x)Na₂Ndx(VO₄)₆O(x/₂) are formed in the range of x = 0-0.25. The crystal structure features of some samples have been refined by the Rietveld method. It was shown that ions Nd³⁺ preferably occupy M(1) site. Influence of the composition x on the electrical conductivity and activation energy has been investigated. 2014 Article Synthesis, characterization and electrical properties of Pb(₈₋x)Na₂Ndx(VO₄)₆O(x/₂) solid solutions / E.I. Getman, T.M. Savankova, A.V. Ignatov, K.G. Didorenko, A.Y. Talykova, L.I. Ardanova // Functional Materials. — 2014. — Т. 21, № 3. — С. 247-253. — Бібліогр.: 28 назв. — англ. 1027-5495 DOI: dx.doi.org/10.15407/fm21.03.247 http://dspace.nbuv.gov.ua/handle/123456789/120455 en Functional Materials НТК «Інститут монокристалів» НАН України
institution Digital Library of Periodicals of National Academy of Sciences of Ukraine
collection DSpace DC
language English
topic Characterization and properties
Characterization and properties
spellingShingle Characterization and properties
Characterization and properties
Getman, E.I.
Savankova, T.M.
Ignatov, A.V.
Didorenko, K.G.
Talykova, A.Y.
Ardanova, L.I.
Synthesis, characterization and electrical properties of Pb(₈₋x)Na₂Ndx(VO₄)₆O(x/₂) solid solutions
Functional Materials
description Substitution of neodymium for lead in the apatite structure in accordance to scheme 2Pb²⁺ +□ o→ 2Nd³⁺ + O²⁻ has been investigated by X-ray powder diffraction, scanning electron microscopy, IR spectroscopy and the measurement of electrical conductivity. It was established that single phase solid solutions Pb(₈₋x)Na₂Ndx(VO₄)₆O(x/₂) are formed in the range of x = 0-0.25. The crystal structure features of some samples have been refined by the Rietveld method. It was shown that ions Nd³⁺ preferably occupy M(1) site. Influence of the composition x on the electrical conductivity and activation energy has been investigated.
format Article
author Getman, E.I.
Savankova, T.M.
Ignatov, A.V.
Didorenko, K.G.
Talykova, A.Y.
Ardanova, L.I.
author_facet Getman, E.I.
Savankova, T.M.
Ignatov, A.V.
Didorenko, K.G.
Talykova, A.Y.
Ardanova, L.I.
author_sort Getman, E.I.
title Synthesis, characterization and electrical properties of Pb(₈₋x)Na₂Ndx(VO₄)₆O(x/₂) solid solutions
title_short Synthesis, characterization and electrical properties of Pb(₈₋x)Na₂Ndx(VO₄)₆O(x/₂) solid solutions
title_full Synthesis, characterization and electrical properties of Pb(₈₋x)Na₂Ndx(VO₄)₆O(x/₂) solid solutions
title_fullStr Synthesis, characterization and electrical properties of Pb(₈₋x)Na₂Ndx(VO₄)₆O(x/₂) solid solutions
title_full_unstemmed Synthesis, characterization and electrical properties of Pb(₈₋x)Na₂Ndx(VO₄)₆O(x/₂) solid solutions
title_sort synthesis, characterization and electrical properties of pb(₈₋x)na₂ndx(vo₄)₆o(x/₂) solid solutions
publisher НТК «Інститут монокристалів» НАН України
publishDate 2014
topic_facet Characterization and properties
url http://dspace.nbuv.gov.ua/handle/123456789/120455
citation_txt Synthesis, characterization and electrical properties of Pb(₈₋x)Na₂Ndx(VO₄)₆O(x/₂) solid solutions / E.I. Getman, T.M. Savankova, A.V. Ignatov, K.G. Didorenko, A.Y. Talykova, L.I. Ardanova // Functional Materials. — 2014. — Т. 21, № 3. — С. 247-253. — Бібліогр.: 28 назв. — англ.
series Functional Materials
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last_indexed 2023-10-18T20:37:05Z
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