The influence of defects and conductivity on the domain structure properties and the memory effect in the ferroelectrics-semiconductors Sn₂P₂Se₆

For the proper uniaxial ferroelectrics Sn₂P₂Se₆ with the controlled content of different type of impurities the investigations of dielectric permeability temperature dependence are performed with the aim to determine the influence of the crystal structure defects upon: the efficiency of the thermal...

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Дата:1999
Автори: Vysochanskii, Yu.M., Molnar, A.A., Khoma, M.M., Motrja, S.F.
Формат: Стаття
Мова:English
Опубліковано: Інститут фізики конденсованих систем НАН України 1999
Назва видання:Condensed Matter Physics
Онлайн доступ:http://dspace.nbuv.gov.ua/handle/123456789/120525
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Назва журналу:Digital Library of Periodicals of National Academy of Sciences of Ukraine
Цитувати:The influence of defects and conductivity on the domain structure properties and the memory effect in the ferroelectrics-semiconductors Sn₂P₂Se₆ / Yu.M. Vysochanskii, A.A. Molnar, M.M. Khoma, S.F. Motrja // Condensed Matter Physics. — 1999. — Т. 2, № 3(19). — С. 421-434. — Бібліогр.: 24 назв. — англ.

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Digital Library of Periodicals of National Academy of Sciences of Ukraine
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spelling irk-123456789-1205252017-06-13T03:05:29Z The influence of defects and conductivity on the domain structure properties and the memory effect in the ferroelectrics-semiconductors Sn₂P₂Se₆ Vysochanskii, Yu.M. Molnar, A.A. Khoma, M.M. Motrja, S.F. For the proper uniaxial ferroelectrics Sn₂P₂Se₆ with the controlled content of different type of impurities the investigations of dielectric permeability temperature dependence are performed with the aim to determine the influence of the crystal structure defects upon: the efficiency of the thermal memory effect recording in the incommensurate (IC) phase; the second order phase transition (PT) from the paraelectric phase to the IC phase at temperature Ti and upon the first order PT from IC phase to ferroelectric phase at temperature Tc; the anomalous hysteresis of the dielectric properties temperature dependence in the IC phase; the dielectric contribution of the domain walls in the ferroelectric phase. Static defects smear the anomaly at the PT from paraelectric phase to IC phase, increase the anomalous hysteresis in the IC phase and the hysteresis of the lock-in transition temperature Tc, suppress the dielectric contribution of domain walls in the ferroelectric phase and destroy the memory effect in the IC phase. The increase of the charge carrier concentration also suppresses the dielectric output of the domain walls in the ferroelectric phase but at the same time it supports a more clear memory recording in the IC phase. Such a tendency agrees with the estimations in the mean-field approximation for the characteristics of a domain structure in the ferroelectric phase and memory effect in the IC phase in the ferroelectrics-semiconductors investigated. Для власного одновiсного сегнетоелектрика Sn₂P₂Se₆ з неконтрольованим вмiстом домiшок рiзного типу виконанi дослiдження температурної залежностi дiелектричної проникностi для встановлення впливу дефектностi кристалiчної структури на ефективнiсть запису термiчної “пам’ятi” в неспiвмiрнiй (НС) фазi, на фазовий перехiд (ФП) другого роду з параелектричної фази до НС фази при температурi i та на ФП першого роду з НС фази до сегнетоелектричної фази при температурi c, на аномальний гiстерезис температурної залежностi дiелектричних властивостей в НС фазi, на дiелектричний вклад доменних стiнок у сегнетоелектричнiй фазi. Статичнi дефекти розмивають аномалiї при ФП з параелектричної в НС фазу, збiльшують аномальний гiстерезис в НС фазi та гiстерезис температури c lock-in переходу, подавляють дiелектричний вклад доменних стiнок у сегнетофазi та руйнують ефект “пам’ятi” в НС фазi. Зростання концентрацiї носiїв заряду також подавляє дiелектричний вiдклик доменних стiнок у сегнетоелектричнiй фазi, однак поряд з цим сприяє чiткішому запису ”пам’ятi” в НС фазi. Така тенденцiя погоджується з виконаними оцiнками в наближеннi середнього поля для характеристик доменної структури в сегнетоелектричнiй фазi та для ефекту “пам’ятi” в НС фазi для дослiджуваних сегнетоелектрикiв- напiвпровiдникiв. 1999 Article The influence of defects and conductivity on the domain structure properties and the memory effect in the ferroelectrics-semiconductors Sn₂P₂Se₆ / Yu.M. Vysochanskii, A.A. Molnar, M.M. Khoma, S.F. Motrja // Condensed Matter Physics. — 1999. — Т. 2, № 3(19). — С. 421-434. — Бібліогр.: 24 назв. — англ. 1607-324X DOI:10.5488/CMP.2.3.421 PACS: 64.70.Rh, 67.70.Kb, 64.60.Fr http://dspace.nbuv.gov.ua/handle/123456789/120525 en Condensed Matter Physics Інститут фізики конденсованих систем НАН України
institution Digital Library of Periodicals of National Academy of Sciences of Ukraine
collection DSpace DC
language English
description For the proper uniaxial ferroelectrics Sn₂P₂Se₆ with the controlled content of different type of impurities the investigations of dielectric permeability temperature dependence are performed with the aim to determine the influence of the crystal structure defects upon: the efficiency of the thermal memory effect recording in the incommensurate (IC) phase; the second order phase transition (PT) from the paraelectric phase to the IC phase at temperature Ti and upon the first order PT from IC phase to ferroelectric phase at temperature Tc; the anomalous hysteresis of the dielectric properties temperature dependence in the IC phase; the dielectric contribution of the domain walls in the ferroelectric phase. Static defects smear the anomaly at the PT from paraelectric phase to IC phase, increase the anomalous hysteresis in the IC phase and the hysteresis of the lock-in transition temperature Tc, suppress the dielectric contribution of domain walls in the ferroelectric phase and destroy the memory effect in the IC phase. The increase of the charge carrier concentration also suppresses the dielectric output of the domain walls in the ferroelectric phase but at the same time it supports a more clear memory recording in the IC phase. Such a tendency agrees with the estimations in the mean-field approximation for the characteristics of a domain structure in the ferroelectric phase and memory effect in the IC phase in the ferroelectrics-semiconductors investigated.
format Article
author Vysochanskii, Yu.M.
Molnar, A.A.
Khoma, M.M.
Motrja, S.F.
spellingShingle Vysochanskii, Yu.M.
Molnar, A.A.
Khoma, M.M.
Motrja, S.F.
The influence of defects and conductivity on the domain structure properties and the memory effect in the ferroelectrics-semiconductors Sn₂P₂Se₆
Condensed Matter Physics
author_facet Vysochanskii, Yu.M.
Molnar, A.A.
Khoma, M.M.
Motrja, S.F.
author_sort Vysochanskii, Yu.M.
title The influence of defects and conductivity on the domain structure properties and the memory effect in the ferroelectrics-semiconductors Sn₂P₂Se₆
title_short The influence of defects and conductivity on the domain structure properties and the memory effect in the ferroelectrics-semiconductors Sn₂P₂Se₆
title_full The influence of defects and conductivity on the domain structure properties and the memory effect in the ferroelectrics-semiconductors Sn₂P₂Se₆
title_fullStr The influence of defects and conductivity on the domain structure properties and the memory effect in the ferroelectrics-semiconductors Sn₂P₂Se₆
title_full_unstemmed The influence of defects and conductivity on the domain structure properties and the memory effect in the ferroelectrics-semiconductors Sn₂P₂Se₆
title_sort influence of defects and conductivity on the domain structure properties and the memory effect in the ferroelectrics-semiconductors sn₂p₂se₆
publisher Інститут фізики конденсованих систем НАН України
publishDate 1999
url http://dspace.nbuv.gov.ua/handle/123456789/120525
citation_txt The influence of defects and conductivity on the domain structure properties and the memory effect in the ferroelectrics-semiconductors Sn₂P₂Se₆ / Yu.M. Vysochanskii, A.A. Molnar, M.M. Khoma, S.F. Motrja // Condensed Matter Physics. — 1999. — Т. 2, № 3(19). — С. 421-434. — Бібліогр.: 24 назв. — англ.
series Condensed Matter Physics
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last_indexed 2023-10-18T20:37:16Z
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