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The temperature coefficient of the potential of zero charge of Ag single crystal face electrodes in aqueous electrolyte solution
The temperature coefficient of the potential of zero charge of Ag single crystal electrodes, dEσ₌₀/dT , was measured by recording capacitance curves at different temperatures. Two experimental approaches were adopted: the “continuity” and the “discontinuity” method, consisting in recording curve...
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| Main Authors: | , |
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| Format: | Article |
| Language: | English |
| Published: |
Інститут фізики конденсованих систем НАН України
2001
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| Series: | Condensed Matter Physics |
| Online Access: | http://dspace.nbuv.gov.ua/handle/123456789/120527 |
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| Summary: | The temperature coefficient of the potential of zero charge of Ag single
crystal electrodes, dEσ₌₀/dT , was measured by recording capacitance
curves at different temperatures. Two experimental approaches
were adopted: the “continuity” and the “discontinuity” method, consisting
in recording curves at different temperatures without and with extraction
of the electrode from the solution, respectively. Appreciable differences
have been observed. The origin of the differences and their significance
are discussed in terms of keeping the appropriate conditions for the electrode/solution
interface during the experiments. |
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