A treatment of the exclusion volume term in the inhomogeneous Poisson-Boltzmann theory for an ion-dipole mixture
The exclusion volume approximation in the Poisson-Boltzmann theory is analysed at the mean field level for an ion-dipole mixture against a plane, uniformly charged hard wall. An earlier treatment is extended to take account of the deviation of the exclusion volume term from the uncharged wall –...
Збережено в:
| Дата: | 2001 |
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| Автори: | , |
| Формат: | Стаття |
| Мова: | English |
| Опубліковано: |
Інститут фізики конденсованих систем НАН України
2001
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| Назва видання: | Condensed Matter Physics |
| Онлайн доступ: | http://dspace.nbuv.gov.ua/handle/123456789/120536 |
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| Назва журналу: | Digital Library of Periodicals of National Academy of Sciences of Ukraine |
| Цитувати: | A treatment of the exclusion volume term in the inhomogeneous Poisson-Boltzmann theory for an ion-dipole mixture / C.W. Outhwaite, S. Lamperski // Condensed Matter Physics. — 2001. — Т. 4, № 4(28). — С. 739-748. — Бібліогр.: 28 назв. — англ. |
Репозиторії
Digital Library of Periodicals of National Academy of Sciences of Ukraine| Резюме: | The exclusion volume approximation in the Poisson-Boltzmann theory is
analysed at the mean field level for an ion-dipole mixture against a plane,
uniformly charged hard wall. An earlier treatment is extended to take account
of the deviation of the exclusion volume term from the uncharged
wall – uncharged hard sphere distribution function. Preliminary numerical
results are presented for a 1:1 electrolyte at c = 1.0 mole/dm³ with unequal
ion and dipole sizes. |
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