A treatment of the exclusion volume term in the inhomogeneous Poisson-Boltzmann theory for an ion-dipole mixture

The exclusion volume approximation in the Poisson-Boltzmann theory is analysed at the mean field level for an ion-dipole mixture against a plane, uniformly charged hard wall. An earlier treatment is extended to take account of the deviation of the exclusion volume term from the uncharged wall –...

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Збережено в:
Бібліографічні деталі
Дата:2001
Автори: Outhwaite, C.W., Lamperski, S.
Формат: Стаття
Мова:English
Опубліковано: Інститут фізики конденсованих систем НАН України 2001
Назва видання:Condensed Matter Physics
Онлайн доступ:http://dspace.nbuv.gov.ua/handle/123456789/120536
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Назва журналу:Digital Library of Periodicals of National Academy of Sciences of Ukraine
Цитувати:A treatment of the exclusion volume term in the inhomogeneous Poisson-Boltzmann theory for an ion-dipole mixture / C.W. Outhwaite, S. Lamperski // Condensed Matter Physics. — 2001. — Т. 4, № 4(28). — С. 739-748. — Бібліогр.: 28 назв. — англ.

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Digital Library of Periodicals of National Academy of Sciences of Ukraine
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Резюме:The exclusion volume approximation in the Poisson-Boltzmann theory is analysed at the mean field level for an ion-dipole mixture against a plane, uniformly charged hard wall. An earlier treatment is extended to take account of the deviation of the exclusion volume term from the uncharged wall – uncharged hard sphere distribution function. Preliminary numerical results are presented for a 1:1 electrolyte at c = 1.0 mole/dm³ with unequal ion and dipole sizes.