Application of Replica Ornstein-Zernike equations in studies of the adsorption of electrolyte mixtures in disordered matrices of charged particles
The Replica Ornstein-Zernike (ROZ) equations were used to study the adsorption of ions from electrolyte mixtures. The adsorbent was represented as a quenched primitive model +1:-1 size symmetric electrolyte, while the mobile particles were ions differing in charge and/or size. The ROZ equations in...
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| Видавець: | Інститут фізики конденсованих систем НАН України |
|---|---|
| Дата: | 2009 |
| Автори: | , , |
| Формат: | Стаття |
| Мова: | English |
| Опубліковано: |
Інститут фізики конденсованих систем НАН України
2009
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| Назва видання: | Condensed Matter Physics |
| Онлайн доступ: | http://dspace.nbuv.gov.ua/handle/123456789/120552 |
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| Цитувати: | Application of Replica Ornstein-Zernike equations in studies of the adsorption of electrolyte mixtures in disordered matrices of charged particles / M. Lukšič, G. Trefalt, B. Hribar-Lee // Condensed Matter Physics. — 2009. — Т. 12, № 4. — С. 717-724. — Бібліогр.: 29 назв. — англ. |
Репозиторії
Digital Library of Periodicals of National Academy of Sciences of Ukraine| id |
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irk-123456789-1205522017-06-13T03:05:41Z Application of Replica Ornstein-Zernike equations in studies of the adsorption of electrolyte mixtures in disordered matrices of charged particles Lukšič, M. Trefalt, G. Hribar-Lee, B. The Replica Ornstein-Zernike (ROZ) equations were used to study the adsorption of ions from electrolyte mixtures. The adsorbent was represented as a quenched primitive model +1:-1 size symmetric electrolyte, while the mobile particles were ions differing in charge and/or size. The ROZ equations in hypernetted-chain (HNC) approximation were tested against new Monte Carlo results in the grand canonical ensemble; good agreement between the two methods was obtained. The ROZ/HNC theory was then used to study the exclusion coefficients as a function of size and/or charge asymmetry of the annealed ions. Реплiчне рiвняння Орнштейна-Цернiке (РОЦ) застосоване для вивчення адсорбцiї iонiв iз сумiшей електролiтiв. Адсорбент розглядається у виглядi замороженої примiтивної +1:-1 моделi розмiрно симетричного електролiту, тодi як рухомi частинки – це iони, що вiдрiзняються зарядом та/або роз- мiрами. Данi, що отриманi з рiвняння РОЦ у гiперланцюжковому наближеннi (ГЛН), порiвняно з но- вими результатами Монте-Карло моделювання у великому канонiчному ансамблi i виявлено хороше узгодження мiж обома методами. Теорiю РОЦ/ГЛН далi було використано для вивчення коефiцiєнтiв виключення, в залежностi вiд параметрiв розмiрної та/або зарядової асиметрiй нерухомих iонiв. 2009 Article Application of Replica Ornstein-Zernike equations in studies of the adsorption of electrolyte mixtures in disordered matrices of charged particles / M. Lukšič, G. Trefalt, B. Hribar-Lee // Condensed Matter Physics. — 2009. — Т. 12, № 4. — С. 717-724. — Бібліогр.: 29 назв. — англ. 1607-324X PACS: 82.60.-s, 02.30.Rz, 61.20.-p DOI:10.5488/CMP.12.4.717 http://dspace.nbuv.gov.ua/handle/123456789/120552 en Condensed Matter Physics Інститут фізики конденсованих систем НАН України |
| institution |
Digital Library of Periodicals of National Academy of Sciences of Ukraine |
| collection |
DSpace DC |
| language |
English |
| description |
The Replica Ornstein-Zernike (ROZ) equations were used to study the adsorption of ions from electrolyte mixtures.
The adsorbent was represented as a quenched primitive model +1:-1 size symmetric electrolyte, while
the mobile particles were ions differing in charge and/or size. The ROZ equations in hypernetted-chain (HNC)
approximation were tested against new Monte Carlo results in the grand canonical ensemble; good agreement
between the two methods was obtained. The ROZ/HNC theory was then used to study the exclusion
coefficients as a function of size and/or charge asymmetry of the annealed ions. |
| format |
Article |
| author |
Lukšič, M. Trefalt, G. Hribar-Lee, B. |
| spellingShingle |
Lukšič, M. Trefalt, G. Hribar-Lee, B. Application of Replica Ornstein-Zernike equations in studies of the adsorption of electrolyte mixtures in disordered matrices of charged particles Condensed Matter Physics |
| author_facet |
Lukšič, M. Trefalt, G. Hribar-Lee, B. |
| author_sort |
Lukšič, M. |
| title |
Application of Replica Ornstein-Zernike equations in studies of the adsorption of electrolyte mixtures in disordered matrices of charged particles |
| title_short |
Application of Replica Ornstein-Zernike equations in studies of the adsorption of electrolyte mixtures in disordered matrices of charged particles |
| title_full |
Application of Replica Ornstein-Zernike equations in studies of the adsorption of electrolyte mixtures in disordered matrices of charged particles |
| title_fullStr |
Application of Replica Ornstein-Zernike equations in studies of the adsorption of electrolyte mixtures in disordered matrices of charged particles |
| title_full_unstemmed |
Application of Replica Ornstein-Zernike equations in studies of the adsorption of electrolyte mixtures in disordered matrices of charged particles |
| title_sort |
application of replica ornstein-zernike equations in studies of the adsorption of electrolyte mixtures in disordered matrices of charged particles |
| publisher |
Інститут фізики конденсованих систем НАН України |
| publishDate |
2009 |
| url |
http://dspace.nbuv.gov.ua/handle/123456789/120552 |
| citation_txt |
Application of Replica Ornstein-Zernike equations in studies of the adsorption of electrolyte mixtures in disordered matrices of charged particles / M. Lukšič, G. Trefalt, B. Hribar-Lee // Condensed Matter Physics. — 2009. — Т. 12, № 4. — С. 717-724. — Бібліогр.: 29 назв. — англ. |
| series |
Condensed Matter Physics |
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2023-10-18T20:37:20Z |
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2023-10-18T20:37:20Z |
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