On features of deoxidization of CsI melt with zirconium getter
Interaction of Zr getter with oxygen-containing admixtures being most abundant in molten alkali metal iodides (deoxidization) is studied. Reaction of Zr with oxide ions (in form of the corresponding alkali metal oxide) is characterized by very negative enthalpy and Gibbs energy values that make the...
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| Дата: | 2016 |
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| Автори: | , , , , , , |
| Формат: | Стаття |
| Мова: | English |
| Опубліковано: |
НТК «Інститут монокристалів» НАН України
2016
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| Назва видання: | Functional Materials |
| Теми: | |
| Онлайн доступ: | http://dspace.nbuv.gov.ua/handle/123456789/120638 |
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| Назва журналу: | Digital Library of Periodicals of National Academy of Sciences of Ukraine |
| Цитувати: | On features of deoxidization of CsI melt with zirconium getter / Yu.N. Datsko, T.P Rebrova, V.L. Cherginets, V.A. Naumenko, A.L. Rebrov, P.V. Mateychenko, I.N. Vjunnik // Functional Materials. — 2016. — Т. 23, № 2. — С. 307-312. — Бібліогр.: 7 назв. — англ. |
Репозитарії
Digital Library of Periodicals of National Academy of Sciences of Ukraine| id |
irk-123456789-120638 |
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| record_format |
dspace |
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irk-123456789-1206382017-06-13T03:03:05Z On features of deoxidization of CsI melt with zirconium getter Datsko, Yu.N. Rebrova, T.P. Cherginets, V.L. Naumenko, V.A. Rebrov, A.L. Mateychenko, P.V. Vjunnik, I.N. Technology Interaction of Zr getter with oxygen-containing admixtures being most abundant in molten alkali metal iodides (deoxidization) is studied. Reaction of Zr with oxide ions (in form of the corresponding alkali metal oxide) is characterized by very negative enthalpy and Gibbs energy values that make the deoxidization process very favorable. Practically the interaction leads to decrease of O²⁻ concentration by a factor of ca. 6. Interaction of Zr with carbonate ions is shown both by the calculations and by experiment Ґй lead to the formation of carbon particles (suspension) in the melts that causes certain limitations of the getter treatment for the purification of practically used growth iodide melts. 2016 Article On features of deoxidization of CsI melt with zirconium getter / Yu.N. Datsko, T.P Rebrova, V.L. Cherginets, V.A. Naumenko, A.L. Rebrov, P.V. Mateychenko, I.N. Vjunnik // Functional Materials. — 2016. — Т. 23, № 2. — С. 307-312. — Бібліогр.: 7 назв. — англ. 1027-5495 http://dspace.nbuv.gov.ua/handle/123456789/120638 DOI: dx.doi.org/10.15407/fm23.02.307 en Functional Materials НТК «Інститут монокристалів» НАН України |
| institution |
Digital Library of Periodicals of National Academy of Sciences of Ukraine |
| collection |
DSpace DC |
| language |
English |
| topic |
Technology Technology |
| spellingShingle |
Technology Technology Datsko, Yu.N. Rebrova, T.P. Cherginets, V.L. Naumenko, V.A. Rebrov, A.L. Mateychenko, P.V. Vjunnik, I.N. On features of deoxidization of CsI melt with zirconium getter Functional Materials |
| description |
Interaction of Zr getter with oxygen-containing admixtures being most abundant in molten alkali metal iodides (deoxidization) is studied. Reaction of Zr with oxide ions (in form of the corresponding alkali metal oxide) is characterized by very negative enthalpy and Gibbs energy values that make the deoxidization process very favorable. Practically the interaction leads to decrease of O²⁻ concentration by a factor of ca. 6. Interaction of Zr with carbonate ions is shown both by the calculations and by experiment Ґй lead to the formation of carbon particles (suspension) in the melts that causes certain limitations of the getter treatment for the purification of practically used growth iodide melts. |
| format |
Article |
| author |
Datsko, Yu.N. Rebrova, T.P. Cherginets, V.L. Naumenko, V.A. Rebrov, A.L. Mateychenko, P.V. Vjunnik, I.N. |
| author_facet |
Datsko, Yu.N. Rebrova, T.P. Cherginets, V.L. Naumenko, V.A. Rebrov, A.L. Mateychenko, P.V. Vjunnik, I.N. |
| author_sort |
Datsko, Yu.N. |
| title |
On features of deoxidization of CsI melt with zirconium getter |
| title_short |
On features of deoxidization of CsI melt with zirconium getter |
| title_full |
On features of deoxidization of CsI melt with zirconium getter |
| title_fullStr |
On features of deoxidization of CsI melt with zirconium getter |
| title_full_unstemmed |
On features of deoxidization of CsI melt with zirconium getter |
| title_sort |
on features of deoxidization of csi melt with zirconium getter |
| publisher |
НТК «Інститут монокристалів» НАН України |
| publishDate |
2016 |
| topic_facet |
Technology |
| url |
http://dspace.nbuv.gov.ua/handle/123456789/120638 |
| citation_txt |
On features of deoxidization of CsI melt with zirconium getter / Yu.N. Datsko, T.P Rebrova, V.L. Cherginets, V.A. Naumenko, A.L. Rebrov, P.V. Mateychenko, I.N. Vjunnik // Functional Materials. — 2016. — Т. 23, № 2. — С. 307-312. — Бібліогр.: 7 назв. — англ. |
| series |
Functional Materials |
| work_keys_str_mv |
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| first_indexed |
2023-10-18T20:37:32Z |
| last_indexed |
2023-10-18T20:37:32Z |
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