Selective adsorption of ions in charged slit-systems
We study the selective adsorption of various cations into a layered slit system using grand canonical Monte Carlo simulations. The slit system is formed by a series of negatively charged membranes. The electrolyte contains two kinds of cations with different sizes and valences modeled by charged har...
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| Видавець: | Інститут фізики конденсованих систем НАН України |
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| Дата: | 2013 |
| Автори: | , , |
| Формат: | Стаття |
| Мова: | English |
| Опубліковано: |
Інститут фізики конденсованих систем НАН України
2013
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| Назва видання: | Condensed Matter Physics |
| Онлайн доступ: | http://dspace.nbuv.gov.ua/handle/123456789/120842 |
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| Цитувати: | Selective adsorption of ions in charged slit-systems / M.Valiskó, D. Henderson, D. Boda // Condensed Matter Physics. — 2013. — Т. 16, № 4. — С. 43601:1-12. — Бібліогр.: 76 назв. — англ. |
Репозиторії
Digital Library of Periodicals of National Academy of Sciences of Ukraine| id |
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irk-123456789-1208422017-06-14T03:04:27Z Selective adsorption of ions in charged slit-systems Valiskó, M. Henderson, D. Boda, D. We study the selective adsorption of various cations into a layered slit system using grand canonical Monte Carlo simulations. The slit system is formed by a series of negatively charged membranes. The electrolyte contains two kinds of cations with different sizes and valences modeled by charged hard spheres immersed in a continuum dielectric solvent. We present results for various cases depending on the combinations of the properties of the competing cations. We concentrate to the case when the divalent cations are larger than the monovalent cations. In this case, size and charge have counterbalancing effects, which results in interesting selectivity phenomena. Ми дослiджуємо селективну адсорбцiю рiзних катiонiв у шарувату щiлиноподiбну систему, використовуючи Монте Карло симуляцiї у великому канонiчному ансамблi. Щiлиноподiбна система формується послiдовнiстю негативно заряджених мембран. Електролiт мiстить два типи катiонiв рiзних розмiрiв i валентностей, якi моделюються зарядженими твердими сферами, зануреними в однорiдний дiелектричний розчинник. Ми представляємо результати для рiзних випадкiв в залежностi вiд комбiнацiї властивостей конкуруючих катiонiв. Ми розглядаємо випадок, коли двовалентнi катiони є бiльшi, нiж моновалентнi. У цьому випадку, розмiр i заряд мають зрiвноважувальний ефект, що приводить до цiкавих селективних явищ. 2013 Article Selective adsorption of ions in charged slit-systems / M.Valiskó, D. Henderson, D. Boda // Condensed Matter Physics. — 2013. — Т. 16, № 4. — С. 43601:1-12. — Бібліогр.: 76 назв. — англ. 1607-324X PACS: 61.20.Qg, 68.03.-g, 81.05.Rm, 61.20.Ja, 07.05.Tp DOI:10.5488/CMP.16.43601 arXiv:1312.4482 http://dspace.nbuv.gov.ua/handle/123456789/120842 en Condensed Matter Physics Інститут фізики конденсованих систем НАН України |
| institution |
Digital Library of Periodicals of National Academy of Sciences of Ukraine |
| collection |
DSpace DC |
| language |
English |
| description |
We study the selective adsorption of various cations into a layered slit system using grand canonical Monte Carlo simulations. The slit system is formed by a series of negatively charged membranes. The electrolyte contains two kinds of cations with different sizes and valences modeled by charged hard spheres immersed in a continuum dielectric solvent. We present results for various cases depending on the combinations of the properties of the competing cations. We concentrate to the case when the divalent cations are larger than the monovalent cations. In this case, size and charge have counterbalancing effects, which results in interesting selectivity phenomena. |
| format |
Article |
| author |
Valiskó, M. Henderson, D. Boda, D. |
| spellingShingle |
Valiskó, M. Henderson, D. Boda, D. Selective adsorption of ions in charged slit-systems Condensed Matter Physics |
| author_facet |
Valiskó, M. Henderson, D. Boda, D. |
| author_sort |
Valiskó, M. |
| title |
Selective adsorption of ions in charged slit-systems |
| title_short |
Selective adsorption of ions in charged slit-systems |
| title_full |
Selective adsorption of ions in charged slit-systems |
| title_fullStr |
Selective adsorption of ions in charged slit-systems |
| title_full_unstemmed |
Selective adsorption of ions in charged slit-systems |
| title_sort |
selective adsorption of ions in charged slit-systems |
| publisher |
Інститут фізики конденсованих систем НАН України |
| publishDate |
2013 |
| url |
http://dspace.nbuv.gov.ua/handle/123456789/120842 |
| citation_txt |
Selective adsorption of ions in charged slit-systems / M.Valiskó, D. Henderson, D. Boda // Condensed Matter Physics. — 2013. — Т. 16, № 4. — С. 43601:1-12. — Бібліогр.: 76 назв. — англ. |
| series |
Condensed Matter Physics |
| work_keys_str_mv |
AT valiskom selectiveadsorptionofionsinchargedslitsystems AT hendersond selectiveadsorptionofionsinchargedslitsystems AT bodad selectiveadsorptionofionsinchargedslitsystems |
| first_indexed |
2023-10-18T20:38:16Z |
| last_indexed |
2023-10-18T20:38:16Z |
| _version_ |
1796150722677440512 |