Extraordinary temperature dependence of isochoric thermal conductivity of crystalline CO₂ doped with inert gases

The isochoric thermal conductivities of solid (CO₂)₀,₉₀₅Kr₀,₀₉₅ and (CO2)₁₋xXex(x = 0.052 and 0.097) solution of different densities was investigated in the temperature interval from 150 K to the onset of melting. An unusual effect of point defects on the thermal conductivity has been detected. I...

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Дата:2006
Автори: Konstantinov, V.A., Manzhelii, V.G., Revyakin, V.P., Sagan, V.V.
Формат: Стаття
Мова:English
Опубліковано: Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України 2006
Назва видання:Физика низких температур
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Онлайн доступ:http://dspace.nbuv.gov.ua/handle/123456789/120890
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Назва журналу:Digital Library of Periodicals of National Academy of Sciences of Ukraine
Цитувати:Extraordinary temperature dependence of isochoric thermal conductivity of crystalline CO₂ doped with inert gases / V.A. Konstantinov, V.G. Manzhelii, V.P. Revyakin, V.V. Sagan // Физика низких температур. — 2006. — Т. 32, № 11. — С. 1414–1416. — Бібліогр.: 9 назв. — англ.

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Digital Library of Periodicals of National Academy of Sciences of Ukraine
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spelling irk-123456789-1208902017-06-14T03:05:14Z Extraordinary temperature dependence of isochoric thermal conductivity of crystalline CO₂ doped with inert gases Konstantinov, V.A. Manzhelii, V.G. Revyakin, V.P. Sagan, V.V. Cryocrystals The isochoric thermal conductivities of solid (CO₂)₀,₉₀₅Kr₀,₀₉₅ and (CO2)₁₋xXex(x = 0.052 and 0.097) solution of different densities was investigated in the temperature interval from 150 K to the onset of melting. An unusual effect of point defects on the thermal conductivity has been detected. In pure CO₂ at T >150 K the isochoric thermal conductivity decreases smoothly with increasing temperature. In contrast, the thermal conductivity of solid CO₂/Kr and CO₂/Xe solutions first decreases passing through a minimum at 200–210 K and then starts to increase with temperature up to the onset of melting. This behavior of the isochoric thermal conductivity is attributed to the rotation of the CO₂ molecules which gains more freedom as the spherically symmetrical inert gas atoms dissolve in CO₂. 2006 Article Extraordinary temperature dependence of isochoric thermal conductivity of crystalline CO₂ doped with inert gases / V.A. Konstantinov, V.G. Manzhelii, V.P. Revyakin, V.V. Sagan // Физика низких температур. — 2006. — Т. 32, № 11. — С. 1414–1416. — Бібліогр.: 9 назв. — англ. 0132-6414 PACS: 66.70.+f, 63.20.Ls http://dspace.nbuv.gov.ua/handle/123456789/120890 en Физика низких температур Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України
institution Digital Library of Periodicals of National Academy of Sciences of Ukraine
collection DSpace DC
language English
topic Cryocrystals
Cryocrystals
spellingShingle Cryocrystals
Cryocrystals
Konstantinov, V.A.
Manzhelii, V.G.
Revyakin, V.P.
Sagan, V.V.
Extraordinary temperature dependence of isochoric thermal conductivity of crystalline CO₂ doped with inert gases
Физика низких температур
description The isochoric thermal conductivities of solid (CO₂)₀,₉₀₅Kr₀,₀₉₅ and (CO2)₁₋xXex(x = 0.052 and 0.097) solution of different densities was investigated in the temperature interval from 150 K to the onset of melting. An unusual effect of point defects on the thermal conductivity has been detected. In pure CO₂ at T >150 K the isochoric thermal conductivity decreases smoothly with increasing temperature. In contrast, the thermal conductivity of solid CO₂/Kr and CO₂/Xe solutions first decreases passing through a minimum at 200–210 K and then starts to increase with temperature up to the onset of melting. This behavior of the isochoric thermal conductivity is attributed to the rotation of the CO₂ molecules which gains more freedom as the spherically symmetrical inert gas atoms dissolve in CO₂.
format Article
author Konstantinov, V.A.
Manzhelii, V.G.
Revyakin, V.P.
Sagan, V.V.
author_facet Konstantinov, V.A.
Manzhelii, V.G.
Revyakin, V.P.
Sagan, V.V.
author_sort Konstantinov, V.A.
title Extraordinary temperature dependence of isochoric thermal conductivity of crystalline CO₂ doped with inert gases
title_short Extraordinary temperature dependence of isochoric thermal conductivity of crystalline CO₂ doped with inert gases
title_full Extraordinary temperature dependence of isochoric thermal conductivity of crystalline CO₂ doped with inert gases
title_fullStr Extraordinary temperature dependence of isochoric thermal conductivity of crystalline CO₂ doped with inert gases
title_full_unstemmed Extraordinary temperature dependence of isochoric thermal conductivity of crystalline CO₂ doped with inert gases
title_sort extraordinary temperature dependence of isochoric thermal conductivity of crystalline co₂ doped with inert gases
publisher Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України
publishDate 2006
topic_facet Cryocrystals
url http://dspace.nbuv.gov.ua/handle/123456789/120890
citation_txt Extraordinary temperature dependence of isochoric thermal conductivity of crystalline CO₂ doped with inert gases / V.A. Konstantinov, V.G. Manzhelii, V.P. Revyakin, V.V. Sagan // Физика низких температур. — 2006. — Т. 32, № 11. — С. 1414–1416. — Бібліогр.: 9 назв. — англ.
series Физика низких температур
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AT manzheliivg extraordinarytemperaturedependenceofisochoricthermalconductivityofcrystallineco2dopedwithinertgases
AT revyakinvp extraordinarytemperaturedependenceofisochoricthermalconductivityofcrystallineco2dopedwithinertgases
AT saganvv extraordinarytemperaturedependenceofisochoricthermalconductivityofcrystallineco2dopedwithinertgases
first_indexed 2023-10-18T20:37:49Z
last_indexed 2023-10-18T20:37:49Z
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