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Ionic chromophores Xe⁺p (p≤ 4) in multishell rare-gas clusters Xem(NF₃)kNe₇₅₀₀ (m, k ≤ 100) studied with fluorescence spectroscopy
We have studied fluorescence spectra of small Xem and Xem(NF3)k clusters (m, k ≤ 10²) embedded in large host Ne₇₅₀₀ clusters, excited with SR excitation in the VUV spectral region above the Xe⁺(²P₁/₂) atomic limit. The IR emission bands due to ionic chromophores Xe⁺p (p = 2, 3, 4) as well as UV (...
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Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України
2006
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| Series: | Физика низких температур |
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| Online Access: | http://dspace.nbuv.gov.ua/handle/123456789/120892 |
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irk-123456789-1208922017-06-14T03:05:16Z Ionic chromophores Xe⁺p (p≤ 4) in multishell rare-gas clusters Xem(NF₃)kNe₇₅₀₀ (m, k ≤ 100) studied with fluorescence spectroscopy Kanaev, A. Museur, L. Laarmann, T. Muller, T. Clusters We have studied fluorescence spectra of small Xem and Xem(NF3)k clusters (m, k ≤ 10²) embedded in large host Ne₇₅₀₀ clusters, excited with SR excitation in the VUV spectral region above the Xe⁺(²P₁/₂) atomic limit. The IR emission bands due to ionic chromophores Xe⁺p (p = 2, 3, 4) as well as UV (B–X) and visible (C–A) bands due to desorbed Xe⁺F⁻– excimer molecules have been observed. The triatomic Xe₂F excimer emission has only been observed under low-energy excitation close to the lowest xenon exciton absorption band. A competition between ionic and charge-transfer reaction channels is followed as a function of the cluster sizes m and k. 2006 Article Ionic chromophores Xe⁺p (p≤ 4) in multishell rare-gas clusters Xem(NF₃)kNe₇₅₀₀ (m, k ≤ 100) studied with fluorescence spectroscopy / A. Kanaev, L. Museur, T. Laarmann, T. Muller // Физика низких температур. — 2006. — Т. 32, № 11. — С. 1426–1433. — Бібліогр.: 28 назв. — англ. 0132-6414 PACS: 36.40.–c, 36.40.Vz, 33.50.Dq http://dspace.nbuv.gov.ua/handle/123456789/120892 en Физика низких температур Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України |
| institution |
Digital Library of Periodicals of National Academy of Sciences of Ukraine |
| collection |
DSpace DC |
| language |
English |
| topic |
Clusters Clusters |
| spellingShingle |
Clusters Clusters Kanaev, A. Museur, L. Laarmann, T. Muller, T. Ionic chromophores Xe⁺p (p≤ 4) in multishell rare-gas clusters Xem(NF₃)kNe₇₅₀₀ (m, k ≤ 100) studied with fluorescence spectroscopy Физика низких температур |
| description |
We have studied fluorescence spectra of small Xem and Xem(NF3)k clusters (m, k ≤ 10²) embedded
in large host Ne₇₅₀₀ clusters, excited with SR excitation in the VUV spectral region above the
Xe⁺(²P₁/₂) atomic limit. The IR emission bands due to ionic chromophores Xe⁺p (p = 2, 3, 4) as
well as UV (B–X) and visible (C–A) bands due to desorbed Xe⁺F⁻– excimer molecules have been
observed. The triatomic Xe₂F excimer emission has only been observed under low-energy excitation
close to the lowest xenon exciton absorption band. A competition between ionic and
charge-transfer reaction channels is followed as a function of the cluster sizes m and k. |
| format |
Article |
| author |
Kanaev, A. Museur, L. Laarmann, T. Muller, T. |
| author_facet |
Kanaev, A. Museur, L. Laarmann, T. Muller, T. |
| author_sort |
Kanaev, A. |
| title |
Ionic chromophores Xe⁺p (p≤ 4) in multishell rare-gas clusters Xem(NF₃)kNe₇₅₀₀ (m, k ≤ 100) studied with fluorescence spectroscopy |
| title_short |
Ionic chromophores Xe⁺p (p≤ 4) in multishell rare-gas clusters Xem(NF₃)kNe₇₅₀₀ (m, k ≤ 100) studied with fluorescence spectroscopy |
| title_full |
Ionic chromophores Xe⁺p (p≤ 4) in multishell rare-gas clusters Xem(NF₃)kNe₇₅₀₀ (m, k ≤ 100) studied with fluorescence spectroscopy |
| title_fullStr |
Ionic chromophores Xe⁺p (p≤ 4) in multishell rare-gas clusters Xem(NF₃)kNe₇₅₀₀ (m, k ≤ 100) studied with fluorescence spectroscopy |
| title_full_unstemmed |
Ionic chromophores Xe⁺p (p≤ 4) in multishell rare-gas clusters Xem(NF₃)kNe₇₅₀₀ (m, k ≤ 100) studied with fluorescence spectroscopy |
| title_sort |
ionic chromophores xe⁺p (p≤ 4) in multishell rare-gas clusters xem(nf₃)kne₇₅₀₀ (m, k ≤ 100) studied with fluorescence spectroscopy |
| publisher |
Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України |
| publishDate |
2006 |
| topic_facet |
Clusters |
| url |
http://dspace.nbuv.gov.ua/handle/123456789/120892 |
| citation_txt |
Ionic chromophores Xe⁺p (p≤ 4) in multishell rare-gas clusters Xem(NF₃)kNe₇₅₀₀ (m, k ≤ 100) studied with fluorescence spectroscopy / A. Kanaev, L. Museur, T. Laarmann, T. Muller // Физика низких температур. — 2006. — Т. 32, № 11. — С. 1426–1433. — Бібліогр.: 28 назв. — англ. |
| series |
Физика низких температур |
| work_keys_str_mv |
AT kanaeva ionicchromophoresxepp4inmultishellraregasclustersxemnf3kne7500mk100studiedwithfluorescencespectroscopy AT museurl ionicchromophoresxepp4inmultishellraregasclustersxemnf3kne7500mk100studiedwithfluorescencespectroscopy AT laarmannt ionicchromophoresxepp4inmultishellraregasclustersxemnf3kne7500mk100studiedwithfluorescencespectroscopy AT mullert ionicchromophoresxepp4inmultishellraregasclustersxemnf3kne7500mk100studiedwithfluorescencespectroscopy |
| first_indexed |
2023-10-18T20:37:49Z |
| last_indexed |
2023-10-18T20:37:49Z |
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