Photovoltaic and optical properties of a polymer - PbS nanocomposite

Photovoltaic and optical properties of a polymer-PbS nanoparticles in polyvinyl alcohol (PVA) films and the effect of annealing in air at various temperatures on these properties are studied in this work. In the range of 1.0 to 3.7 eV, absorption spectra of PbS nanocomposite films are correctly fitt...

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Дата:2005
Автори: Lutsyk, P., Dzura, L., Kutsenko, A., Vertsimakha, Ya., Sworakowski, J.
Формат: Стаття
Мова:English
Опубліковано: Інститут фізики напівпровідників імені В.Є. Лашкарьова НАН України 2005
Назва видання:Semiconductor Physics Quantum Electronics & Optoelectronics
Онлайн доступ:http://dspace.nbuv.gov.ua/handle/123456789/120969
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Назва журналу:Digital Library of Periodicals of National Academy of Sciences of Ukraine
Цитувати:Photovoltaic and optical properties of a polymer - PbS nanocomposite / P. Lutsyk, L. Dzura, A. Kutsenko, Ya. Vertsimakha, J. Sworakowski // Semiconductor Physics Quantum Electronics & Optoelectronics. — 2005. — Т. 8, № 3. — С. 54-59. — Бібліогр.: 11 назв. — англ.

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Digital Library of Periodicals of National Academy of Sciences of Ukraine
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spelling irk-123456789-1209692017-06-14T03:03:54Z Photovoltaic and optical properties of a polymer - PbS nanocomposite Lutsyk, P. Dzura, L. Kutsenko, A. Vertsimakha, Ya. Sworakowski, J. Photovoltaic and optical properties of a polymer-PbS nanoparticles in polyvinyl alcohol (PVA) films and the effect of annealing in air at various temperatures on these properties are studied in this work. In the range of 1.0 to 3.7 eV, absorption spectra of PbS nanocomposite films are correctly fitted by five Gaussian bands peaking at 1.5, 1.84, 2.41, 3.06, and 3.58 eV. A characteristic feature of the films is the presence of green and blue luminescence with intensity maxima at 2.25 and 3.02 eV, respectively. The luminescence intensity strongly depends on the excitation energy and the annealing temperature in air. The highest intensity of the green luminescence is observed under the excitation with 2.35 eV radiation, whereas the intensity of the blue luminescence peaks under 3.46 eV excitation. After annealing at 370 K, the intensity of the green luminescence decreases a few times whereas the intensity of the blue emission increases. The photovoltaic sensitivity of the PbS nanocomposite films depends on the annealing conditions, attaining the maximum after annealing in air at approximately glass transition temperature of PVA (370 K). The spectral range of the photosensitivity of PbS nanocomposite films is wider than that of CdSe- and CuInS₂-polymer nanocomposite films. 2005 Article Photovoltaic and optical properties of a polymer - PbS nanocomposite / P. Lutsyk, L. Dzura, A. Kutsenko, Ya. Vertsimakha, J. Sworakowski // Semiconductor Physics Quantum Electronics & Optoelectronics. — 2005. — Т. 8, № 3. — С. 54-59. — Бібліогр.: 11 назв. — англ. 1560-8034 PACS: 73.50. Pz, 78.20. –e, 78.67. Bf. http://dspace.nbuv.gov.ua/handle/123456789/120969 en Semiconductor Physics Quantum Electronics & Optoelectronics Інститут фізики напівпровідників імені В.Є. Лашкарьова НАН України
institution Digital Library of Periodicals of National Academy of Sciences of Ukraine
collection DSpace DC
language English
description Photovoltaic and optical properties of a polymer-PbS nanoparticles in polyvinyl alcohol (PVA) films and the effect of annealing in air at various temperatures on these properties are studied in this work. In the range of 1.0 to 3.7 eV, absorption spectra of PbS nanocomposite films are correctly fitted by five Gaussian bands peaking at 1.5, 1.84, 2.41, 3.06, and 3.58 eV. A characteristic feature of the films is the presence of green and blue luminescence with intensity maxima at 2.25 and 3.02 eV, respectively. The luminescence intensity strongly depends on the excitation energy and the annealing temperature in air. The highest intensity of the green luminescence is observed under the excitation with 2.35 eV radiation, whereas the intensity of the blue luminescence peaks under 3.46 eV excitation. After annealing at 370 K, the intensity of the green luminescence decreases a few times whereas the intensity of the blue emission increases. The photovoltaic sensitivity of the PbS nanocomposite films depends on the annealing conditions, attaining the maximum after annealing in air at approximately glass transition temperature of PVA (370 K). The spectral range of the photosensitivity of PbS nanocomposite films is wider than that of CdSe- and CuInS₂-polymer nanocomposite films.
format Article
author Lutsyk, P.
Dzura, L.
Kutsenko, A.
Vertsimakha, Ya.
Sworakowski, J.
spellingShingle Lutsyk, P.
Dzura, L.
Kutsenko, A.
Vertsimakha, Ya.
Sworakowski, J.
Photovoltaic and optical properties of a polymer - PbS nanocomposite
Semiconductor Physics Quantum Electronics & Optoelectronics
author_facet Lutsyk, P.
Dzura, L.
Kutsenko, A.
Vertsimakha, Ya.
Sworakowski, J.
author_sort Lutsyk, P.
title Photovoltaic and optical properties of a polymer - PbS nanocomposite
title_short Photovoltaic and optical properties of a polymer - PbS nanocomposite
title_full Photovoltaic and optical properties of a polymer - PbS nanocomposite
title_fullStr Photovoltaic and optical properties of a polymer - PbS nanocomposite
title_full_unstemmed Photovoltaic and optical properties of a polymer - PbS nanocomposite
title_sort photovoltaic and optical properties of a polymer - pbs nanocomposite
publisher Інститут фізики напівпровідників імені В.Є. Лашкарьова НАН України
publishDate 2005
url http://dspace.nbuv.gov.ua/handle/123456789/120969
citation_txt Photovoltaic and optical properties of a polymer - PbS nanocomposite / P. Lutsyk, L. Dzura, A. Kutsenko, Ya. Vertsimakha, J. Sworakowski // Semiconductor Physics Quantum Electronics & Optoelectronics. — 2005. — Т. 8, № 3. — С. 54-59. — Бібліогр.: 11 назв. — англ.
series Semiconductor Physics Quantum Electronics & Optoelectronics
work_keys_str_mv AT lutsykp photovoltaicandopticalpropertiesofapolymerpbsnanocomposite
AT dzural photovoltaicandopticalpropertiesofapolymerpbsnanocomposite
AT kutsenkoa photovoltaicandopticalpropertiesofapolymerpbsnanocomposite
AT vertsimakhaya photovoltaicandopticalpropertiesofapolymerpbsnanocomposite
AT sworakowskij photovoltaicandopticalpropertiesofapolymerpbsnanocomposite
first_indexed 2023-10-18T20:38:31Z
last_indexed 2023-10-18T20:38:31Z
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