The application of the associative mean spherical approximation in the theory of nonaqueous electrolyte solutions
Ionic association in electrolyte solutions is investigated in the framework of chemical models. The associative mean spherical approximation (AMSA) for electrolyte theory is reviewed. It is shown that AMSA in combination with the Ebeling association constant satisfactorily reproduces the thermody...
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| Дата: | 2000 |
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| Автори: | , , , , |
| Формат: | Стаття |
| Мова: | English |
| Опубліковано: |
Інститут фізики конденсованих систем НАН України
2000
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| Назва видання: | Condensed Matter Physics |
| Онлайн доступ: | http://dspace.nbuv.gov.ua/handle/123456789/121004 |
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| Назва журналу: | Digital Library of Periodicals of National Academy of Sciences of Ukraine |
| Цитувати: | The application of the associative mean spherical approximation in the theory of nonaqueous electrolyte solutions / J. Barthel, H. Krienke, M.F. Holovko, V.I. Kapko, I.A. Protsykevich // Condensed Matter Physics. — 2000. — Т. 3, № 3(23). — С. 657-674. — Бібліогр.: 31 назв. — англ. |
Репозитарії
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irk-123456789-1210042017-06-14T03:06:03Z The application of the associative mean spherical approximation in the theory of nonaqueous electrolyte solutions Barthel, J. Krienke, H. Holovko, M.F. Kapko, V.I. Protsykevich, I.A. Ionic association in electrolyte solutions is investigated in the framework of chemical models. The associative mean spherical approximation (AMSA) for electrolyte theory is reviewed. It is shown that AMSA in combination with the Ebeling association constant satisfactorily reproduces the thermodynamic measurement data up to high concentrations for nonaqueous solutions of solvents of relative permittivities in the range 20 < ε < 36 . For ionic solutions of lower permittivity the AMSA is modified by including ion trimers and tetramers to obtain a correct description of osmotic coefficients and ionic conductivities. Іонна асоціація в розчинах електролітів досліджується в рамках хімічних моделей. Дано огляд асоціативного середньосферичного наближення (АССН) в теорії електролітів. Показано, що АССН у комбінації з асоціативною константою Ебелінга задовільно відтворює дані термодинамічних вимірювань, включаючи область високих концентрацій, для неводних розчинів електролітів з розчинниками з діелектричною проникністю в області 20 < ε < 36 . Для іонних розчинів з низькою діелектричною проникністю АССН модифіковане включенням іонних тримерів і тетрамерів, щоб отримати правильний опис осмотичних коефіцієнтів та іонних провідностей. 2000 Article The application of the associative mean spherical approximation in the theory of nonaqueous electrolyte solutions / J. Barthel, H. Krienke, M.F. Holovko, V.I. Kapko, I.A. Protsykevich // Condensed Matter Physics. — 2000. — Т. 3, № 3(23). — С. 657-674. — Бібліогр.: 31 назв. — англ. 1607-324X DOI:10.5488/CMP.3.3.657 PACS: 61.20.Qg, 66.10.Ed http://dspace.nbuv.gov.ua/handle/123456789/121004 en Condensed Matter Physics Інститут фізики конденсованих систем НАН України |
| institution |
Digital Library of Periodicals of National Academy of Sciences of Ukraine |
| collection |
DSpace DC |
| language |
English |
| description |
Ionic association in electrolyte solutions is investigated in the framework of
chemical models. The associative mean spherical approximation (AMSA)
for electrolyte theory is reviewed. It is shown that AMSA in combination
with the Ebeling association constant satisfactorily reproduces the thermodynamic measurement data up to high concentrations for nonaqueous
solutions of solvents of relative permittivities in the range 20 < ε < 36 . For
ionic solutions of lower permittivity the AMSA is modified by including ion
trimers and tetramers to obtain a correct description of osmotic coefficients
and ionic conductivities. |
| format |
Article |
| author |
Barthel, J. Krienke, H. Holovko, M.F. Kapko, V.I. Protsykevich, I.A. |
| spellingShingle |
Barthel, J. Krienke, H. Holovko, M.F. Kapko, V.I. Protsykevich, I.A. The application of the associative mean spherical approximation in the theory of nonaqueous electrolyte solutions Condensed Matter Physics |
| author_facet |
Barthel, J. Krienke, H. Holovko, M.F. Kapko, V.I. Protsykevich, I.A. |
| author_sort |
Barthel, J. |
| title |
The application of the associative mean spherical approximation in the theory of nonaqueous electrolyte solutions |
| title_short |
The application of the associative mean spherical approximation in the theory of nonaqueous electrolyte solutions |
| title_full |
The application of the associative mean spherical approximation in the theory of nonaqueous electrolyte solutions |
| title_fullStr |
The application of the associative mean spherical approximation in the theory of nonaqueous electrolyte solutions |
| title_full_unstemmed |
The application of the associative mean spherical approximation in the theory of nonaqueous electrolyte solutions |
| title_sort |
application of the associative mean spherical approximation in the theory of nonaqueous electrolyte solutions |
| publisher |
Інститут фізики конденсованих систем НАН України |
| publishDate |
2000 |
| url |
http://dspace.nbuv.gov.ua/handle/123456789/121004 |
| citation_txt |
The application of the associative mean spherical approximation in the theory of nonaqueous electrolyte solutions / J. Barthel, H. Krienke, M.F. Holovko, V.I. Kapko, I.A. Protsykevich // Condensed Matter Physics. — 2000. — Т. 3, № 3(23). — С. 657-674. — Бібліогр.: 31 назв. — англ. |
| series |
Condensed Matter Physics |
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2023-10-18T20:38:42Z |
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