The application of the associative mean spherical approximation in the theory of nonaqueous electrolyte solutions

Ionic association in electrolyte solutions is investigated in the framework of chemical models. The associative mean spherical approximation (AMSA) for electrolyte theory is reviewed. It is shown that AMSA in combination with the Ebeling association constant satisfactorily reproduces the thermody...

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Дата:2000
Автори: Barthel, J., Krienke, H., Holovko, M.F., Kapko, V.I., Protsykevich, I.A.
Формат: Стаття
Мова:English
Опубліковано: Інститут фізики конденсованих систем НАН України 2000
Назва видання:Condensed Matter Physics
Онлайн доступ:http://dspace.nbuv.gov.ua/handle/123456789/121004
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Назва журналу:Digital Library of Periodicals of National Academy of Sciences of Ukraine
Цитувати:The application of the associative mean spherical approximation in the theory of nonaqueous electrolyte solutions / J. Barthel, H. Krienke, M.F. Holovko, V.I. Kapko, I.A. Protsykevich // Condensed Matter Physics. — 2000. — Т. 3, № 3(23). — С. 657-674. — Бібліогр.: 31 назв. — англ.

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Digital Library of Periodicals of National Academy of Sciences of Ukraine
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spelling irk-123456789-1210042017-06-14T03:06:03Z The application of the associative mean spherical approximation in the theory of nonaqueous electrolyte solutions Barthel, J. Krienke, H. Holovko, M.F. Kapko, V.I. Protsykevich, I.A. Ionic association in electrolyte solutions is investigated in the framework of chemical models. The associative mean spherical approximation (AMSA) for electrolyte theory is reviewed. It is shown that AMSA in combination with the Ebeling association constant satisfactorily reproduces the thermodynamic measurement data up to high concentrations for nonaqueous solutions of solvents of relative permittivities in the range 20 < ε < 36 . For ionic solutions of lower permittivity the AMSA is modified by including ion trimers and tetramers to obtain a correct description of osmotic coefficients and ionic conductivities. Іонна асоціація в розчинах електролітів досліджується в рамках хімічних моделей. Дано огляд асоціативного середньосферичного наближення (АССН) в теорії електролітів. Показано, що АССН у комбінації з асоціативною константою Ебелінга задовільно відтворює дані термодинамічних вимірювань, включаючи область високих концентрацій, для неводних розчинів електролітів з розчинниками з діелектричною проникністю в області 20 < ε < 36 . Для іонних розчинів з низькою діелектричною проникністю АССН модифіковане включенням іонних тримерів і тетрамерів, щоб отримати правильний опис осмотичних коефіцієнтів та іонних провідностей. 2000 Article The application of the associative mean spherical approximation in the theory of nonaqueous electrolyte solutions / J. Barthel, H. Krienke, M.F. Holovko, V.I. Kapko, I.A. Protsykevich // Condensed Matter Physics. — 2000. — Т. 3, № 3(23). — С. 657-674. — Бібліогр.: 31 назв. — англ. 1607-324X DOI:10.5488/CMP.3.3.657 PACS: 61.20.Qg, 66.10.Ed http://dspace.nbuv.gov.ua/handle/123456789/121004 en Condensed Matter Physics Інститут фізики конденсованих систем НАН України
institution Digital Library of Periodicals of National Academy of Sciences of Ukraine
collection DSpace DC
language English
description Ionic association in electrolyte solutions is investigated in the framework of chemical models. The associative mean spherical approximation (AMSA) for electrolyte theory is reviewed. It is shown that AMSA in combination with the Ebeling association constant satisfactorily reproduces the thermodynamic measurement data up to high concentrations for nonaqueous solutions of solvents of relative permittivities in the range 20 < ε < 36 . For ionic solutions of lower permittivity the AMSA is modified by including ion trimers and tetramers to obtain a correct description of osmotic coefficients and ionic conductivities.
format Article
author Barthel, J.
Krienke, H.
Holovko, M.F.
Kapko, V.I.
Protsykevich, I.A.
spellingShingle Barthel, J.
Krienke, H.
Holovko, M.F.
Kapko, V.I.
Protsykevich, I.A.
The application of the associative mean spherical approximation in the theory of nonaqueous electrolyte solutions
Condensed Matter Physics
author_facet Barthel, J.
Krienke, H.
Holovko, M.F.
Kapko, V.I.
Protsykevich, I.A.
author_sort Barthel, J.
title The application of the associative mean spherical approximation in the theory of nonaqueous electrolyte solutions
title_short The application of the associative mean spherical approximation in the theory of nonaqueous electrolyte solutions
title_full The application of the associative mean spherical approximation in the theory of nonaqueous electrolyte solutions
title_fullStr The application of the associative mean spherical approximation in the theory of nonaqueous electrolyte solutions
title_full_unstemmed The application of the associative mean spherical approximation in the theory of nonaqueous electrolyte solutions
title_sort application of the associative mean spherical approximation in the theory of nonaqueous electrolyte solutions
publisher Інститут фізики конденсованих систем НАН України
publishDate 2000
url http://dspace.nbuv.gov.ua/handle/123456789/121004
citation_txt The application of the associative mean spherical approximation in the theory of nonaqueous electrolyte solutions / J. Barthel, H. Krienke, M.F. Holovko, V.I. Kapko, I.A. Protsykevich // Condensed Matter Physics. — 2000. — Т. 3, № 3(23). — С. 657-674. — Бібліогр.: 31 назв. — англ.
series Condensed Matter Physics
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