Growth kinetics of PbS nanocrystals in organo-metallic Langmuir-Blodgett films studied by optical absorption spectroscopy
Formation and growth of lead sulfide nanocrystals in lead stearate Langmuir-Blodgett (LB) films are investigated using the optical absorption spectroscopy method. The kinetics of changes in the concentration of lead ions in different states formed during the growth process, as well as the evolution...
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| Дата: | 2002 |
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| Автор: | |
| Формат: | Стаття |
| Мова: | English |
| Опубліковано: |
Інститут фізики напівпровідників імені В.Є. Лашкарьова НАН України
2002
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| Назва видання: | Semiconductor Physics Quantum Electronics & Optoelectronics |
| Онлайн доступ: | http://dspace.nbuv.gov.ua/handle/123456789/121334 |
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| Назва журналу: | Digital Library of Periodicals of National Academy of Sciences of Ukraine |
| Цитувати: | Growth kinetics of PbS nanocrystals in organo-metallic Langmuir-Blodgett films studied by optical absorption spectroscopy / Yu.N. Savin // Semiconductor Physics Quantum Electronics & Optoelectronics. — 2002. — Т. 5, № 3. — С. 337-341. — Бібліогр.: 14 назв. — англ. |
Репозитарії
Digital Library of Periodicals of National Academy of Sciences of Ukraine| id |
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irk-123456789-1213342017-06-15T03:05:15Z Growth kinetics of PbS nanocrystals in organo-metallic Langmuir-Blodgett films studied by optical absorption spectroscopy Savin, Yu.N. Formation and growth of lead sulfide nanocrystals in lead stearate Langmuir-Blodgett (LB) films are investigated using the optical absorption spectroscopy method. The kinetics of changes in the concentration of lead ions in different states formed during the growth process, as well as the evolution of the nanocrystal average size versus growth time, are studied. Irrespective of the primary Pb2+ ion concentration in films, found was a nonlinear dependence of the nanoparticle growth rate vs time: at the initial stage the growth rate is higher than at the final one. The idea of diffusive decomposition of solid solution is used to analyze the experimental results. It is shown that high concentrations of metal ions at the interfaces of LB-film monolayers as well as diffusion restrictions of mass-transfer process play a decisive role in the formation and growth of nanocrystals in ordered organic matrixes. 2002 Article Growth kinetics of PbS nanocrystals in organo-metallic Langmuir-Blodgett films studied by optical absorption spectroscopy / Yu.N. Savin // Semiconductor Physics Quantum Electronics & Optoelectronics. — 2002. — Т. 5, № 3. — С. 337-341. — Бібліогр.: 14 назв. — англ. 1560-8034 PACS: 68.18.+p, 78.67 Bf http://dspace.nbuv.gov.ua/handle/123456789/121334 en Semiconductor Physics Quantum Electronics & Optoelectronics Інститут фізики напівпровідників імені В.Є. Лашкарьова НАН України |
| institution |
Digital Library of Periodicals of National Academy of Sciences of Ukraine |
| collection |
DSpace DC |
| language |
English |
| description |
Formation and growth of lead sulfide nanocrystals in lead stearate Langmuir-Blodgett (LB) films are investigated using the optical absorption spectroscopy method. The kinetics of changes in the concentration of lead ions in different states formed during the growth process, as well as the evolution of the nanocrystal average size versus growth time, are studied. Irrespective of the primary Pb2+ ion concentration in films, found was a nonlinear dependence of the nanoparticle growth rate vs time: at the initial stage the growth rate is higher than at the final one. The idea of diffusive decomposition of solid solution is used to analyze the experimental results. It is shown that high concentrations of metal ions at the interfaces of LB-film monolayers as well as diffusion restrictions of mass-transfer process play a decisive role in the formation and growth of nanocrystals in ordered organic matrixes. |
| format |
Article |
| author |
Savin, Yu.N. |
| spellingShingle |
Savin, Yu.N. Growth kinetics of PbS nanocrystals in organo-metallic Langmuir-Blodgett films studied by optical absorption spectroscopy Semiconductor Physics Quantum Electronics & Optoelectronics |
| author_facet |
Savin, Yu.N. |
| author_sort |
Savin, Yu.N. |
| title |
Growth kinetics of PbS nanocrystals in organo-metallic Langmuir-Blodgett films studied by optical absorption spectroscopy |
| title_short |
Growth kinetics of PbS nanocrystals in organo-metallic Langmuir-Blodgett films studied by optical absorption spectroscopy |
| title_full |
Growth kinetics of PbS nanocrystals in organo-metallic Langmuir-Blodgett films studied by optical absorption spectroscopy |
| title_fullStr |
Growth kinetics of PbS nanocrystals in organo-metallic Langmuir-Blodgett films studied by optical absorption spectroscopy |
| title_full_unstemmed |
Growth kinetics of PbS nanocrystals in organo-metallic Langmuir-Blodgett films studied by optical absorption spectroscopy |
| title_sort |
growth kinetics of pbs nanocrystals in organo-metallic langmuir-blodgett films studied by optical absorption spectroscopy |
| publisher |
Інститут фізики напівпровідників імені В.Є. Лашкарьова НАН України |
| publishDate |
2002 |
| url |
http://dspace.nbuv.gov.ua/handle/123456789/121334 |
| citation_txt |
Growth kinetics of PbS nanocrystals in organo-metallic Langmuir-Blodgett films studied by optical absorption spectroscopy / Yu.N. Savin // Semiconductor Physics Quantum Electronics & Optoelectronics. — 2002. — Т. 5, № 3. — С. 337-341. — Бібліогр.: 14 назв. — англ. |
| series |
Semiconductor Physics Quantum Electronics & Optoelectronics |
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AT savinyun growthkineticsofpbsnanocrystalsinorganometalliclangmuirblodgettfilmsstudiedbyopticalabsorptionspectroscopy |
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2023-10-18T20:39:12Z |
| last_indexed |
2023-10-18T20:39:12Z |
| _version_ |
1796150761482092544 |