Heat capacity of p-H₂–p-D₂–Ne solid solution: Effect of (p-D₂)Ne clusters

The heat capacity of a solid solution of 1% p-D₂ and 0.25% Ne in p-H₂ has been investigated in the interval ΔT = 0.5–4 K. An excess heat capacity ΔCNe of this solution exceeding the heat capacity of the 1% p-D₂ in p-H₂ solution has been detected and analyzed. It is found that below 2 K the domina...

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Бібліографічні деталі
Дата:2005
Автори: Bagatskii, M.I., Minchina, I.Ya., Bagatskii, V.M.
Формат: Стаття
Мова:English
Опубліковано: Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України 2005
Назва видання:Физика низких температур
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Онлайн доступ:http://dspace.nbuv.gov.ua/handle/123456789/121480
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Назва журналу:Digital Library of Periodicals of National Academy of Sciences of Ukraine
Цитувати:Heat capacity of p-H₂–p-D₂–Ne solid solution: Effect of (p-D₂)Ne clusters / M.I. Bagatskii, I.Ya. Minchina, V.M. Bagatskii // Физика низких температур. — 2005. — Т. 31, № 6. — С. 620-623. — Бібліогр.: 15 назв. — англ.

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Digital Library of Periodicals of National Academy of Sciences of Ukraine
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Резюме:The heat capacity of a solid solution of 1% p-D₂ and 0.25% Ne in p-H₂ has been investigated in the interval ΔT = 0.5–4 K. An excess heat capacity ΔCNe of this solution exceeding the heat capacity of the 1% p-D₂ in p-H₂ solution has been detected and analyzed. It is found that below 2 K the dominant contribution to the heat capacity ΔCNe is made by the rotation of the p-D₂ molecules in the (p-D₂)Ne type clusters. The number of (p-D₂)Ne clusters in the solid sample is strongly dependent on the conditions of preparation. The splitting of the J = 1 level of the p-D₂ molecules in the (p-D₂)Ne clusters Δ = 3.2 K is consistent with the theoretical estimate.