Polyassociative thermodynamical model of A²B⁶ semiconductor melt and phase equilibrium in Cd-Hg-Te system: 3. Optimization of the thermodynamical functions of the model and quasi-binary structural diagram of Cd-Hg-Te system
Within the frames of the model of the polyassociative solutions the comparative analysis was performed of the formation parameters of multi-atom complexes in CdTe and Hg-Te systems. It was shown, that thermodynamical properties of the studied systems can be described in the supposition of the presen...
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| Дата: | 2005 |
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| Автори: | , , |
| Формат: | Стаття |
| Мова: | English |
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Інститут фізики напівпровідників імені В.Є. Лашкарьова НАН України
2005
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| Назва видання: | Semiconductor Physics Quantum Electronics & Optoelectronics |
| Онлайн доступ: | http://dspace.nbuv.gov.ua/handle/123456789/121650 |
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| Назва журналу: | Digital Library of Periodicals of National Academy of Sciences of Ukraine |
| Цитувати: | Polyassociative thermodynamical model of A²B⁶ semiconductor melt and phase equilibrium in Cd-Hg-Te system: 3. Optimization of the thermodynamical functions of the model and quasi-binary structural diagram of Cd-Hg-Te system / Moskvin P.P., Rashkovetskiy L.V., Stronski A.V. // Semiconductor Physics Quantum Electronics & Optoelectronics. — 2005. — Т. 8, № 2. — С. 81-85. — Бібліогр.: 12 назв. — англ. |
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Digital Library of Periodicals of National Academy of Sciences of Ukraine| id |
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irk-123456789-1216502017-06-16T03:03:15Z Polyassociative thermodynamical model of A²B⁶ semiconductor melt and phase equilibrium in Cd-Hg-Te system: 3. Optimization of the thermodynamical functions of the model and quasi-binary structural diagram of Cd-Hg-Te system P.P., Moskvin L.V., Rashkovetskiy A.V., Stronski Within the frames of the model of the polyassociative solutions the comparative analysis was performed of the formation parameters of multi-atom complexes in CdTe and Hg-Te systems. It was shown, that thermodynamical properties of the studied systems can be described in the supposition of the presence in the liquid phase of the ATe, A₂Te₃, ATe₂, A₂Te (A = Cd, Hg) and free Te, Cd, Hg atoms. In accordance with the model of polyassociative solutions the data on p–T–x equilibrium in the region of quasi-binary cross-section of Cd-Hg-Te system structural diagram were obtained. It was shown, that the mixing effects in the three-component liquid phase are satisfactorily described by the formation of CdHgTe and CdHgTe₃ associates. The good correspondence of the calculations and experiment in the high temperature part of the Cd-Hg-Te system structural diagram was achieved. 2005 Article Polyassociative thermodynamical model of A²B⁶ semiconductor melt and phase equilibrium in Cd-Hg-Te system: 3. Optimization of the thermodynamical functions of the model and quasi-binary structural diagram of Cd-Hg-Te system / Moskvin P.P., Rashkovetskiy L.V., Stronski A.V. // Semiconductor Physics Quantum Electronics & Optoelectronics. — 2005. — Т. 8, № 2. — С. 81-85. — Бібліогр.: 12 назв. — англ. 1560-8034 PACS: 64.90.+b http://dspace.nbuv.gov.ua/handle/123456789/121650 en Semiconductor Physics Quantum Electronics & Optoelectronics Інститут фізики напівпровідників імені В.Є. Лашкарьова НАН України |
| institution |
Digital Library of Periodicals of National Academy of Sciences of Ukraine |
| collection |
DSpace DC |
| language |
English |
| description |
Within the frames of the model of the polyassociative solutions the comparative analysis was performed of the formation parameters of multi-atom complexes in CdTe and Hg-Te systems. It was shown, that thermodynamical properties of the studied systems can be described in the supposition of the presence in the liquid phase of the ATe, A₂Te₃, ATe₂, A₂Te (A = Cd, Hg) and free Te, Cd, Hg atoms. In accordance with the model of polyassociative solutions the data on p–T–x equilibrium in the region of quasi-binary cross-section of Cd-Hg-Te system structural diagram were obtained. It was shown, that the mixing effects in the three-component liquid phase are satisfactorily described by the formation of CdHgTe and CdHgTe₃ associates. The good correspondence of the calculations and experiment in the high temperature part of the Cd-Hg-Te system structural diagram was achieved. |
| format |
Article |
| author |
P.P., Moskvin L.V., Rashkovetskiy A.V., Stronski |
| spellingShingle |
P.P., Moskvin L.V., Rashkovetskiy A.V., Stronski Polyassociative thermodynamical model of A²B⁶ semiconductor melt and phase equilibrium in Cd-Hg-Te system: 3. Optimization of the thermodynamical functions of the model and quasi-binary structural diagram of Cd-Hg-Te system Semiconductor Physics Quantum Electronics & Optoelectronics |
| author_facet |
P.P., Moskvin L.V., Rashkovetskiy A.V., Stronski |
| author_sort |
P.P., Moskvin |
| title |
Polyassociative thermodynamical model of A²B⁶ semiconductor melt and phase equilibrium in Cd-Hg-Te system: 3. Optimization of the thermodynamical functions of the model and quasi-binary structural diagram of Cd-Hg-Te system |
| title_short |
Polyassociative thermodynamical model of A²B⁶ semiconductor melt and phase equilibrium in Cd-Hg-Te system: 3. Optimization of the thermodynamical functions of the model and quasi-binary structural diagram of Cd-Hg-Te system |
| title_full |
Polyassociative thermodynamical model of A²B⁶ semiconductor melt and phase equilibrium in Cd-Hg-Te system: 3. Optimization of the thermodynamical functions of the model and quasi-binary structural diagram of Cd-Hg-Te system |
| title_fullStr |
Polyassociative thermodynamical model of A²B⁶ semiconductor melt and phase equilibrium in Cd-Hg-Te system: 3. Optimization of the thermodynamical functions of the model and quasi-binary structural diagram of Cd-Hg-Te system |
| title_full_unstemmed |
Polyassociative thermodynamical model of A²B⁶ semiconductor melt and phase equilibrium in Cd-Hg-Te system: 3. Optimization of the thermodynamical functions of the model and quasi-binary structural diagram of Cd-Hg-Te system |
| title_sort |
polyassociative thermodynamical model of a²b⁶ semiconductor melt and phase equilibrium in cd-hg-te system: 3. optimization of the thermodynamical functions of the model and quasi-binary structural diagram of cd-hg-te system |
| publisher |
Інститут фізики напівпровідників імені В.Є. Лашкарьова НАН України |
| publishDate |
2005 |
| url |
http://dspace.nbuv.gov.ua/handle/123456789/121650 |
| citation_txt |
Polyassociative thermodynamical model of A²B⁶ semiconductor melt and phase equilibrium in Cd-Hg-Te system: 3. Optimization of the thermodynamical functions of the model and quasi-binary structural diagram of Cd-Hg-Te system
/ Moskvin P.P., Rashkovetskiy L.V., Stronski A.V. // Semiconductor Physics Quantum Electronics & Optoelectronics. — 2005. — Т. 8, № 2. — С. 81-85. — Бібліогр.: 12 назв. — англ. |
| series |
Semiconductor Physics Quantum Electronics & Optoelectronics |
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2023-10-18T20:39:58Z |
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