Structure of quench condensed nH₂–N₂ binary alloys: isotope effect

Structure of quench condensed nH₂–N₂ alloys was investigated by powder x-ray diffraction over a wide range of temperatures, compositions, and rates of deposition. The structure of the deposits is shown to depend on the condensation regime. Under mild regime, no solid nitrogen reflections from hydr...

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Дата:2007
Автори: Galtsov, N.N., Prokhvatilov, A.I., Strzhemechny, M.A.
Формат: Стаття
Мова:English
Опубліковано: Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України 2007
Назва видання:Физика низких температур
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Онлайн доступ:http://dspace.nbuv.gov.ua/handle/123456789/121784
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Назва журналу:Digital Library of Periodicals of National Academy of Sciences of Ukraine
Цитувати:Structure of quench condensed nH₂–N₂ binary alloys: isotope effect / N.N. Galtsov, A.I. Prokhvatilov, M.A. Strzhemechny // Физика низких температур. — 2007. — Т. 33, № 6-7. — С. 668-672. — Бібліогр.: 19 назв. — англ.

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Digital Library of Periodicals of National Academy of Sciences of Ukraine
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spelling irk-123456789-1217842017-06-17T03:03:09Z Structure of quench condensed nH₂–N₂ binary alloys: isotope effect Galtsov, N.N. Prokhvatilov, A.I. Strzhemechny, M.A. Quantum Crystals Structure of quench condensed nH₂–N₂ alloys was investigated by powder x-ray diffraction over a wide range of temperatures, compositions, and rates of deposition. The structure of the deposits is shown to depend on the condensation regime. Under mild regime, no solid nitrogen reflections from hydrogen-rich deposits were observed. When the temperature is increased to the hydrogen triple point, nitrogen lines appear at substantially larger angles compared to pure N₂, which suggests presence of dissolved hydrogen. The quantum nature of this hydrogen is suppressed in the nitrogen matrix. The samples grown in mild regime exhibit the highest apparent solubility (up to 25%) of hydrogen in solid N₂. When H₂ is substituted by D₂, the isotope effect consists in a wider range of mono-phase states based on the nitrogen cubic lattice, which can accommodate up to 70% of deuterium, if grown under mild regime. 2007 Article Structure of quench condensed nH₂–N₂ binary alloys: isotope effect / N.N. Galtsov, A.I. Prokhvatilov, M.A. Strzhemechny // Физика низких температур. — 2007. — Т. 33, № 6-7. — С. 668-672. — Бібліогр.: 19 назв. — англ. 0132-6414 PACS: 78.55.Kz; 31.50.+w http://dspace.nbuv.gov.ua/handle/123456789/121784 en Физика низких температур Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України
institution Digital Library of Periodicals of National Academy of Sciences of Ukraine
collection DSpace DC
language English
topic Quantum Crystals
Quantum Crystals
spellingShingle Quantum Crystals
Quantum Crystals
Galtsov, N.N.
Prokhvatilov, A.I.
Strzhemechny, M.A.
Structure of quench condensed nH₂–N₂ binary alloys: isotope effect
Физика низких температур
description Structure of quench condensed nH₂–N₂ alloys was investigated by powder x-ray diffraction over a wide range of temperatures, compositions, and rates of deposition. The structure of the deposits is shown to depend on the condensation regime. Under mild regime, no solid nitrogen reflections from hydrogen-rich deposits were observed. When the temperature is increased to the hydrogen triple point, nitrogen lines appear at substantially larger angles compared to pure N₂, which suggests presence of dissolved hydrogen. The quantum nature of this hydrogen is suppressed in the nitrogen matrix. The samples grown in mild regime exhibit the highest apparent solubility (up to 25%) of hydrogen in solid N₂. When H₂ is substituted by D₂, the isotope effect consists in a wider range of mono-phase states based on the nitrogen cubic lattice, which can accommodate up to 70% of deuterium, if grown under mild regime.
format Article
author Galtsov, N.N.
Prokhvatilov, A.I.
Strzhemechny, M.A.
author_facet Galtsov, N.N.
Prokhvatilov, A.I.
Strzhemechny, M.A.
author_sort Galtsov, N.N.
title Structure of quench condensed nH₂–N₂ binary alloys: isotope effect
title_short Structure of quench condensed nH₂–N₂ binary alloys: isotope effect
title_full Structure of quench condensed nH₂–N₂ binary alloys: isotope effect
title_fullStr Structure of quench condensed nH₂–N₂ binary alloys: isotope effect
title_full_unstemmed Structure of quench condensed nH₂–N₂ binary alloys: isotope effect
title_sort structure of quench condensed nh₂–n₂ binary alloys: isotope effect
publisher Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України
publishDate 2007
topic_facet Quantum Crystals
url http://dspace.nbuv.gov.ua/handle/123456789/121784
citation_txt Structure of quench condensed nH₂–N₂ binary alloys: isotope effect / N.N. Galtsov, A.I. Prokhvatilov, M.A. Strzhemechny // Физика низких температур. — 2007. — Т. 33, № 6-7. — С. 668-672. — Бібліогр.: 19 назв. — англ.
series Физика низких температур
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AT prokhvatilovai structureofquenchcondensednh2n2binaryalloysisotopeeffect
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first_indexed 2023-10-18T20:40:18Z
last_indexed 2023-10-18T20:40:18Z
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