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Effect of nanostructuration on compressibility of cubic BN

Compressibility of high-purity nanostructured cBN has been studied under quasi-hydrostatic conditions at 300 K up to 35 GPa using diamond anvil cell and angle-dispersive synchrotron powder X-ray diffraction. It has been found that the data fit to the Vinet equation of state yields the values of the...

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Bibliographic Details
Main Authors: Le Godec, Y., Kurakevych, O.O., Munsch, P., Garbarino, G., Mezouar, M., Solozhenko, V.L.
Format: Article
Language:English
Published: Інститут надтвердих матеріалів ім. В.М. Бакуля НАН України 2012
Series:Сверхтвердые материалы
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Online Access:http://dspace.nbuv.gov.ua/handle/123456789/126003
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Summary:Compressibility of high-purity nanostructured cBN has been studied under quasi-hydrostatic conditions at 300 K up to 35 GPa using diamond anvil cell and angle-dispersive synchrotron powder X-ray diffraction. It has been found that the data fit to the Vinet equation of state yields the values of the bulk modulus B₀ of 375(4) GPa with its first pressure derivative B₀´ of 2.3(3), thus, the nanometer grain size (≈ 20 nm) results in a decrease of the bulk modulus by ≈ 9‰.