Charge-ordering induces magnetic axes rotation in organic materials (TMTTF)₂X (with X = SbF₆, AsF₆, and PF₆)

We have performed a comprehensive EPR investigation of the quasi-one-dimensional organic systems (TMTTF)₂X with centrosymmetrical anions X (X = SbF₆, AsF₆, and PF₆). We observe a strong rotation of g-factor principal axes when the temperature decreases below charge-ordering temperature TCO. The po...

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Дата:2015
Автори: Dutoit, C.-E., Bertaina, S., Orio, M., Dressel, M., Stepanov, A.
Формат: Стаття
Мова:English
Опубліковано: Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України 2015
Назва видання:Физика низких температур
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Онлайн доступ:http://dspace.nbuv.gov.ua/handle/123456789/128242
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Назва журналу:Digital Library of Periodicals of National Academy of Sciences of Ukraine
Цитувати:Charge-ordering induces magnetic axes rotation in organic materials (TMTTF)₂X (with X = SbF₆, AsF₆, and PF₆) / C.-E. Dutoit, S. Bertaina, M. Orio, M. Dressel, A. Stepanov // Физика низких температур. — 2015. — Т. 41, № 11. — С. 1206–1208. — Бібліогр.: 16 назв. — англ.

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Digital Library of Periodicals of National Academy of Sciences of Ukraine
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spelling irk-123456789-1282422018-01-08T03:04:14Z Charge-ordering induces magnetic axes rotation in organic materials (TMTTF)₂X (with X = SbF₆, AsF₆, and PF₆) Dutoit, C.-E. Bertaina, S. Orio, M. Dressel, M. Stepanov, A. Кpаткие сообщения We have performed a comprehensive EPR investigation of the quasi-one-dimensional organic systems (TMTTF)₂X with centrosymmetrical anions X (X = SbF₆, AsF₆, and PF₆). We observe a strong rotation of g-factor principal axes when the temperature decreases below charge-ordering temperature TCO. The possible origin of this rotation is analyzed on the basis of quantum chemical calculations performed using density functional theory method. A good agreement between theory and experiment is found. 2015 Article Charge-ordering induces magnetic axes rotation in organic materials (TMTTF)₂X (with X = SbF₆, AsF₆, and PF₆) / C.-E. Dutoit, S. Bertaina, M. Orio, M. Dressel, A. Stepanov // Физика низких температур. — 2015. — Т. 41, № 11. — С. 1206–1208. — Бібліогр.: 16 назв. — англ. 0132-6414 PACS: 71.27.+a, 75.85.+t, 76.30.–v http://dspace.nbuv.gov.ua/handle/123456789/128242 en Физика низких температур Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України
institution Digital Library of Periodicals of National Academy of Sciences of Ukraine
collection DSpace DC
language English
topic Кpаткие сообщения
Кpаткие сообщения
spellingShingle Кpаткие сообщения
Кpаткие сообщения
Dutoit, C.-E.
Bertaina, S.
Orio, M.
Dressel, M.
Stepanov, A.
Charge-ordering induces magnetic axes rotation in organic materials (TMTTF)₂X (with X = SbF₆, AsF₆, and PF₆)
Физика низких температур
description We have performed a comprehensive EPR investigation of the quasi-one-dimensional organic systems (TMTTF)₂X with centrosymmetrical anions X (X = SbF₆, AsF₆, and PF₆). We observe a strong rotation of g-factor principal axes when the temperature decreases below charge-ordering temperature TCO. The possible origin of this rotation is analyzed on the basis of quantum chemical calculations performed using density functional theory method. A good agreement between theory and experiment is found.
format Article
author Dutoit, C.-E.
Bertaina, S.
Orio, M.
Dressel, M.
Stepanov, A.
author_facet Dutoit, C.-E.
Bertaina, S.
Orio, M.
Dressel, M.
Stepanov, A.
author_sort Dutoit, C.-E.
title Charge-ordering induces magnetic axes rotation in organic materials (TMTTF)₂X (with X = SbF₆, AsF₆, and PF₆)
title_short Charge-ordering induces magnetic axes rotation in organic materials (TMTTF)₂X (with X = SbF₆, AsF₆, and PF₆)
title_full Charge-ordering induces magnetic axes rotation in organic materials (TMTTF)₂X (with X = SbF₆, AsF₆, and PF₆)
title_fullStr Charge-ordering induces magnetic axes rotation in organic materials (TMTTF)₂X (with X = SbF₆, AsF₆, and PF₆)
title_full_unstemmed Charge-ordering induces magnetic axes rotation in organic materials (TMTTF)₂X (with X = SbF₆, AsF₆, and PF₆)
title_sort charge-ordering induces magnetic axes rotation in organic materials (tmttf)₂x (with x = sbf₆, asf₆, and pf₆)
publisher Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України
publishDate 2015
topic_facet Кpаткие сообщения
url http://dspace.nbuv.gov.ua/handle/123456789/128242
citation_txt Charge-ordering induces magnetic axes rotation in organic materials (TMTTF)₂X (with X = SbF₆, AsF₆, and PF₆) / C.-E. Dutoit, S. Bertaina, M. Orio, M. Dressel, A. Stepanov // Физика низких температур. — 2015. — Т. 41, № 11. — С. 1206–1208. — Бібліогр.: 16 назв. — англ.
series Физика низких температур
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AT oriom chargeorderinginducesmagneticaxesrotationinorganicmaterialstmttf2xwithxsbf6asf6andpf6
AT dresselm chargeorderinginducesmagneticaxesrotationinorganicmaterialstmttf2xwithxsbf6asf6andpf6
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first_indexed 2023-10-18T20:54:54Z
last_indexed 2023-10-18T20:54:54Z
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