2025-02-23T03:49:31-05:00 DEBUG: VuFindSearch\Backend\Solr\Connector: Query fl=%2A&wt=json&json.nl=arrarr&q=id%3A%22irk-123456789-128766%22&qt=morelikethis&rows=5
2025-02-23T03:49:31-05:00 DEBUG: VuFindSearch\Backend\Solr\Connector: => GET http://localhost:8983/solr/biblio/select?fl=%2A&wt=json&json.nl=arrarr&q=id%3A%22irk-123456789-128766%22&qt=morelikethis&rows=5
2025-02-23T03:49:31-05:00 DEBUG: VuFindSearch\Backend\Solr\Connector: <= 200 OK
2025-02-23T03:49:31-05:00 DEBUG: Deserialized SOLR response
Structure and photoluminescence of helium-intercalated fullerite C₆₀

Structure and photoluminescence of helium-intercalated fullerite C₆₀

Intercalation of C₆₀ single crystals with helium was studied by powder x-ray diffractometry. It was established that the intercalation is a two-stage process, octahedral cavities are filled first and then tetrahedral ones, the chemical pressure being negative during both stages. For the first time l...

Full description

Saved in:
Bibliographic Details
Main Authors: Legchenkova, I.V., Prokhvatilov, A.I., Stetsenko, Yu.E., Strzhemechny, M.A., Yagotintsev, K.A., Avdeenko, A.A., Eremenko, V.V., Zinoviev, P.V., Zoryansky, V.N., Silaeva, N.B., Ruoff, R.S.
Format: Article
Language:English
Published: Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України 2002
Series:Физика низких температур
Subjects:
Письма pедактоpу
Online Access:http://dspace.nbuv.gov.ua/handle/123456789/128766
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:Intercalation of C₆₀ single crystals with helium was studied by powder x-ray diffractometry. It was established that the intercalation is a two-stage process, octahedral cavities are filled first and then tetrahedral ones, the chemical pressure being negative during both stages. For the first time low-temperature (5 K) photoluminescence spectra of helium-intercalated fullerite C₆₀ were studied. The presence of helium in lattice voids was shown to reduce that part of the luminescent intensity which is due to the emission of covalently bound pairs of C₆₀ molecules, the socalled "deep traps" with the 0-0 transition energy close to 1.69 eV. The mechanism of the effect of the intercalation with helium on the pair formation in fullerite C₆₀ is discussed.

Similar Items