Translational-rotational interaction in dynamics and thermodynamics of 2D atomic crystal with molecular impurity

The interaction between the rotational degrees of freedom of a diatomic molecular impurity and the phonon excitations of a two-dimensional atomic matrix commensurate with a substrate is investigated theoretically. It is shown, that the translational-rotational interaction changes the form of the rot...

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Дата:2003
Автори: Antsygina, T.N., Poltavskaya, M.I., Chishko, K.A.
Формат: Стаття
Мова:English
Опубліковано: Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України 2003
Назва видання:Физика низких температур
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Онлайн доступ:http://dspace.nbuv.gov.ua/handle/123456789/128916
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Назва журналу:Digital Library of Periodicals of National Academy of Sciences of Ukraine
Цитувати:Translational-rotational interaction in dynamics and thermodynamics of 2D atomic crystal with molecular impurity / T.N. Antsygina, M.I. Poltavskaya, K.A. Chishko // Физика низких температур. — 2003. — Т. 29, № 9-10. — С. 961-966. — Бібліогр.: 12 назв. — англ.

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Digital Library of Periodicals of National Academy of Sciences of Ukraine
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spelling irk-123456789-1289162018-01-15T03:04:01Z Translational-rotational interaction in dynamics and thermodynamics of 2D atomic crystal with molecular impurity Antsygina, T.N. Poltavskaya, M.I. Chishko, K.A. Physics in Quantum Crystals The interaction between the rotational degrees of freedom of a diatomic molecular impurity and the phonon excitations of a two-dimensional atomic matrix commensurate with a substrate is investigated theoretically. It is shown, that the translational-rotational interaction changes the form of the rotational kinetic energy operator as compared to the corresponding expression for a free rotator, and also renormalizes the parameters of the crystal field without change in its initial form. The contribution of the impurity rotational degrees of freedom to the low-temperature heat capacity for a dilute solution of diatomic molecules in an atomic two-dimensional matrix is calculated. The possibility of experimental observation of the effects obtained is discussed. 2003 Article Translational-rotational interaction in dynamics and thermodynamics of 2D atomic crystal with molecular impurity / T.N. Antsygina, M.I. Poltavskaya, K.A. Chishko // Физика низких температур. — 2003. — Т. 29, № 9-10. — С. 961-966. — Бібліогр.: 12 назв. — англ. 0132-6414 PACS: 68.35.Dv, 68.35.Ja, 68.65.+g http://dspace.nbuv.gov.ua/handle/123456789/128916 en Физика низких температур Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України
institution Digital Library of Periodicals of National Academy of Sciences of Ukraine
collection DSpace DC
language English
topic Physics in Quantum Crystals
Physics in Quantum Crystals
spellingShingle Physics in Quantum Crystals
Physics in Quantum Crystals
Antsygina, T.N.
Poltavskaya, M.I.
Chishko, K.A.
Translational-rotational interaction in dynamics and thermodynamics of 2D atomic crystal with molecular impurity
Физика низких температур
description The interaction between the rotational degrees of freedom of a diatomic molecular impurity and the phonon excitations of a two-dimensional atomic matrix commensurate with a substrate is investigated theoretically. It is shown, that the translational-rotational interaction changes the form of the rotational kinetic energy operator as compared to the corresponding expression for a free rotator, and also renormalizes the parameters of the crystal field without change in its initial form. The contribution of the impurity rotational degrees of freedom to the low-temperature heat capacity for a dilute solution of diatomic molecules in an atomic two-dimensional matrix is calculated. The possibility of experimental observation of the effects obtained is discussed.
format Article
author Antsygina, T.N.
Poltavskaya, M.I.
Chishko, K.A.
author_facet Antsygina, T.N.
Poltavskaya, M.I.
Chishko, K.A.
author_sort Antsygina, T.N.
title Translational-rotational interaction in dynamics and thermodynamics of 2D atomic crystal with molecular impurity
title_short Translational-rotational interaction in dynamics and thermodynamics of 2D atomic crystal with molecular impurity
title_full Translational-rotational interaction in dynamics and thermodynamics of 2D atomic crystal with molecular impurity
title_fullStr Translational-rotational interaction in dynamics and thermodynamics of 2D atomic crystal with molecular impurity
title_full_unstemmed Translational-rotational interaction in dynamics and thermodynamics of 2D atomic crystal with molecular impurity
title_sort translational-rotational interaction in dynamics and thermodynamics of 2d atomic crystal with molecular impurity
publisher Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України
publishDate 2003
topic_facet Physics in Quantum Crystals
url http://dspace.nbuv.gov.ua/handle/123456789/128916
citation_txt Translational-rotational interaction in dynamics and thermodynamics of 2D atomic crystal with molecular impurity / T.N. Antsygina, M.I. Poltavskaya, K.A. Chishko // Физика низких температур. — 2003. — Т. 29, № 9-10. — С. 961-966. — Бібліогр.: 12 назв. — англ.
series Физика низких температур
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AT poltavskayami translationalrotationalinteractionindynamicsandthermodynamicsof2datomiccrystalwithmolecularimpurity
AT chishkoka translationalrotationalinteractionindynamicsandthermodynamicsof2datomiccrystalwithmolecularimpurity
first_indexed 2023-10-18T20:56:26Z
last_indexed 2023-10-18T20:56:26Z
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