Translational-rotational interaction in dynamics and thermodynamics of 2D atomic crystal with molecular impurity
The interaction between the rotational degrees of freedom of a diatomic molecular impurity and the phonon excitations of a two-dimensional atomic matrix commensurate with a substrate is investigated theoretically. It is shown, that the translational-rotational interaction changes the form of the rot...
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Дата: | 2003 |
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Автори: | , , |
Формат: | Стаття |
Мова: | English |
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Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України
2003
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Назва видання: | Физика низких температур |
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Онлайн доступ: | http://dspace.nbuv.gov.ua/handle/123456789/128916 |
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Назва журналу: | Digital Library of Periodicals of National Academy of Sciences of Ukraine |
Цитувати: | Translational-rotational interaction in dynamics and thermodynamics of 2D atomic crystal with molecular impurity / T.N. Antsygina, M.I. Poltavskaya, K.A. Chishko // Физика низких температур. — 2003. — Т. 29, № 9-10. — С. 961-966. — Бібліогр.: 12 назв. — англ. |
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irk-123456789-1289162018-01-15T03:04:01Z Translational-rotational interaction in dynamics and thermodynamics of 2D atomic crystal with molecular impurity Antsygina, T.N. Poltavskaya, M.I. Chishko, K.A. Physics in Quantum Crystals The interaction between the rotational degrees of freedom of a diatomic molecular impurity and the phonon excitations of a two-dimensional atomic matrix commensurate with a substrate is investigated theoretically. It is shown, that the translational-rotational interaction changes the form of the rotational kinetic energy operator as compared to the corresponding expression for a free rotator, and also renormalizes the parameters of the crystal field without change in its initial form. The contribution of the impurity rotational degrees of freedom to the low-temperature heat capacity for a dilute solution of diatomic molecules in an atomic two-dimensional matrix is calculated. The possibility of experimental observation of the effects obtained is discussed. 2003 Article Translational-rotational interaction in dynamics and thermodynamics of 2D atomic crystal with molecular impurity / T.N. Antsygina, M.I. Poltavskaya, K.A. Chishko // Физика низких температур. — 2003. — Т. 29, № 9-10. — С. 961-966. — Бібліогр.: 12 назв. — англ. 0132-6414 PACS: 68.35.Dv, 68.35.Ja, 68.65.+g http://dspace.nbuv.gov.ua/handle/123456789/128916 en Физика низких температур Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України |
institution |
Digital Library of Periodicals of National Academy of Sciences of Ukraine |
collection |
DSpace DC |
language |
English |
topic |
Physics in Quantum Crystals Physics in Quantum Crystals |
spellingShingle |
Physics in Quantum Crystals Physics in Quantum Crystals Antsygina, T.N. Poltavskaya, M.I. Chishko, K.A. Translational-rotational interaction in dynamics and thermodynamics of 2D atomic crystal with molecular impurity Физика низких температур |
description |
The interaction between the rotational degrees of freedom of a diatomic molecular impurity and the phonon excitations of a two-dimensional atomic matrix commensurate with a substrate is investigated theoretically. It is shown, that the translational-rotational interaction changes the form of the rotational kinetic energy operator as compared to the corresponding expression for a free rotator, and also renormalizes the parameters of the crystal field without change in its initial form. The contribution of the impurity rotational degrees of freedom to the low-temperature heat capacity for a dilute solution of diatomic molecules in an atomic two-dimensional matrix is calculated. The possibility of experimental observation of the effects obtained is discussed. |
format |
Article |
author |
Antsygina, T.N. Poltavskaya, M.I. Chishko, K.A. |
author_facet |
Antsygina, T.N. Poltavskaya, M.I. Chishko, K.A. |
author_sort |
Antsygina, T.N. |
title |
Translational-rotational interaction in dynamics and thermodynamics of 2D atomic crystal with molecular impurity |
title_short |
Translational-rotational interaction in dynamics and thermodynamics of 2D atomic crystal with molecular impurity |
title_full |
Translational-rotational interaction in dynamics and thermodynamics of 2D atomic crystal with molecular impurity |
title_fullStr |
Translational-rotational interaction in dynamics and thermodynamics of 2D atomic crystal with molecular impurity |
title_full_unstemmed |
Translational-rotational interaction in dynamics and thermodynamics of 2D atomic crystal with molecular impurity |
title_sort |
translational-rotational interaction in dynamics and thermodynamics of 2d atomic crystal with molecular impurity |
publisher |
Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України |
publishDate |
2003 |
topic_facet |
Physics in Quantum Crystals |
url |
http://dspace.nbuv.gov.ua/handle/123456789/128916 |
citation_txt |
Translational-rotational interaction in dynamics and thermodynamics of 2D atomic crystal with molecular impurity / T.N. Antsygina, M.I. Poltavskaya, K.A. Chishko // Физика низких температур. — 2003. — Т. 29, № 9-10. — С. 961-966. — Бібліогр.: 12 назв. — англ. |
series |
Физика низких температур |
work_keys_str_mv |
AT antsyginatn translationalrotationalinteractionindynamicsandthermodynamicsof2datomiccrystalwithmolecularimpurity AT poltavskayami translationalrotationalinteractionindynamicsandthermodynamicsof2datomiccrystalwithmolecularimpurity AT chishkoka translationalrotationalinteractionindynamicsandthermodynamicsof2datomiccrystalwithmolecularimpurity |
first_indexed |
2023-10-18T20:56:26Z |
last_indexed |
2023-10-18T20:56:26Z |
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1796151506532040704 |