Time-resolved CARS measurements of vibrational decoherence of I₂ isolated in matrix Ar
Time-resolved coherent anti-Stokes Raman scattering is applied to prepare and interrogate vibrational coherences on the ground electronic surface of molecular iodine isolated in Ar matrices. The coherence decay time shows a linear dependence on vibrational quantum numbers, for v = 3–15. The temperat...
Збережено в:
| Дата: | 2003 |
|---|---|
| Автори: | , , , , |
| Формат: | Стаття |
| Мова: | English |
| Опубліковано: |
Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України
2003
|
| Назва видання: | Физика низких температур |
| Теми: | |
| Онлайн доступ: | http://dspace.nbuv.gov.ua/handle/123456789/128933 |
| Теги: |
Додати тег
Немає тегів, Будьте першим, хто поставить тег для цього запису!
|
| Назва журналу: | Digital Library of Periodicals of National Academy of Sciences of Ukraine |
| Цитувати: | Time-resolved CARS measurements of vibrational decoherence of I₂ isolated in matrix Ar / M. Karavitis, D. Segale, Z. Bihary, M. Pettersson, V.A. Apkarian // Физика низких температур. — 2003. — Т. 29, № 9-10. — С. 1071-1080. — Бібліогр.: 26 назв. — англ. |
Репозитарії
Digital Library of Periodicals of National Academy of Sciences of Ukraine| id |
irk-123456789-128933 |
|---|---|
| record_format |
dspace |
| spelling |
irk-123456789-1289332018-01-15T03:04:29Z Time-resolved CARS measurements of vibrational decoherence of I₂ isolated in matrix Ar Karavitis, M. Segale, D. Bihary, Z. Pettersson, M. Apkarian, V.A. Spectroscopy in Cryocrystals and Matrices Time-resolved coherent anti-Stokes Raman scattering is applied to prepare and interrogate vibrational coherences on the ground electronic surface of molecular iodine isolated in Ar matrices. The coherence decay time shows a linear dependence on vibrational quantum numbers, for v = 3–15. The temperature dependence of decoherence rates is negligible for v < 7, in the experimental range T = 18–32 K. For a v = 13, 14 superposition, the temperature dependence indicates dephasing by a 66 cm–¹ pseudo-local phonon, just outside the Debye edge of the solid. The accuracy of the data is limited due to two-photon induced dissociation of the molecule, which process is characterized using polarized fields. The T → 0 limit of dephasing is discussed. 2003 Article Time-resolved CARS measurements of vibrational decoherence of I₂ isolated in matrix Ar / M. Karavitis, D. Segale, Z. Bihary, M. Pettersson, V.A. Apkarian // Физика низких температур. — 2003. — Т. 29, № 9-10. — С. 1071-1080. — Бібліогр.: 26 назв. — англ. 0132-6414 PACS: 42.65.Dr, 67.80.-s http://dspace.nbuv.gov.ua/handle/123456789/128933 en Физика низких температур Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України |
| institution |
Digital Library of Periodicals of National Academy of Sciences of Ukraine |
| collection |
DSpace DC |
| language |
English |
| topic |
Spectroscopy in Cryocrystals and Matrices Spectroscopy in Cryocrystals and Matrices |
| spellingShingle |
Spectroscopy in Cryocrystals and Matrices Spectroscopy in Cryocrystals and Matrices Karavitis, M. Segale, D. Bihary, Z. Pettersson, M. Apkarian, V.A. Time-resolved CARS measurements of vibrational decoherence of I₂ isolated in matrix Ar Физика низких температур |
| description |
Time-resolved coherent anti-Stokes Raman scattering is applied to prepare and interrogate vibrational coherences on the ground electronic surface of molecular iodine isolated in Ar matrices. The coherence decay time shows a linear dependence on vibrational quantum numbers, for v = 3–15. The temperature dependence of decoherence rates is negligible for v < 7, in the experimental range T = 18–32 K. For a v = 13, 14 superposition, the temperature dependence indicates dephasing by a 66 cm–¹ pseudo-local phonon, just outside the Debye edge of the solid. The accuracy of the data is limited due to two-photon induced dissociation of the molecule, which process is characterized using polarized fields. The T → 0 limit of dephasing is discussed. |
| format |
Article |
| author |
Karavitis, M. Segale, D. Bihary, Z. Pettersson, M. Apkarian, V.A. |
| author_facet |
Karavitis, M. Segale, D. Bihary, Z. Pettersson, M. Apkarian, V.A. |
| author_sort |
Karavitis, M. |
| title |
Time-resolved CARS measurements of vibrational decoherence of I₂ isolated in matrix Ar |
| title_short |
Time-resolved CARS measurements of vibrational decoherence of I₂ isolated in matrix Ar |
| title_full |
Time-resolved CARS measurements of vibrational decoherence of I₂ isolated in matrix Ar |
| title_fullStr |
Time-resolved CARS measurements of vibrational decoherence of I₂ isolated in matrix Ar |
| title_full_unstemmed |
Time-resolved CARS measurements of vibrational decoherence of I₂ isolated in matrix Ar |
| title_sort |
time-resolved cars measurements of vibrational decoherence of i₂ isolated in matrix ar |
| publisher |
Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України |
| publishDate |
2003 |
| topic_facet |
Spectroscopy in Cryocrystals and Matrices |
| url |
http://dspace.nbuv.gov.ua/handle/123456789/128933 |
| citation_txt |
Time-resolved CARS measurements of vibrational decoherence of I₂ isolated in matrix Ar / M. Karavitis, D. Segale, Z. Bihary, M. Pettersson, V.A. Apkarian // Физика низких температур. — 2003. — Т. 29, № 9-10. — С. 1071-1080. — Бібліогр.: 26 назв. — англ. |
| series |
Физика низких температур |
| work_keys_str_mv |
AT karavitism timeresolvedcarsmeasurementsofvibrationaldecoherenceofi2isolatedinmatrixar AT segaled timeresolvedcarsmeasurementsofvibrationaldecoherenceofi2isolatedinmatrixar AT biharyz timeresolvedcarsmeasurementsofvibrationaldecoherenceofi2isolatedinmatrixar AT petterssonm timeresolvedcarsmeasurementsofvibrationaldecoherenceofi2isolatedinmatrixar AT apkarianva timeresolvedcarsmeasurementsofvibrationaldecoherenceofi2isolatedinmatrixar |
| first_indexed |
2023-10-18T20:56:29Z |
| last_indexed |
2023-10-18T20:56:29Z |
| _version_ |
1796151508434157568 |