Matrix-isolation FTIR study of azidoacetone and azidoacetonitrile
Azidoacetonitrile (N₃CH₂CN) and azidoacetone (N₃CH₂COCH₃) were studied by matrix-isolation FTIR spectroscopy in solid neon, argon and nitrogen. The IR spectra calculated using the density fuctional theoretical method are discussed in comparison with the experimental data. Significant broadening of t...
Збережено в:
| Дата: | 2003 |
|---|---|
| Автори: | , , , , , , , , , |
| Формат: | Стаття |
| Мова: | English |
| Опубліковано: |
Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України
2003
|
| Назва видання: | Физика низких температур |
| Теми: | |
| Онлайн доступ: | http://dspace.nbuv.gov.ua/handle/123456789/128943 |
| Теги: |
Додати тег
Немає тегів, Будьте першим, хто поставить тег для цього запису!
|
| Назва журналу: | Digital Library of Periodicals of National Academy of Sciences of Ukraine |
| Цитувати: | Matrix-isolation FTIR study of azidoacetone and azidoacetonitrile / Marcin Frankowski, Manuel Algarra, Paula Rodrigues, Maria T. Barros, M. Natália D.S. Cordeiro, Brigitte S. Fox, Alice M. Smith-Gicklhorn, Martin K. Beyer, Maria L. Costa, Vladimir E. Bondybey // Физика низких температур. — 2003. — Т. 29, № 9-10. — С. 1140-1146. — Бібліогр.: 14 назв. — англ. |
Репозитарії
Digital Library of Periodicals of National Academy of Sciences of Ukraine| id |
irk-123456789-128943 |
|---|---|
| record_format |
dspace |
| spelling |
irk-123456789-1289432018-01-15T03:04:24Z Matrix-isolation FTIR study of azidoacetone and azidoacetonitrile Frankowski, Marcin Algarra, Manuel Rodrigues, Paula Barros, Maria T. D.S. Cordeiro, M. Natália Fox, Brigitte S. Smith-Gicklhorn, Alice M. Beyer, Martin K. Costa, Maria L. Bondybey, Vladimir E. Spectroscopy in Cryocrystals and Matrices Azidoacetonitrile (N₃CH₂CN) and azidoacetone (N₃CH₂COCH₃) were studied by matrix-isolation FTIR spectroscopy in solid neon, argon and nitrogen. The IR spectra calculated using the density fuctional theoretical method are discussed in comparison with the experimental data. Significant broadening of the recorded azide bands indicate an awkward fit of these compounds into the solid environment. The strongest absorption is observed for both compounds in the regions of asymmetric and symmetric stretches of the N₃ azide group. Strong band splittings in the N₃ asymmetric stretch region can be most likely explained by very strong Fermi resonances with the CN stretch and combinations and overtones of the numerous lower frequency vibrational modes. 2003 Article Matrix-isolation FTIR study of azidoacetone and azidoacetonitrile / Marcin Frankowski, Manuel Algarra, Paula Rodrigues, Maria T. Barros, M. Natália D.S. Cordeiro, Brigitte S. Fox, Alice M. Smith-Gicklhorn, Martin K. Beyer, Maria L. Costa, Vladimir E. Bondybey // Физика низких температур. — 2003. — Т. 29, № 9-10. — С. 1140-1146. — Бібліогр.: 14 назв. — англ. 0132-6414 PACS: 67.40.Yv, 07.60.Vg http://dspace.nbuv.gov.ua/handle/123456789/128943 en Физика низких температур Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України |
| institution |
Digital Library of Periodicals of National Academy of Sciences of Ukraine |
| collection |
DSpace DC |
| language |
English |
| topic |
Spectroscopy in Cryocrystals and Matrices Spectroscopy in Cryocrystals and Matrices |
| spellingShingle |
Spectroscopy in Cryocrystals and Matrices Spectroscopy in Cryocrystals and Matrices Frankowski, Marcin Algarra, Manuel Rodrigues, Paula Barros, Maria T. D.S. Cordeiro, M. Natália Fox, Brigitte S. Smith-Gicklhorn, Alice M. Beyer, Martin K. Costa, Maria L. Bondybey, Vladimir E. Matrix-isolation FTIR study of azidoacetone and azidoacetonitrile Физика низких температур |
| description |
Azidoacetonitrile (N₃CH₂CN) and azidoacetone (N₃CH₂COCH₃) were studied by matrix-isolation FTIR spectroscopy in solid neon, argon and nitrogen. The IR spectra calculated using the density fuctional theoretical method are discussed in comparison with the experimental data. Significant broadening of the recorded azide bands indicate an awkward fit of these compounds into the solid environment. The strongest absorption is observed for both compounds in the regions of asymmetric and symmetric stretches of the N₃ azide group. Strong band splittings in the N₃ asymmetric stretch region can be most likely explained by very strong Fermi resonances with the CN stretch and combinations and overtones of the numerous lower frequency vibrational modes. |
| format |
Article |
| author |
Frankowski, Marcin Algarra, Manuel Rodrigues, Paula Barros, Maria T. D.S. Cordeiro, M. Natália Fox, Brigitte S. Smith-Gicklhorn, Alice M. Beyer, Martin K. Costa, Maria L. Bondybey, Vladimir E. |
| author_facet |
Frankowski, Marcin Algarra, Manuel Rodrigues, Paula Barros, Maria T. D.S. Cordeiro, M. Natália Fox, Brigitte S. Smith-Gicklhorn, Alice M. Beyer, Martin K. Costa, Maria L. Bondybey, Vladimir E. |
| author_sort |
Frankowski, Marcin |
| title |
Matrix-isolation FTIR study of azidoacetone and azidoacetonitrile |
| title_short |
Matrix-isolation FTIR study of azidoacetone and azidoacetonitrile |
| title_full |
Matrix-isolation FTIR study of azidoacetone and azidoacetonitrile |
| title_fullStr |
Matrix-isolation FTIR study of azidoacetone and azidoacetonitrile |
| title_full_unstemmed |
Matrix-isolation FTIR study of azidoacetone and azidoacetonitrile |
| title_sort |
matrix-isolation ftir study of azidoacetone and azidoacetonitrile |
| publisher |
Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України |
| publishDate |
2003 |
| topic_facet |
Spectroscopy in Cryocrystals and Matrices |
| url |
http://dspace.nbuv.gov.ua/handle/123456789/128943 |
| citation_txt |
Matrix-isolation FTIR study of azidoacetone and azidoacetonitrile / Marcin Frankowski, Manuel Algarra, Paula Rodrigues, Maria T. Barros, M. Natália D.S. Cordeiro, Brigitte S. Fox, Alice M. Smith-Gicklhorn, Martin K. Beyer, Maria L. Costa, Vladimir E. Bondybey // Физика низких температур. — 2003. — Т. 29, № 9-10. — С. 1140-1146. — Бібліогр.: 14 назв. — англ. |
| series |
Физика низких температур |
| work_keys_str_mv |
AT frankowskimarcin matrixisolationftirstudyofazidoacetoneandazidoacetonitrile AT algarramanuel matrixisolationftirstudyofazidoacetoneandazidoacetonitrile AT rodriguespaula matrixisolationftirstudyofazidoacetoneandazidoacetonitrile AT barrosmariat matrixisolationftirstudyofazidoacetoneandazidoacetonitrile AT dscordeiromnatalia matrixisolationftirstudyofazidoacetoneandazidoacetonitrile AT foxbrigittes matrixisolationftirstudyofazidoacetoneandazidoacetonitrile AT smithgicklhornalicem matrixisolationftirstudyofazidoacetoneandazidoacetonitrile AT beyermartink matrixisolationftirstudyofazidoacetoneandazidoacetonitrile AT costamarial matrixisolationftirstudyofazidoacetoneandazidoacetonitrile AT bondybeyvladimire matrixisolationftirstudyofazidoacetoneandazidoacetonitrile |
| first_indexed |
2023-10-18T20:56:30Z |
| last_indexed |
2023-10-18T20:56:30Z |
| _version_ |
1796151509493219328 |