Observation of the high resolution infrared absorption spectrum of CO₂ molecules isolated in solid parahydrogen
We report the observation of high resolution (0.008 cm⁻¹) infrared absorption spectra of CO₂ molecules isolated in solid parahydrogen(pH₂) matrices at T=2.4 to 4.8 K. Several extremely sharp (0.01 to 0.04 cm⁻¹ full-width-at-half-maximum) absorption features appear in the 2343.5 to 2345 cm⁻¹ region....
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| Дата: | 2000 |
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| Автори: | , |
| Формат: | Стаття |
| Мова: | English |
| Опубліковано: |
Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України
2000
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| Назва видання: | Физика низких температур |
| Теми: | |
| Онлайн доступ: | http://dspace.nbuv.gov.ua/handle/123456789/129213 |
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| Назва журналу: | Digital Library of Periodicals of National Academy of Sciences of Ukraine |
| Цитувати: | Observation of the high resolution infrared absorption spectrum of CO₂ molecules isolated in solid parahydrogen / Simon Tam, Mario E. Fajardo // Физика низких температур. — 2000. — Т. 26, № 9-10. — С. 889-898. — Бібліогр.: 86 назв. — англ. |
Репозитарії
Digital Library of Periodicals of National Academy of Sciences of Ukraine| id |
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| spelling |
irk-123456789-1292132018-01-17T03:04:27Z Observation of the high resolution infrared absorption spectrum of CO₂ molecules isolated in solid parahydrogen Tam, Simon Fajardo, Mario E. Low-Temperature Physics and Chemistry in Cryomatrice We report the observation of high resolution (0.008 cm⁻¹) infrared absorption spectra of CO₂ molecules isolated in solid parahydrogen(pH₂) matrices at T=2.4 to 4.8 K. Several extremely sharp (0.01 to 0.04 cm⁻¹ full-width-at-half-maximum) absorption features appear in the 2343.5 to 2345 cm⁻¹ region. We assign the three strongest peaks to the v3 mode of isolated CO₂ molecules. The spectra are consistent with trapping of the CO₂ molecules in three distinct double-substitutional sites in hcp and fcc regions of the pH₂ solid. We offer several hypotheses as to the origins of the numerous weaker absorption features. 2000 Article Observation of the high resolution infrared absorption spectrum of CO₂ molecules isolated in solid parahydrogen / Simon Tam, Mario E. Fajardo // Физика низких температур. — 2000. — Т. 26, № 9-10. — С. 889-898. — Бібліогр.: 86 назв. — англ. 0132-6414 PACS: 07.20.Mc, 61.72.Ww, 67.80.-s, 78.30.-j, 81.10.Bk, 81.30.Kf http://dspace.nbuv.gov.ua/handle/123456789/129213 en Физика низких температур Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України |
| institution |
Digital Library of Periodicals of National Academy of Sciences of Ukraine |
| collection |
DSpace DC |
| language |
English |
| topic |
Low-Temperature Physics and Chemistry in Cryomatrice Low-Temperature Physics and Chemistry in Cryomatrice |
| spellingShingle |
Low-Temperature Physics and Chemistry in Cryomatrice Low-Temperature Physics and Chemistry in Cryomatrice Tam, Simon Fajardo, Mario E. Observation of the high resolution infrared absorption spectrum of CO₂ molecules isolated in solid parahydrogen Физика низких температур |
| description |
We report the observation of high resolution (0.008 cm⁻¹) infrared absorption spectra of CO₂ molecules isolated in solid parahydrogen(pH₂) matrices at T=2.4 to 4.8 K. Several extremely sharp (0.01 to 0.04 cm⁻¹ full-width-at-half-maximum) absorption features appear in the 2343.5 to 2345 cm⁻¹ region. We assign the three strongest peaks to the v3 mode of isolated CO₂ molecules. The spectra are consistent with trapping of the CO₂ molecules in three distinct double-substitutional sites in hcp and fcc regions of the pH₂ solid. We offer several hypotheses as to the origins of the numerous weaker absorption features. |
| format |
Article |
| author |
Tam, Simon Fajardo, Mario E. |
| author_facet |
Tam, Simon Fajardo, Mario E. |
| author_sort |
Tam, Simon |
| title |
Observation of the high resolution infrared absorption spectrum of CO₂ molecules isolated in solid parahydrogen |
| title_short |
Observation of the high resolution infrared absorption spectrum of CO₂ molecules isolated in solid parahydrogen |
| title_full |
Observation of the high resolution infrared absorption spectrum of CO₂ molecules isolated in solid parahydrogen |
| title_fullStr |
Observation of the high resolution infrared absorption spectrum of CO₂ molecules isolated in solid parahydrogen |
| title_full_unstemmed |
Observation of the high resolution infrared absorption spectrum of CO₂ molecules isolated in solid parahydrogen |
| title_sort |
observation of the high resolution infrared absorption spectrum of co₂ molecules isolated in solid parahydrogen |
| publisher |
Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України |
| publishDate |
2000 |
| topic_facet |
Low-Temperature Physics and Chemistry in Cryomatrice |
| url |
http://dspace.nbuv.gov.ua/handle/123456789/129213 |
| citation_txt |
Observation of the high resolution infrared absorption spectrum of CO₂ molecules isolated in solid parahydrogen / Simon Tam, Mario E. Fajardo // Физика низких температур. — 2000. — Т. 26, № 9-10. — С. 889-898. — Бібліогр.: 86 назв. — англ. |
| series |
Физика низких температур |
| work_keys_str_mv |
AT tamsimon observationofthehighresolutioninfraredabsorptionspectrumofco2moleculesisolatedinsolidparahydrogen AT fajardomarioe observationofthehighresolutioninfraredabsorptionspectrumofco2moleculesisolatedinsolidparahydrogen |
| first_indexed |
2023-10-18T20:57:10Z |
| last_indexed |
2023-10-18T20:57:10Z |
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1796151537466081280 |