Reactions of laser-ablated aluminum atoms with nitrogen during condensation at 10 K. Infrared spectra and density functional calculations for Alx Ny molecular
Laser-ablated aluminum atoms react with dinitrogen on condensation at 10 K to form N₃ radicals and the subject molecules, which are identified by nitrogen isotopic substitution, further reactions on annealing, and comparison with isotopic frequencies computed by density functional theory. The major...
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| Дата: | 2000 |
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| Автори: | , , , , |
| Формат: | Стаття |
| Мова: | English |
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Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України
2000
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| Назва видання: | Физика низких температур |
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| Онлайн доступ: | http://dspace.nbuv.gov.ua/handle/123456789/129221 |
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| Назва журналу: | Digital Library of Periodicals of National Academy of Sciences of Ukraine |
| Цитувати: | Reactions of laser-ablated aluminum atoms with nitrogen during condensation at 10 K. Infrared spectra and density functional calculations for Alx Ny molecular / Lester Andrews, Mingfei Zhou, George V. Chertihin, William D. Bare, Yacine Hannachi // Физика низких температур. — 2000. — Т. 26, № 9-10. — С. 992-1000. — Бібліогр.: 30 назв. — англ. |
Репозитарії
Digital Library of Periodicals of National Academy of Sciences of Ukraine| id |
irk-123456789-129221 |
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dspace |
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irk-123456789-1292212018-01-18T03:02:42Z Reactions of laser-ablated aluminum atoms with nitrogen during condensation at 10 K. Infrared spectra and density functional calculations for Alx Ny molecular Andrews, Lester Zhou, Mingfei Chertihin, George V. Bare, William D. Hannachi, Yacine Low-Temperature Physics and Chemistry in Cryomatrice Laser-ablated aluminum atoms react with dinitrogen on condensation at 10 K to form N₃ radicals and the subject molecules, which are identified by nitrogen isotopic substitution, further reactions on annealing, and comparison with isotopic frequencies computed by density functional theory. The major AlN₃ product is identified from three fundamentals and a statistically mixed nitrogen isotopic octet pattern. The aluminum-rich Al₂N and Al₃N species are major products produced on annealing to allow diffusion and further reaction of trapped species. This work provides the first experimental evidence for molecular AlxNy species that may be involved in ceramic film growth. 2000 Article Reactions of laser-ablated aluminum atoms with nitrogen during condensation at 10 K. Infrared spectra and density functional calculations for Alx Ny molecular / Lester Andrews, Mingfei Zhou, George V. Chertihin, William D. Bare, Yacine Hannachi // Физика низких температур. — 2000. — Т. 26, № 9-10. — С. 992-1000. — Бібліогр.: 30 назв. — англ. 0132-6414 PACS: 81.15.Fg, 82.30.Cf http://dspace.nbuv.gov.ua/handle/123456789/129221 en Физика низких температур Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України |
| institution |
Digital Library of Periodicals of National Academy of Sciences of Ukraine |
| collection |
DSpace DC |
| language |
English |
| topic |
Low-Temperature Physics and Chemistry in Cryomatrice Low-Temperature Physics and Chemistry in Cryomatrice |
| spellingShingle |
Low-Temperature Physics and Chemistry in Cryomatrice Low-Temperature Physics and Chemistry in Cryomatrice Andrews, Lester Zhou, Mingfei Chertihin, George V. Bare, William D. Hannachi, Yacine Reactions of laser-ablated aluminum atoms with nitrogen during condensation at 10 K. Infrared spectra and density functional calculations for Alx Ny molecular Физика низких температур |
| description |
Laser-ablated aluminum atoms react with dinitrogen on condensation at 10 K to form N₃ radicals and the subject molecules, which are identified by nitrogen isotopic substitution, further reactions on annealing, and comparison with isotopic frequencies computed by density functional theory. The major AlN₃ product is identified from three fundamentals and a statistically mixed nitrogen isotopic octet pattern. The aluminum-rich Al₂N and Al₃N species are major products produced on annealing to allow diffusion and further reaction of trapped species. This work provides the first experimental evidence for molecular AlxNy species that may be involved in ceramic film growth. |
| format |
Article |
| author |
Andrews, Lester Zhou, Mingfei Chertihin, George V. Bare, William D. Hannachi, Yacine |
| author_facet |
Andrews, Lester Zhou, Mingfei Chertihin, George V. Bare, William D. Hannachi, Yacine |
| author_sort |
Andrews, Lester |
| title |
Reactions of laser-ablated aluminum atoms with nitrogen during condensation at 10 K. Infrared spectra and density functional calculations for Alx Ny molecular |
| title_short |
Reactions of laser-ablated aluminum atoms with nitrogen during condensation at 10 K. Infrared spectra and density functional calculations for Alx Ny molecular |
| title_full |
Reactions of laser-ablated aluminum atoms with nitrogen during condensation at 10 K. Infrared spectra and density functional calculations for Alx Ny molecular |
| title_fullStr |
Reactions of laser-ablated aluminum atoms with nitrogen during condensation at 10 K. Infrared spectra and density functional calculations for Alx Ny molecular |
| title_full_unstemmed |
Reactions of laser-ablated aluminum atoms with nitrogen during condensation at 10 K. Infrared spectra and density functional calculations for Alx Ny molecular |
| title_sort |
reactions of laser-ablated aluminum atoms with nitrogen during condensation at 10 k. infrared spectra and density functional calculations for alx ny molecular |
| publisher |
Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України |
| publishDate |
2000 |
| topic_facet |
Low-Temperature Physics and Chemistry in Cryomatrice |
| url |
http://dspace.nbuv.gov.ua/handle/123456789/129221 |
| citation_txt |
Reactions of laser-ablated aluminum atoms with nitrogen during condensation at 10 K. Infrared spectra and density functional calculations for Alx Ny molecular / Lester Andrews, Mingfei Zhou, George V. Chertihin, William D. Bare, Yacine Hannachi // Физика низких температур. — 2000. — Т. 26, № 9-10. — С. 992-1000. — Бібліогр.: 30 назв. — англ. |
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Физика низких температур |
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2023-10-18T20:57:11Z |
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