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Spectroscopy of yttrium dimers in argon matrices
The absorption and resonance Raman spectra of yttrium dimers (Y₂) in argon matrices are measured for the first time. The absorption spectrum (scattering depletion spectrum SDS) shows a weak, broad transition centered near 485 nm. Resonance Raman spectra obtained by exciting into this absorption band...
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Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України
2000
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Online Access: | http://dspace.nbuv.gov.ua/handle/123456789/129223 |
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irk-123456789-1292232018-01-18T03:02:40Z Spectroscopy of yttrium dimers in argon matrices Fang, Li Chen, Xiaoyu Shen, Xiaole Liu, Yifei Lindsay, D.M. Lombardi, John R. Low-Temperature Physics and Chemistry in Cryomatrice The absorption and resonance Raman spectra of yttrium dimers (Y₂) in argon matrices are measured for the first time. The absorption spectrum (scattering depletion spectrum SDS) shows a weak, broad transition centered near 485 nm. Resonance Raman spectra obtained by exciting into this absorption band with several visible laser lines (465.5–496.5 nm) give a single, sharp progression with up to ten Stokes transitions. These data give ωe=184.4(4) cm⁻¹, with ωexe=0.30(3) cm⁻¹, leading to a spectroscopic dissociation energy of De=3.5(4) eV. Comparison of our results with several ab initio calculations adds confirmation to the assignment of the ground state of Y₂ to be the ¹Σg⁺ state. 2000 Article Spectroscopy of yttrium dimers in argon matrices / Li Fang, Xiaoyu Chen, Xiaole Shen, Yifei Liu, D.M. Lindsay, John R. Lombardi // Физика низких температур. — 2000. — Т. 26, № 9-10. — С. 1011-1015. — Бібліогр.: 23 назв. — англ. 0132-6414 PACS: 78.30.Hv, 71.55.Ht http://dspace.nbuv.gov.ua/handle/123456789/129223 en Физика низких температур Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України |
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Low-Temperature Physics and Chemistry in Cryomatrice Low-Temperature Physics and Chemistry in Cryomatrice |
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Low-Temperature Physics and Chemistry in Cryomatrice Low-Temperature Physics and Chemistry in Cryomatrice Fang, Li Chen, Xiaoyu Shen, Xiaole Liu, Yifei Lindsay, D.M. Lombardi, John R. Spectroscopy of yttrium dimers in argon matrices Физика низких температур |
description |
The absorption and resonance Raman spectra of yttrium dimers (Y₂) in argon matrices are measured for the first time. The absorption spectrum (scattering depletion spectrum SDS) shows a weak, broad transition centered near 485 nm. Resonance Raman spectra obtained by exciting into this absorption band with several visible laser lines (465.5–496.5 nm) give a single, sharp progression with up to ten Stokes transitions. These data give ωe=184.4(4) cm⁻¹, with ωexe=0.30(3) cm⁻¹, leading to a spectroscopic dissociation energy of De=3.5(4) eV. Comparison of our results with several ab initio calculations adds confirmation to the assignment of the ground state of Y₂ to be the ¹Σg⁺ state. |
format |
Article |
author |
Fang, Li Chen, Xiaoyu Shen, Xiaole Liu, Yifei Lindsay, D.M. Lombardi, John R. |
author_facet |
Fang, Li Chen, Xiaoyu Shen, Xiaole Liu, Yifei Lindsay, D.M. Lombardi, John R. |
author_sort |
Fang, Li |
title |
Spectroscopy of yttrium dimers in argon matrices |
title_short |
Spectroscopy of yttrium dimers in argon matrices |
title_full |
Spectroscopy of yttrium dimers in argon matrices |
title_fullStr |
Spectroscopy of yttrium dimers in argon matrices |
title_full_unstemmed |
Spectroscopy of yttrium dimers in argon matrices |
title_sort |
spectroscopy of yttrium dimers in argon matrices |
publisher |
Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України |
publishDate |
2000 |
topic_facet |
Low-Temperature Physics and Chemistry in Cryomatrice |
url |
http://dspace.nbuv.gov.ua/handle/123456789/129223 |
citation_txt |
Spectroscopy of yttrium dimers in argon matrices / Li Fang, Xiaoyu Chen, Xiaole Shen, Yifei Liu, D.M. Lindsay, John R. Lombardi // Физика низких температур. — 2000. — Т. 26, № 9-10. — С. 1011-1015. — Бібліогр.: 23 назв. — англ. |
series |
Физика низких температур |
work_keys_str_mv |
AT fangli spectroscopyofyttriumdimersinargonmatrices AT chenxiaoyu spectroscopyofyttriumdimersinargonmatrices AT shenxiaole spectroscopyofyttriumdimersinargonmatrices AT liuyifei spectroscopyofyttriumdimersinargonmatrices AT lindsaydm spectroscopyofyttriumdimersinargonmatrices AT lombardijohnr spectroscopyofyttriumdimersinargonmatrices |
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2023-10-18T20:57:11Z |
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2023-10-18T20:57:11Z |
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1796151538417139712 |